Search results for "8-hydroxyquinolinium"

showing 2 items of 2 documents

CCDC 152559: Experimental Crystal Structure Determination

2001

Related Article: F.Benetollo, G.Bombieri, A.Del Pra, G.Alonzo, N.Bertazzi|2001|Inorg.Chim.Acta|319|49|doi:10.1016/S0020-1693(01)00436-4

Space GroupCrystallographytetrakis(8-Hydroxyquinolinium) hexachlorobismuthate chloride dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

The influence of aromatic cations on the geometries of the Bi(III) halide polyhedra. Synthesis and crystal structures of quinolinium, isoquinolinium …

2001

Abstract The compounds [quinolinium]4[Bi2Cl10] (1), [isoquinolinium]4[Bi2Cl10].2H2O (2) and [8-hydroxyquinolinium]4[BiCl6]·Cl·2H2O (3) have been obtained by reacting bismuthate oxide and the appropriate base in HCl acid medium. The crystal structures of 1 and 2 consist of quinolinium and isoquinolinium cations, respectively, interacting through hydrogen bonding with [Bi2Cl10]4− dimers. The different degree of interactions in the two derivatives causes significant differences in the bond distances of the anions. The crystal structure of 3 is made of [BiCl6]3− and Cl− anions and 8-hydroxyquinolinium cations. Hydrogen bond interactions including the N-bonded and O-bonded H atoms together with …

chemistry.chemical_classificationBase (chemistry)Hydrogen bondInorganic chemistryChlorine atomBismuthateOxideHalideCrystal structureInorganic ChemistryCrystallographychemistry.chemical_compoundPolyhedron8-hydroxyquinoliniumchemistrybismuthMaterials ChemistrystructurePhysical and Theoretical ChemistryInorganica Chimica Acta

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