Search results for "620 Engineering"

showing 2 items of 12 documents

Real-time observation of the charge transfer to solvent dynamics

2013

Intermolecular electron-transfer reactions have a crucial role in biology, solution chemistry and electrochemistry. The first step of such reactions is the expulsion of the electron to the solvent, whose mechanism is determined by the structure and dynamical response of the latter. Here we visualize the electron transfer to water using ultrafast fluorescence spectroscopy with polychromatic detection from the ultraviolet to the visible region, upon photo-excitation of the so-called charge transfer to solvent states of aqueous iodide. The initial emission is short lived (similar to 60 fs) and it relaxes to a broad distribution of lower-energy charge transfer to solvent states upon rearrangeme…

electron transfer ultrafast fluorescence charge-transfer-to-solvent solvation homogeneity.Physics::Biological PhysicsMultidisciplinaryMaterials scienceAqueous solutionSettore FIS/01 - Fisica SperimentaleGeneral Physics and AstronomyHalideCharge (physics)General ChemistryElectron620 EngineeringGeneral Biochemistry Genetics and Molecular BiologyCondensed Matter::Soft Condensed MatterSolventElectron transferChemical physicsScientific methodPhysics::Chemical PhysicsSolvent effectsSettore CHIM/02 - Chimica FisicaNature Communications
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Prospective Validation of Facial Nerve Monitoring to Prevent Nerve Damage During Robotic Drilling

2019

Facial nerve damage has a detrimental effect on a patient's life, therefore safety mechanisms to ensure its preservation are essential during lateral skull base surgery. During robotic cochlear implantation a trajectory passing the facial nerve at <0.5 mm is needed. Recently a stimulation probe and nerve monitoring approach were developed and introduced clinically, however for patient safety no trajectory was drilled closer than 0.4 mm. Here we assess the performance of the nerve monitoring system at closer distances. In a sheep model eight trajectories were drilled to test the setup followed by 12 trajectories during which the ENT surgeon relied solely on the nerve monitoring system and…

medicine.medical_specialtylcsh:Surgery610 Medicine & healthENT surgeon03 medical and health sciences0302 clinical medicinerobotic surgerymedicineotorhinolaryngologic diseasesRobotic surgeryCochlear implantation610 Medicine & healthOriginal Research630 Agriculturebusiness.industrynerve stimulation electrodemonopolar and bipolarMonitoring systemlcsh:RD1-811Microcomputed tomography620 EngineeringFacial nerveneurophysiology monitoringSurgeryrobotic cochlear implantationRobotic systems030220 oncology & carcinogenesisSkull base surgery570 Life sciences; biologySurgerybusiness030217 neurology & neurosurgeryFrontiers in Surgery
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