Search results for "ABLATION"

showing 2 items of 322 documents

Multi-color resonance ionization of laser ablated gadolinium at high laser power

2005

Abstract Spectroscopic and analytical properties of a trace analytical method using multi-step resonance ionization at high laser intensities (>kW/cm 2 ) have been investigated with gadolinium as a test element. Strongly saturated transitions are observed, which have been used for a temperature determination of the atoms in the laser ablated plume. Regimes of multi-step resonance ionization and multiphoton ionization could be distinguished. Analytical performances due to resonance enhancement and resulting discrimination against non-resonant background, precision in isotope ratio determination and overall detection efficiency are discussed.

Materials scienceMatrix-assisted laser desorption electrospray ionizationLaser ablationPhotoionizationLaserAtomic and Molecular Physics and OpticsIon sourceElectronic Optical and Magnetic Materialslaw.inventionAtmospheric-pressure laser ionizationlawIonizationPhysics::Atomic and Molecular ClustersPhysics::Atomic PhysicsLaser power scalingElectrical and Electronic EngineeringPhysical and Theoretical ChemistryAtomic physicsOptics Communications
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Trace element data covering 96-7 ka BP from stalagmite CM (Santo Tomas Cave, Cuba)

2020

We present a new speleothem trace element and stable isotope record, which extends previous paleoclimate evidence from Cuban speleothems to the last 96 ka. Stable isotope samples were micromilled at a resolution of 0.10-0.33mm, and measured using an IRMS equipped with a Gasbench. Line scans of Element/Calcium ratios of the speleothem were measured by laser ablation ICPMS and were reduced to the resolution of the stable isotope records.

Phosphorus/Calcium ratioSpeleothem samplepaleoclimatologytrace elementsCentral AmericaStrontium/Calcium ratioBarium Calcium ratioUranium Calcium ratioMagnesium/Calcium ratioLaser ablation inductively coupled plasma sector field mass spectrometer LA ICP SF MSUranium/Calcium ratioPhosphorus Calcium ratioAGEEarth System ResearchMagnesium Calcium ratioLaser-ablation inductively coupled plasma sector field mass spectrometer (LA-ICP-SF-MS)Barium/Calcium ratioStrontium Calcium ratiospeleothem
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