Search results for "AA"

Exceptional affinity of nanostructured organic-inorganic hybrid materials towards dioxygen: confinement effect of copper complexes

2007

We report the exceptional reactivity towards dioxygen of a nanostructured organic-inorganic hybrid material due to the confinement of copper cyclam within a silica matrix. The key step is the metalation reaction of the ligand, which can occur before or after xerogel formation through the sol-gel process. The incorporation of a Cu(II) center into the material after xerogel formation leads to a bridged Cu(I)/Cu(II) mixed-valence dinuclear species. This complex exhibits a very high affinity towards dioxygen, attributable to auto-organization of the active species in the solid. The remarkable properties of these copper complexes in the silica matrix demonstrate a high cooperative effect for O(2…

Fully reliable a posteriori error control for evolutionary problems

2015

Immigrant entrepreneur firm start-up behavior and reasoning : a reflective study of causation, effectuation and bricolage

2013

Entrepreneurship research studies how and why firms come into being, survive and grow (Davidsson, 2004; Gartner, 1985; Schumpeter, 1934). Early literature has proposed a linear model of entrepreneurship which is intentional (Bird, 1988), opportunity discovery (Kirzner, 1997; Shane and Venkataraman, 2000) and goal & strategy oriented (Wiklund & Shepherd, 2005). Being a mainstream in the earlier research, it is labelled as causation model by Sarasvathy (2001). Several scholars such as Baker & Nelson (2005) and Sarasvathy (2001a, b; 2008) questioned the validity of the model and proposed two additional models to the classic model: Effectuation (Sarasvathy, 1998) and Entrepreneurial Bricolage (…

The Experience of Impecuniousness in a Noble Family at the End of the Nineteenth Century

2017

Abstract Being a member of the elite imposed high demands on the livelihood of noble civil servant families in Finland at the end of the nineteenth century. Although the salaries of high-ranking officials were relatively substantial, they could not always ensure the standard of living which was demanded by the elite of the Grand Duchy of Finland. This article concerns the family of the governor, Baron Gustaf Aminoff, and their livelihood. The living of the Aminoff family was totally derived from Governor Aminoff's salaries and fees; they had no other sources of income, such as a manor or land. The Aminoff family constantly suffered a lack of money and its everyday consumption was rational a…

Altered morphological and electrophysiological properties of Cajal-Retzius cells in cerebral cortex of embryonic Presenilin-1 knockout mice

2004

Mutations of Presenilin-1 are the major cause of familial Alzheimer's disease. Presenilin-1 knockout (PS1-/-) mice develop severe cortical dysplasia related to human type 2 lissencephaly. This overmigration syndrome has been attributed to the premature loss of Cajal-Retzius cells (CRcs), pioneer neurons required for the termination of radial neuronal migration. To elucidate the potential cellular mechanisms responsible for this premature neuronal loss, we investigated the morphological and electrophysiological properties of visually identified CRcs of wild-type (WT) and PS1-/- mouse brains at embryonic day 16.5. The density of CRcs was substantially reduced in the cerebral cortex of PS1-/-.…

GABA: Receptors, transporters and metabolism

1996

Estimating the age and season-at-death of ungulates from the analysis of archaeological dental cementum: Recent improvements and perspectives from th…

2018

International audience

The resilience of Finnish farms: Exploring the interplay between agency and structure

2020

Resilience implies, in its essence, the capacity of a system to tolerate disturbances while retaining its essential functions. In the context of agriculture, resilience thinking calls for considering the ability of farms to thrive in turbulent times along with the ability of the ecological system – in which the agricultural production is embedded – to retain its function and integrity. Resilience is a relevant conceptual tool to analyse the contradictory management demands that farms are facing within the current neoliberal market regime: being economically viable and environmentally sustainable. In this study, the resilience of farms was operationalised through farmers' perceptions concern…

Theoretical study on travelling web dynamics and instability under non-homogeneous tension

2013

Problems of dynamics and stability of a moving web, travelling between two rollers at a constant velocity, are studied using analytical approaches. Transverse vibrations of the web are described by a partial differential equation that includes the centrifugal force, in-plane tension, elastic reaction and nonstationary inertial terms. The model of a thin elastic plate subjected to bending and non-homogeneous tension is used to describe the bending moment and the distribution of membrane forces. The stability of the plate is investigated with the help of studies of small out-of-plane vibrations. The influence of linearly distributed in-plane tension on the characteristics of the web vibration…

Poverty and Tax Exemptions in Mid-Nineteenth Century Finland

2017

The topic of this article is the nature and social character of Finnish rural poverty during the early stages of industrialization. Specifically, I analyze households exempted from two separate taxes in order to locate and study the rural poor. Contrary to several previous considerations deeming taxation sources unreliable in poverty studies, it is shown that under controlled settings tax exemption information does display promising features. These include a high exemption percentage of households without adult male members, small average household size of the tax exempted and a clear concentration of the exemptions on the lower rural social classes. My findings also highlight the fact that…