Search results for "ATAL"
showing 10 items of 10591 documents
Ortho -Functionalized Aryltetrazines by Direct Palladium-Catalyzed C−H Halogenation: Application to Fast Electrophilic Fluorination Reactions
2016
International audience; A general catalyzed direct C-H functionalization of s-tetrazines is reported. Under mild reaction conditions, N-directed ortho-C-H activation of tetrazines allows the introduction of various functional groups, thus forming carbon-heteroatom bonds: C-X (X=I, Br, Cl) and C-O. Based on this methodology, we developed electrophilic mono- and poly-ortho-fluorination of tetrazines. Microwave irradiation was optimized to afford fluorinated s-aryltetrazines, with satisfactory selectivity, within only ten minutes. This work provides an efficient and practical entry for further accessing highly substituted tetrazine derivatives (iodo, bromo, chloro, fluoro, and acetate precurso…
Synteza i właściwości fizykochemiczne ftalocyjaniny manganu
2017
Ftalocyjaniny to organiczne związki chemiczne, które uzyskuje się jedynie na drodze syntezy chemicznej. Stanowią one jednak analogi strukturalne porfiryn, które naturalnie występują w przyrodzie, m.in. w takich cząsteczkach jak witamina B12 czy chlorofil. Obszerne badania dotyczące kompleksów ftalocyjanin wynikają z budowy tych związków, ponieważ cząsteczkę ftalocyjaniny można modyfikować na bardzo wiele sposobów. Wpływa to na różnorodność zastosowań ftalocyjanin, m.in. w urządzeniach elektronicznych, fotowoltaicznych, jako fotosensiblilizatory, barwniki i pigmenty. Kompleksy ftalocyjanin z takimi metalami jak mangan czy kobalt są intensywnie badane ze względu na ich interesujące właściwośc…
Habitat area and local habitat conditions outweigh fragmentation effects on insect communities in vineyards
2022
Fragmentation of habitat, for example by intensive agricultural practices, can be detrimental to local biodiversity. However, it often remains unclear whether such biodiversity declines are caused by loss of habitat area or increased fragmentation, and how habitat quality factors into it. In our study system, vegetated vineyards are typically small, and isolated from one another, potentially limiting the distribution and dispersal of organisms. In a full-factorial experiment of a priori selected vegetated vineyard patches of differing size and fragmentation, we aimed to disentangle the effects of habitat area (area of vegetated vineyards), habitat fragmentation (number of vegetated vineyard…
Conservation of the positions of metazoan introns from sponges to humans
2002
Abstract Sponges (phylum Porifera) are the phylogenetic oldest Metazoa still extant. They can be considered as reference animals (Urmetazoa) for the understanding of the evolutionary processes resulting in the creation of Metazoa in general and also for the metazoan gene organization in particular. In the marine sponge Suberites domuncula , genes encoding p38 and JNK kinases contain nine and twelve introns, respectively. Eight introns in both genes share the same positions and the identical phases. One p38 intron slipped for six bases and the JNK gene has three more introns. However, the sequences of the introns are not conserved and the introns in JNK gene are generally much longer. Intron…
Photocatalytic nano-composite architectural lime mortar for degradation of urban pollutants under solar and visible (interior) light
2017
Abstract Recent advances in nano-technology and nano-additives can give enhanced properties to natural hydraulic lime (NHL), creating a multifunctional material. We have prepared a novel nanocomposite, made of a commercial mortar with 1 wt% and 5 wt% added titania nanoparticles (NPs). These TiO 2 NPs are themselves doped with 1 mol% silver, to give the material enhanced photocatalytic and antimicrobial properties. The Ag-doped TiO 2 NPs were made from a simple, costs effective, aqueous green nanosynthesis process, and the end material only contains 0.01–0.05% Ag. As this mortar is intended to both combat atmospheric pollution, and create more durable/lower maintenance building facades (plas…
EU:n maatalouspolitiikka ja kestävä kehitys
2015
Maatalous on EU:n pisimmälle integroitu toimiala ja politiikanala. Yhteisen maatalouspolitiikan tarina 1960-luvulta nykyaikaan kuvaa muuttuvia ja monipuolistuvia yhteiskunnallisia haasteita, joihin politiikkatoimenpiteillä on vastattu. Alkuaikoina päähuomio oli elintarvikehuollossa ja viljelijöiden toimeentulossa, mutta ajan myötä mukaan on tullut vahvoja alueellisia, ympäristöllisiä ja myös kulttuurisia painotuksia. Kestävän kehityksen käsittein tarkasteltuna yhteinen maatalouspolitiikka on muuttunut moniulotteisemmaksi. Viimeisimmillä uudistuksilla on tavoiteltu kestävyyden sekä taloudelliseen, ympäristölliseen, sosiaaliseen että kulttuuriseen ulottuvuuteen liittyviä muutoksia. Kestävä ke…
Disruptive Utopianism : Opening the Present
2020
Színháztörténeti metszetek a 19. század végétöl a 20. század közepéig
2008
The target area of my research is the history of the theatre in the last decades of the 19th and the first decades of the 20th centuries. I am trying to reveal what kind of theatre existed on the fringes of the world of theatre, because in the first decades of the 20th century several artists tried to follow the new European trends and to make use of their results. I wish to present this process through the careers of two actors: Irén Feld and Artúr Bárdos. Besides these experiments I wish to deal with theatre in the country. In the second half of the 19th century several modern theatre buildings were erected in the country, along which the quality of the performances slightly improved, too…
Rearing background and exposure environment together explain higher survival of aquaculture fish during a bacterial outbreak
2019
1.Parasitic diseases represent one of the greatest challenges for aquaculture worldwide and there is an increasing emphasis on ecological solutions to prevent infections. One proposed solution is enriched rearing, where traditional stimulus‐poor rearing tanks are equipped with different types of structures to increase habitat complexity. Such spatial enrichment is known to increase survival of fish during parasite epidemics, but the underlying mechanisms are still unclear. 2.We studied whether enriched rearing affected infection of an important fish pathogen Flavobacterium columnare in young Atlantic salmon (Salmo salar) and sea‐migrating brown trout (Salmo trutta). First, we used natural b…