Search results for "AH"
showing 10 items of 6917 documents
The vibrational levels of methane obtained from analyses of high-resolution spectra
2006
International audience; Methane and its tetrahedral isotopologues are spherical-top molecules whose high-resolution rovibrational spectra can only be analyzed in detail, thanks to sophisticated symmetry-adapted tensorial models. However, the effective Hamiltonian parameters of such models do not give direct access to the positions of the vibrational sublevels. In this paper, we present a calculation of the vibrational level positions for 12CH4, 13CH4, 12CD4 and 13CD4 performed using the effective Hamiltonian parameters obtained through recent analyses. We also include the results of a re-analysis of the octad system of 12CH4 performed with a higher order of the development which slightly im…
External pressure and composition effects on the atomic and electronic structure of SnWO4
2015
The atomic and electronic structure of tin tungstates, α-SnWO4, α-Sn1.03W0.99O4 and β-SnWO4 ,w as studied by the W L3-edge X-ray absorption spectroscopy and first-principles linear combination of atomic orbital (LCAO) calculations based on the hybrid exchange-correlation density functional (DFT)/ Hartree–Fock (HF) scheme. It was found that the crystal structure of both α-phases is built up of strongly distorted WO6 octahedra, whereas that of β-SnWO4 is composed of nearly regular WO4 tetrahedra. In addition, there are distorted SnO6 octahedra in both α- and β-phases. The metal–oxygen octahedra distortion is explained by the second-order Jahn–Teller effect. The influence of pressure on the st…
Interaction of Cd(II) and Ni(II) terpyridine complexes with model polynucleotides: A multidisciplinary approach
2016
Two metal complexes of 2,2′:6′,2′′-terpyridine (terpy), i.e. Cd(terpy)Cl2 and Ni(terpy)Cl2·3H2O, have been prepared and extensively characterized. The interaction of Cd(terpy)Cl2 with synthetic DNA models, poly(dA-dT)·poly(dA-dT) (polyAT) and poly(dG-dC)·poly(dG-dC) (polyGC), has been studied by CD, fluorescence and UV-vis electronic absorption spectroscopy at several metal/polynucleotide–phosphate ratios and for different NaCl concentrations. All the experimental results indicate an intercalative mechanism of interaction. The optimized geometry of the cadmium complex intercalated between the sixth and seventh base pairs of (AT) and (GC) dodecanucleotide duplexes, obtained by quantum mechan…
Sovraccarico e rischi da dipendenza da lavoro negli accademici italiani: un'indagine conoscitiva
2018
Negli ultimi anni in Italia si è assistito ad un cambiamento nel lavoro del docente universitario, che ha spinto ad aumentare la quota di tempo da dedicare alle diverse attività (molte delle quali inattese all'atto della assunzione) e che ha prodotto una sorta di giustificazione "culturale" di comportamenti che possono essere configurabili a margine del rischio workaholism. Esiste una ampia letteratura relativa al peso del sovraccarico lavorativo dei lavoratori del sistema dell'educazione, ed in particolare connessi al peso delle attività d'aula ed all'aumento del lavoro burocratico; le ricerche che si sono occupate della "higher education" hanno però perlopiù connesso il sovraccarico lavor…
International workshop on next generation gamma-ray source
2022
Journal of physics / G 49(1), 010502 (2022). doi:10.1088/1361-6471/ac2827
Determination of phosphorus by instrumental neutron activation and bremsstrahlung measurement in bone samples
1997
A non destructive method based on the31P(n,γ)32P reaction for the assay of phosphorus in bone samples is described. This method involves a thermal neutron irradiation of 2 minutes in a reactor followed by the measurement of the bremsstrahlung produced by the β− of32P in a Ge-detector surrounded by an anti-Compton shield. Accuracy and precision were tested by analysing the certified NIST 1486 Bone Meal reference material and tri-calcium phosphate (Ca3(PO4)2) samples. The value obtained for the reference material was in good agreement with the certified value and with relative standard deviation of 4.1% the precision was acceptable. The value obtained for Ca3(PO4)2 shows a deviation of −6% fr…
Inhibitory effects on mitochondrial complex I of semisynthetic mono-Tetrahydrofuran acetogenin derivatives
2003
Modifications in the terminal alpha,beta-unsaturated gamma-methyl-gamma-lactone moiety or in the alkyl chain that links this terminal gamma-lactone with the alpha,alpha'-dihydroxylated THF system of the natural mono-tetrahydrofuranic acetogenins, annonacin and annonacinone, led to the preparation of eight semisynthetic derivatives. Their inhibitory effects on mitochondrial complex I is discussed and compared with that of the classical complex I inhibitor, rotenone.
Combining gestures and vocalizations to imitate sounds
2015
International audience; Communicating about sounds is a difficult task without a technical language, and naïve speakers often rely on different kinds of non-linguistic vocalizations and body gestures (Lemaitre et al. 2014). Previous work has independently studied how effectively people describe sounds with gestures or vocalizations (Caramiaux, 2014, Lemaitre and Rocchesso, 2014). However, speech communication studies suggest a more intimate link between the two processes (Kendon, 2004). Our study thus focused on the combination of manual gestures and non-speech vocalizations in the communication of sounds. We first collected a large database of vocal and gestural imitations of a variety of …
Comparing identification of vocal imitations and computational sketches of everyday sounds
2016
International audience; Sounds are notably difficult to describe. It is thus not surprising that human speakers often use many imitative vocalizations to communicate about sounds. In practice,vocal imitations of non-speech everyday sounds (e.g. the sound of a car passing by) arevery effective: listeners identify sounds better with vocal imitations than with verbal descriptions, despite the fact that vocal imitations are often inaccurate, constrained by the human vocal apparatus. The present study investigated the semantic representations evoked by vocal imitations by experimentally quantifying how well listeners could match sounds to category labels. Itcompared two different types of sounds…
SOLID LIPID NANOPARTICLES FOR APPLICATIONS IN GENE THERAPY: A REVIEW OF THE STATE OF THE ART
2010
Importance of the field. Gene therapy represents a new paradigm in the prevention and treatment of many inherited and acquired diseases, including genetic disorders, such as cystic fibrosis, haemophilia and many somatic diseases, such as tumours, neurodegenerative diseases and viral infections, such as AIDS. Areas covered in this review. Among a large array of non-viral transfection agents used for in-vitro applications, cationic SLNs are the topic of this review, being recently proposed as an alternative carrier for DNA delivery, due to many technological advantages such as large-scale production from substances generally recognized as safe, good storage stability and possibility of steam …