Search results for "ATAL"

Supramolecular Organocatalysis in Water Mediated by Macrocyclic Compounds

2018

In the last decades many efforts have been devoted to design supramolecular organocatalysts able to work in water as the reaction medium. The use of water as solvent provides promising benefits with respect to environmental impact. In this context, macrocyclic compounds played a role of primary importance thanks to their ease of synthesis and their molecular recognition abilities toward the reactants. The aim of this review is to give an overview of the recent advances in the field of supramolecular organocatalysis in water, focusing the attention on calixarene and cyclodextrins derivatives. Calixarenes and cyclodextrins, thanks to their hydrophobic cavities, are able to host selectively th…

The Supranational Dimension in Max Weber’s Vision of Politics

2019

Max Weber analyzed politics from the perspective of Chancen for actors, and he never separated world politics from domestic politics. The “Westphalian balance” between great European powers shaped Weber’s views on international polity. However, he also regarded Western individualism, human rights, and parliamentary democracy as necessary qualities to possess in order to be recognized as a great power. This vision provided the basis for his wartime critique of the expansionist tendencies in German foreign policy and for his demand for the parliamentarization of German politics. After the end of World War I, Weber used Woodrow Wilson’s idea of the League of Nations as the basis for a proposal…

Regionalizm zagrożeniem czy wyzwaniem dla demokratycznego państwa prawa? Kilka uwag w sprawie Katalonii

2018

Aspiracje Katalończyków do przekształcenia wspólnoty autonomicznej wpływają na koncepcję strukturalną państwa autonomicznego, nierozerwalną jedność narodu hiszpańskiego wyrażoną w art. 2, jak również przypisaną ludowi hiszpańskiemu suwerenność na mocy art. 1.2. Unia Europejska nie ingeruje w rozwiązania systemowe państw członkowskich. Problem stopnia decentralizacji, autonomii czy podziału zadań na linii władze centralne – poziom regionalny pozostawia kompetencji władz krajowych. Konstruktywnej dyskusji – w obliczu Brexitu, referendum w Szkocji, powracającej perspektywy Catalanexitu czy też innych silnych ruchów regionalnych – wydaje się jednak obawiać, a jest to problem, którego nie można …

On the biradicaloid nature of long quinoidal oligothiophenes: experimental evidence guided by theoretical studies.

2007

Structure and Photocatalytic Properties of TiO2-WO3Composites Prepared by Electrophoretic Deposition

2015

In this work TiO2-WO3 composite films containing different oxide concentrations were prepared by electrophoretic deposition on steel substrates. Composite coating structures were analyzed by X -ray diffraction, Raman spectra and scanning electron microscopy. The results showed an even distribution of WO3 particles in the entire composite layer. Light absorption measurements were used for photocatalytic properties evaluation. It was found that the removal ratio of methylene blue depends on the (TiO2):(WO3) concentration ratio. The most effective photodegradation was determined for the sample that was electrophoretically deposited from the suspension with the molar content ratio n(TiO2):n(WO3…

Constant inner potential DFT for modelling electrochemical systems under constant potential and bias

2021

Electrochemical interfaces and reactions play a decisive role in e.g. clean energy conversion but understanding their complex chemistry remains an outstanding challenge. Constant potential or grand canonical ensemble (GCE) simulations are indispensable for unraveling the properties of electrochemical processes as a function of the electrode potential. Currently, constant electrode potential calculations at the density functional theory (DFT) level are carried out by fixing the Fermi level of the simulation cell. However, the Fermi level from DFT calculations does does not always reflect the experimentally controlled electrode potential or describe the thermodynamic independent variable in G…

A route to simple nonionic surfactants

2016

AbstractA method for the synthesis of nonionic surfactants – N-alkyl-O-(2-hydroxyethyl) carbamates is proposed by acylation of fatty amines with ethylene carbonate without any solvent or catalyst. The surface tension of the prepared surfactants was measured, toxicity and biodegradability were determined for the surfactant with n-dodecyl as a hydrophobic group and N-monosubstituted amide and hydroxyl groups for their hydrophilic part.

An Easy Route Towards Regioselectively Difunctionalized Cyclens and New Cryptands.

2006

Reductive amination of various aldehydes with cyclen represents a very convenient method for the synthesis of a wide range of 1,7-difunctionalized cyclens, as well as new cryptands.

Synthesis and selected properties of metallo and metal-free 2,3,9,10,16,17,23,24-octacarboxyphthalocyanines

2015

This review article reports methods of synthe sis and selected physicochemical properties of metallo and metal-free 2,3,9,10,16,17,23,24–octacarboxyphthalocyanines. The most frequently used methods of synthesis for this class of co mpounds are described in this article. Moreover, aggregation, catalytic and photocatalytic properties of these complexes are presented. Potential applications of metallo and metal-free 2,3,9,10,16,17,23,24–octacarboxyphthalocyanines are also given.

Use of Fe and Al containing electrocoagulation sludge as an adsorbent and a catalyst in water treatment

2023

In this study, three different electrocoagulation (EC) sludges were studied as an adsorbent (removal of humic acids) and as a catalyst [catalytic wet peroxide oxidation (CWPO) of bisphenol A (BPA)]. The sludges originated from electrocoagulation process in which aluminum (Al) and iron (Fe) electrodes were used for the treatment of mining industry wastewater. All the materials were used as dried sludge and calcined material. The stability of these materials was studied in neutral and alkaline conditions with analysis of the leached iron content in solution. Based on the EC sludge characterization with X-ray fluorescence (XRF), X-ray diffractometer (XRD), and diffuse-reflectance infrared Four…