Search results for "97"
showing 10 items of 1081 documents
Investigation of the Thermomechanical Response of Cyclically Loaded NiTi Alloys by Means of Temperature Frequency Domain Analyses
2021
Nickel–Titanium (NiTi) shape memory alloys subjected to cyclic loading exhibit reversible temperature changes whose modulation is correlated with the applied load. This reveals the presence of reversible thermomechanical heat sources activated by the applied stresses. One such source is the elastocaloric effect, accounting for the latent heat of Austenite–Martensite phase transformation. It is, however, observed that when the amplitude of cyclic loads is not sufficient to activate or further propagate this phase transformation, the material still exhibits a strong cyclic temperature modulation. The present work investigates the thermomechanical behaviour of NiTi under such low-amplitude cyc…
Multivariate Assessment of Procedures for Molecularly Imprinted Polymer Synthesis for Pesticides Determination in Environmental and Agricultural Samp…
2021
In the case of quantitative and qualitative analysis of pesticides in environmental and food samples, it is required to perform a sample pre-treatment process. It allows to minimalize the impact of interferences on the final results, as well as increase the recovery rate. Nowadays, apart from routinely employed sample preparation techniques such as solid-phase extraction (SPE) or solid-phase microextraction (SPME), the application of molecularly imprinted polymers (MIPs) is gaining greater popularity. It is mainly related to their physicochemical properties, sorption capacity and selectivity, thermo-mechanical resistance, as well as a wide range of polymerization techniques allowing to obta…
Influence of Temperature on Characteristics of Particulate Matter and Ecological Risk Assessment of Heavy Metals during Sewage Sludge Pyrolysis
2021
The formation process of Particulate Matter (PM) during sludge pyrolysis at different temperatures (300–700 °C) and the ecological risks of heavy metals were studied. The results showed that the particulate matter is mainly condensed on the quartz film in a carbon-based organic matter when the pyrolysis temperature was between 200–500 °C in a volatilization process. Inorganic particles was found in the particulate matter when the temperature was raised to 500–700 °C in a decomposition stage. Heavy metals were enriched in particulate matter with increase in pyrolysis temperature. When the temperature reached 700 °C, the concentration of Pb and Cd in the particulate matter significantly incre…
Oxidation State and Local Structure of Chromium Ions in LaOCl
2021
This research is funded by the Latvian Council of Science, project “Novel transparent nanocomposite oxyfluoride materials for optical applications”, project No. LZP-2018/1-0335. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017- TeamingPhase2 under grant agreement No. 739508, project CAMART2.
Fabrication of CZTSe/CIGS Nanowire Arrays by One-Step Electrodeposition for Solar-Cell Application
2021
The paper reports some preliminary results concerning the manufacturing process of CuZnSnSe (CZTSe) and CuInGaSe (CIGS) nanowire arrays obtained by one-step electrodeposition for p-n junction fabrication. CZTSe nanowires were obtained through electrodeposition in a polycarbonate membrane by applying a rectangular pulsed current, while their morphology was optimized by appropriately setting the potential and the electrolyte composition. The electrochemical parameters, including pH and composition of the solution, were optimized to obtain a mechanically stable array of nanowires. The samples were characterized by scanning electron microscopy, Raman spectroscopy, and energy-dispersion spectros…
Shedding Light on Graphene Quantum Dots: Key Synthetic Strategies, Characterization Tools, and Cutting-Edge Applications
2021
During the last 20 years, the scientific community has shown growing interest towards carbonaceous nanomaterials due to their appealing mechanical, thermal, and optical features, depending on the specific nanoforms. Among these, graphene quantum dots (GQDs) recently emerged as one of the most promising nanomaterials due to their outstanding electrical properties, chemical stability, and intense and tunable photoluminescence, as it is witnessed by a booming number of reported applications, ranging from the biological field to the photovoltaic market. To date, a plethora of synthetic protocols have been investigated to modulate the portfolio of features that GQDs possess and to facilitate the…
Palladion Theosophicum : septem fultum columnis, congrua thesium varietate circumornatis ... / singulas propugnaturus ... pro obtinenda almae Sophiae…
1697
Escut xil. de la Ciutat de València a continuació de la port. Caplletra ornada Sign.: [ ]2, A-I4 Reclams Port. amb orla tip.
Graph-based exploration and clustering analysis of semantic spaces
2019
Abstract The goal of this study is to demonstrate how network science and graph theory tools and concepts can be effectively used for exploring and comparing semantic spaces of word embeddings and lexical databases. Specifically, we construct semantic networks based on word2vec representation of words, which is “learnt” from large text corpora (Google news, Amazon reviews), and “human built” word networks derived from the well-known lexical databases: WordNet and Moby Thesaurus. We compare “global” (e.g., degrees, distances, clustering coefficients) and “local” (e.g., most central nodes and community-type dense clusters) characteristics of considered networks. Our observations suggest that …
Influence of the Preparation Method and Photo-Oxidation Treatment on the Thermal and Gas Transport Properties of Dense Films Based on a Poly(ether-bl…
2018
Dense films based on the hydrophobic Pebax®
Coordination Driven Capture of Nicotine Inside a Mesoporous MOF.
2017
Metal organic frameworks (MOFs) are a wide class of crystalline porous polymers studied in many fields, ranging from catalysis to gas storage. In the past few years, MOFs have been studied for the encapsulation of organic or organometallic molecules and for the development of potential drug carriers. Here, we report on the study of two structurally-related mesoporous Cu-MOFs, namely PCN-6 and PCN-6′ (PCN stands for Porous Coordination Network), for nicotine trapping. Nicotine is a well-known alkaloid liquid molecule at room temperature, whose crystalline structure is still unknown. In this work, the loading process was monitored by electron ionization mass spectrometry by using a direct ins…