Search results for "ATOMIC SPECTROSCOPY"
showing 9 items of 29 documents
Dispersive evaluation of the Lamb shift in muonic deuterium from chiral effective field theory
2020
We merge the dispersive relation approach and the ab initio method to compute nuclear structure corrections to the Lamb shift in muonic deuterium. We calculate the deuteron response functions and corresponding uncertainties up to next-to-next-to-next-to-leading order in chiral effective field theory and compare our results to selected electromagnetic data to test the validity of the theory. We then feed response functions calculated over a wide range of kinematics to the dispersion-theory formalism and show that an improved accuracy is obtained compared to that with the use of available experimental data in the dispersive analysis. This opens up the possibility of applying this hybrid metho…
Nuclear Ground-State Properties from Laser and Mass Spectroscopy
1990
Atomic physics played an important role in establishing our present-day knowledge on the atomic nucleus. Especially mass spectrometry and optical spectroscopy were the main sources of information on nuclear properties in the early days of nuclear physics. Still now, precise information on nuclear masses (or binding energies) are obtained by mass spectrometry whereas mass differences between two isotopes are usually determined by nuclear-spectroscopy techniques via a determination of the Q-value of nuclear reactions or decay. Almost all our information on the nuclear spins I, the nuclear magnetic dipole moment μ I, the spectroscopic quadrupole moment Q, and the changes in the mean-square cha…
Search for Ultralight Scalar Dark Matter with Atomic Spectroscopy
2015
We report new limits on ultralight scalar dark matter (DM) with dilaton-like couplings to photons that can induce oscillations in the fine-structure constant alpha. Atomic dysprosium exhibits an electronic structure with two nearly degenerate levels whose energy splitting is sensitive to changes in alpha. Spectroscopy data for two isotopes of dysprosium over a two-year span is analyzed for coherent oscillations with angular frequencies below 1 rad/s. No signal consistent with a DM coupling is identified, leading to new constraints on dilaton-like photon couplings over a wide mass range. Under the assumption that the scalar field comprises all of the DM, our limits on the coupling exceed tho…
Probing fast oscillating scalar dark matter with atoms and molecules
2021
Light scalar Dark Matter with scalar couplings to matter is expected within several scenarios to induce variations in the fundamental constants of nature. Such variations can be searched for, among other ways, via atomic spectroscopy. Sensitive atomic observables arise primarily due to possible changes in the fine-structure constant or the electron mass. Most of the searches to date have focused on slow variations of the constants (i.e. modulation frequencies $<$ 1 Hz). In a recent experiment \mbox{[Phys. Rev. Lett. 123, 141102 (2019)]} called WReSL (Weekend Relaxion-Search Laboratory), we reported on a direct search for rapid variations in the radio-frequency band. Such a search is particu…
Optical frequency combs for space applications
2016
Optical frequency comb-based high resolution laser spectroscopy has been demonstrated in space under micro-gravity on two sounding rocket based experiments. The comb has been used to simultaneously measure two different atomic transitions.
Fast apparent oscillations of fundamental constants
2019
Precision spectroscopy of atoms and molecules allows one to search for and to put stringent limits on the variation of fundamental constants. These experiments are typically interpreted in terms of variations of the fine structure constant $\alpha$ and the electron to proton mass ratio $\mu=m_e/m_p$. Atomic spectroscopy is usually less sensitive to other fundamental constants, unless the hyperfine structure of atomic levels is studied. However, the number of possible dimensionless constants increases when we allow for fast variations of the constants, where "fast" is determined by the time scale of the response of the studied species or experimental apparatus used. In this case, the relevan…
Liquid sample introduction in inductively coupled plasma atomic emission and mass spectrometry — Critical review
2014
Abstract Inductively coupled plasma optical emission spectroscopy (ICP-OES) and mass spectrometry (ICP-MS) can be considered as the most important tools in inorganic analytical chemistry. Huge progress has been made since the first analytical applications of the ICP. More stable RF generators, improved spectrometers and detection systems were designed along with the achievements gained from advanced microelectronics, leading to overall greatly improved analytical performance of such instruments. In contrast, for the vast majority of cases liquid sample introduction is still based on the pneumatic principle as described in the late 19th century. High flow pneumatic nebulizers typically deman…
Critical review of the atomic spectrometric analysis of arsenic in foods
1994
The literature on the determination of arsenic in foods by atomic spectroscopy involving hydride generation, platform furnace Zeeman and inductively coupled plasma has been critically reviewed. Hydride generation has been largely displaced as a powerful tool by platform furnace Zeeman, using the STPF (stabilized temperature platform furnace) concept for the control of interferences. Inductively coupled plasma with conventional pneumatic nebulization has been little used. An alternative is to employ hydride generation-ICP with extraction of the arsenic in an organic phase. This technique permits proper control of interferences together with an increase in sensitivity. Depending on the conten…
The measurement of impurities in silicon for solar cell production
2012
The power conversion efficiency of solar cells is largely dependent on impurity levels in silicon. In the current investigations two sample preparation methods of silicon had been used before analysis - acid dissolution at atmospheric pressure and pressured microwave assisted technique. Quantification of impurities in solar silicon was done by inductively coupled plasma mass spectrometry and electrothermal atomic spectrometry. Microwave assisted dissolution of solar silicon was more effective compared to the traditional dissolution method on the hot plate, but complete dissolution of impurities and silicon matrix was achieved with a nitric and hydrofluoric acid mixture. The mass of solar si…