Search results for "78"
showing 10 items of 1163 documents
Retrieval of absolute SO2 column amounts from scattered-light spectra: implications for the evaluation of data from automated DOAS networks
2018
Scanning spectrometer networks using scattered solar radiation in the ultraviolet spectral region have become an increasingly important tool for monitoring volcanic sulfur dioxide (SO2) emissions. Often measured spectra are evaluated using the differential optical absorption spectroscopy (DOAS) technique. In order to obtain absolute column densities (CDs), the DOAS evaluation requires a Fraunhofer reference spectrum (FRS) that is free of absorption structures of the trace gas of interest. For measurements at volcanoes such a FRS can be readily obtained if the scan (i.e. series of measurements at different elevation angles) includes viewing directions where the plume is not seen. In this cas…
Aerosol quantification with the Aerodyne Aerosol Mass Spectrometer: detection limits and ionizer background effects
2008
Systematic laboratory experiments were performed to investigate quantification of various species with two versions of the Aerodyne Aerosol Mass Spectrometer, a Quadrupole Aerosol Mass Spectrometer (Q-AMS) and a compact Time-of-Flight Aerosol Mass Spectrometer (c-ToF-AMS). Here we present a new method to continuously determine the detection limits of the AMS analyzers during regular measurements, yielding detection limit (<i>DL</i>) information under various measurement conditions. Minimum detection limits range from 0.03 μg m<sup>&minus;3</sup> (nitrate, sulfate, and chloride) up to 0.5 μg m<sup>&minus;3</sup> (organics) for the Q-AMS. Those of t…
Quantitative single-particle analysis with the Aerodyne aerosol mass spectrometer: development of a new classification algorithm and its application …
2018
Single-particle mass spectrometry has proven a valuable tool for gaining information on the mixing state of aerosol particles. With the Aerodyne aerosol mass spectrometer (AMS) equipped with a light-scattering probe, non-refractory components of submicron particles with diameters larger than about 300 nm can even be quantified on a single-particle basis. Here, we present a new method for the analysis of AMS single-particle mass spectra. The developed algorithm classifies the particles according to their components (e.g. sulphate, nitrate, different types of organics) and simultaneously provides quantitative information about the composition of the single particles. This classification algor…
Organosulfates in atmospheric aerosol: synthesis and quantitative analysis of PM2.5 from Xi'an, northwestern China
2018
The sources, formation mechanism and amount of organosulfates (OS) in atmospheric aerosol are not yet well understood, partly due to the lack of authentic standards for quantification. In this study, we report an improved robust procedure for the synthesis of organosulfates with different functional groups. Nine authentic organosulfate standards were synthesized and four standards (benzyl sulfate, phenyl sulfate, glycolic acid sulfate, and hydroxyacetone sulfate) were used to quantify their ambient concentrations. The authentic standards and ambient aerosol samples were analyzed using an optimized ultra performance liquid chromatography–electrospray ionization-tandem mass spectrometric meth…
Design of a mobile aerosol research laboratory and data processing tools for effective stationary and mobile field measurements
2012
A compact mobile aerosol research laboratory (MoLa) for stationary and mobile measurements of aerosol and trace gas characteristics was developed at the Max Planck Institute for Chemistry (MPIC) in Mainz, Germany. Major efforts were made to design an aerosol inlet system which is optimized and characterised for both, stationary and mobile measurements using a particle loss modelling approach. The instrumentation on board allows the determination of a multitude of physical and chemical aerosol parameters, for example particle number and mass concentration (PM<sub>1/2.5/10</sub>), particle size distributions in the diameter range 6 nm up to 32 μm, and chemical composition of the s…
The ion trap aerosol mass spectrometer: field intercomparison with the ToF-AMS and the capability of differentiating organic compound classes via MS-…
2017
Further development and optimisation of a previously described ion trap aerosol mass spectrometer (IT-AMS) are presented, which resulted in more reproducible and robust operation and allowed for the instrument's first field deployment. Results from this 11-day-long measurement indicate that the instrument is capable of providing quantitative information on organics, nitrate, and sulfate mass concentrations with reasonable detection limits (0.5–1.4 µg m−3 for 1 h averages) and that results obtained with the IT-AMS can directly be related to those from Aerodyne aerosol mass spectrometers. The capability of the IT-AMS to elucidate the structure of fragment ions is demonstrated via an MS4 study…
Bathymetry time series using high spatial resolution satellite images
2020
The use of the new generation of remote sensors, such as echo sounders and Global Navigation Satellite System (GNSS) receivers with differential correction installed in a drone, allows the acquisition of high-precision data in areas of shallow water, as in the case of the channel of the Encañizadas in the Mar Menor lagoon. This high precision information is the first step to develop the methodology to monitor the bathymetry of the Mar Menor channels. The use of high spatial resolution satellite images is the solution for monitoring many hydrological changes and it is the basis of the three-dimensional (3D) numerical models used to study transport over time, environmental variability, and wa…
A Self-Contained and Automated Method for Flood Hazard Maps Prediction in Urban Areas
2020
Water depths and velocities predicted inside urban areas during severe storms are traditionally the final result of a chain of hydrologic and hydraulic models. The use of a single model embedding all the components of the rainfall&ndash
Estimating Human Impacts on Soil Erosion Considering Different Hillslope Inclinations and Land Uses in the Coastal Region of Syria
2020
Soils in the coastal region of Syria (CRoS) are one of the most fragile components of natural ecosystems. However, they are adversely affected by water erosion processes after extreme land cover modifications such as wildfires or intensive agricultural activities. The main goal of this research was to clarify the dynamic interaction between erosion processes and different ecosystem components (inclination, land cover/land use, and rainy storms) along with the vulnerable territory of the CRoS. Experiments were carried out in five different locations using a total of 15 erosion plots. Soil loss and runoff were quantified in each experimental plot, considering different inclinations and land u…
Strategies for Improving Optimal Positioning of Quality Sensors in Urban Drainage Systems for Non-Conservative Contaminants
2021
In the urban drainage sector, the problem of polluting discharges in sewers may act on the proper functioning of the sewer system, on the wastewater treatment plant reliability and on the receiving water body preservation. Therefore, the implementation of a chemical monitoring network is necessary to promptly detect and contain the event of contamination. Sensor location is usually an optimization exercise that is based on probabilistic or black-box methods and their efficiency is usually dependent on the initial assumption made on possible eligibility of nodes to become a monitoring point. It is a common practice to establish an initial non-informative assumption by considering all network…