Search results for "ATAL"
showing 10 items of 10591 documents
La cosificació de les normes d'ús lingüístic. Aspectes sociològics d'un discurs distorsionat
1996
The subject matter of sociolinguistics are the rules or patterns of the functioning of language. But rules and transgressions are complementary facts, and sociolinguists must study both conventional and intentional language use (that is, traditional and meaningful social actions). When sociolinguistics deals exclusively with norms, but ne t with transgressions, sociolinguists reify a socially constructed reality. By applying the concept of reification, we consider that sociolinguists confuse rules, laws and regularities; therefore, more interpretation is needed to complement explanation, and it seems that sociolinguistics needs more «research programmes» studying the importance of individua…
Chasing Weak Forces: Hierarchically Assembled Helicates as a Probe for the Evaluation of the Energetics of Weak Interactions.
2017
London dispersion forces are the weakest interactions between molecules. Because of this, their influence on chemical processes is often low, but can definitely not be ignored, and even becomes important in cases of molecules with large contact surfaces. Hierarchically assembled dinuclear titanium(IV) helicates represent a rare example in which the direct observation of London dispersion forces is possible in solution even in the presence of strong cohesive solvent effects. Hereby, the dispersion forces do not unlimitedly support the formation of the dimeric complexes. Although they have some favorable enthalpic contribution to the dimerization of the monomeric complex units, large flexible…
Maanviljelijöiden sopeutuminen maatalouden rakennemuutokseen : sopeutumisen identiteettiteoreettista tarkastelua Saarijärven-Viitasaaren seutukunnassa
2012
Suomalaisen maatalouden nopea rakennemuutos on muuttanut maataloutta, maataloustyötä ja siihen liittyvää elämäntapaa kokonaisvaltaisesti. Tässä työssä selvitän, millä tavoin maanviljelijät ovat sopeutuneet maatalouden rakennemuutokseen. Lähestyn viljelijöiden sopeutumista sosiaalipsykologisesta näkökulmasta ja huomioni on maanviljelijöiden tekemässä identiteettityössä. Maanviljelijöiden identiteetin katsotaan selittävän maatalouden toimintaympäristössä tapahtuneiden muutosten omaksumista. Käyttämäni Sheldon Strykerin strukturalistinen identiteettiteoria pohjautuu George Herbert Meadin ja Herbert Blumerin hahmottelemaan symboliseen interaktionismiin. Symboliseen interaktionismiin pohjautuva …
Suomen maatalouden sopeutuminen Euroopan unionin maatalousjärjestelmään
1997
Newborn hearing screening in Sicily: Lesson learned
2013
Financialization of Eldercare in a Nordic Welfare State
2022
Abstract The increasing presence of for-profit service providers in publicly-funded eldercare has transformed care in Nordic welfare states which have a strong tradition of public care provision. Macro-level research on care policies has mainly focused on public institutions, national policies, and marketization. The financialization of eldercare has not received much scholarly attention, and existing studies mostly focus on the UK. The financialization of eldercare refers to the ways in which care is both a site of profit extraction and financial engineering. The Nordic system is relatively universal, and, with rapidly ageing demographics, there is a secured demand for eldercare services. …
Constructing social Europe through European cultural heritage
2021
The political and economic crises of the recent decades as well as the new changes brought on by globalization and digitalization have contributed to exacerbate social inequalities and injustice and revealed different social realities in Europe. The EU increasingly deals with social issues in its cultural and heritage policy. In this article, we explore the construction of this social dimension and advance the concept of 'social Europe' by exploring its cultural aspect based on our analysis of a recent EU heritage action, the European Heritage Label. In this action, the narrations of the European past and the attempts to foster common cultural heritage in Europe function as building blocks …
The Dawn of the Human-Machine Era: A forecast of new and emerging language technologies
2021
New language technologies are coming, thanks to the huge and competing private investment fuelling rapid progress; we can either understand and foresee their effects, or be taken by surprise and spend our time trying to catch up. This report scketches out some transformative new technologies that are likely to fundamentally change our use of language. Some of these may feel unrealistically futuristic or far-fetched, but a central purpose of this report - and the wider LITHME network - is to illustrate that these are mostly just the logical development and maturation of technologies currently in prototype. But will everyone benefit from all these shiny new gadgets? Throughout this report we …
A Theoretical and Experimental Investigation of the Spectroscopic Properties of a DNA-Intercalator Salphen-Type ZnIIComplex
2014
The photophysical and DNA-binding properties of the cationic zinc(II) complex of 5-triethylammonium methyl salicylidene ortho-phenylenediiminato (ZnL 2 + ) were investi- gated by a combination of experimental and theoretical methods. DFT calculations were performed on both the ground and the first excited states of ZnL 2 + and on its possi- ble mono- and dioxidation products, both in vacuo and in selected solvents mimicked by the polarizable continuum model. Comparison of the calculated absorption and fluores- cence transitions with the corresponding experimental data led to the conclusion that visible light induces a two-elec- tron photooxidation process located on the phenylenediimi- nato…
BODIPY atropisomer interconversion, face discrimination, and superstructure appending
2016
International audience; A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two inter-convertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins.