Search results for "Absolut"
showing 10 items of 551 documents
Vibrational circular dichroism spectroscopy for probing the expression of chirality in mechanically planar chiral rotaxanes
2020
Mechanically interlocked molecules can exhibit molecular chirality that arises due to the mechanical bond rather than covalent stereogenic units. Developing applications of such systems is made challenging by the absence of techniques for assigning the absolute configuration of products and methods to probe how the mechanical stereogenic unit influences the spatial arrangements of the functional groups in solution. Here we demonstrate for the first time that Vibrational Circular Dichroism (VCD) can be used to not only discriminate between mechanical stereoisomers but also provide detailed information on their (co)conformations. The latter is particularly important as these molecules are now…
COMPLEX ANALYSIS OF COMPANY BANKRUPTCY FORECASTING: THEORETICAL INSIGHT
2018
In modern conditions for dynamic and competitive businesses, more and more companies face financial problems and eventually go bankrupt. A noteworthy trend: not only new companies that have not yet managed to establish themselves in the market go bankrupt but also large companies operating for years and maintaining good traditions. Bankruptcies of companies cause many problems not only for the companies themselves but also for the state and many members of society. Thus, it is crucial to evaluate the financial state of a company and its activity results as accurately and early as possible when forecasting the possibility of a bankruptcy. The paper recommends a complex analysis methodology f…
Revealing the pace of river landscape evolution during the Quaternary: recent developments in numerical dating methods
2016
During the last twenty years, several technical developments have considerably intensified the use of numerical dating methods for the Quaternary. The study of fluvial archives has greatly benefited from these enhancements, opening new dating horizons for a range of archives at distinct time scales and thereby providing new insights into previously unanswered questions. In this contribution, we separately present the state of the art of five numerical dating methods that are frequently used in the fluvial context: radiocarbon, Luminescence, Electron Spin Resonance (ESR), 230Th/U and terrestrial cosmogenic nuclides (TCN) dating. We focus on the major recent developments for each technique th…
Large Eddy Simulations of Rough Turbulent Channel Flows Bounded by Irregular Roughness: Advances Toward a Universal Roughness Correlation
2020
The downward shift of the mean velocity profile in the logarithmic region, known as roughness function, $$\Delta U^+$$ , is the major macroscopic effect of roughness in wall bounded flows. This speed decrease, which is strictly linked to the friction Reynolds number and the geometrical properties which define the roughness pattern such as roughness height, density, shape parameters, has been deeply investigated in the past decades. Among the geometrical parameters, the effective slope (ES) seems to be suitable to estimate the roughness function at fixed friction Reynolds number, Re $$_{\tau }$$ . In the present work, the effects of several geometrical parameters on the roughness function, i…
Fusaristatins D–F and (7S,8R)-(−)-chlamydospordiol from Fusarium sp. BZCB-CA, an endophyte of Bothriospermum chinense
2021
Abstract Three new lipodepsipeptides, fusaristatins D–F (1–3) and a new α-pyrone derivative, (7S,8R)-(−)-chlamydospordiol (5), together with eight known compounds (4, 6–12) were obtained from solid rice cultures of Fusarium sp. BZCB-CA, an endophyte of the Chinese medicinal plant, Bothriospermum chinense. The planar structures of the new metabolites (1–3, 5) were established by spectroscopic techniques (1D/2D NMR and HRESIMS). Marfey’s method was applied to determine the absolute configuration of 1, while the absolute configuration of 5 was determined by single-crystal X-ray crystallography analysis in addition to Mosher’s method. Crystallographic data of inflatin C (7) are also supplied he…
The efficiency of gel permeation chromatography
2007
The resolution power of gel permeation chromatography (GPC) columns and their combinations is tested as a function of the pore sizes of the gels and as a function of the elution velocity. The efficiency of GPC is characterized by the ratio UG/UT, where UG is the experimental, and UT the theoretical, inhomogeneity. The latter quantity is obtained from absolute measurements of Mw, and Mn. The ratio passes through a minimum for a series of columns with increasing pore sizes. The minimum occurs at that column or column set which is best suited to resolving a given polymer. UG/UT for any column decreases with decreasing elution velocity. At a certain velocity UG/UT becomes 1. This velocity is us…
An efficient data model for energy prediction using wireless sensors
2019
International audience; Energy prediction is in high importance for smart homes and smart cities, since it helps reduce power consumption and provides better energy and cost savings. Many algorithms have been used for predicting energy consumption using data collected from Internet of Things (IoT) devices and wireless sensors. In this paper, we propose a system based on Multilayer Perceptron (MLP) to predict energy consumption of a building using collected information (e.g., light energy, day of the week, humidity, temperature, etc.) from a Wireless Sensor Network (WSN). We compare our system against four other classification algorithms, namely: Linear Regression (LR), Support Vector Machin…
Curve packing and modulus estimates
2018
A family of planar curves is called a Moser family if it contains an isometric copy of every rectifiable curve in $\mathbb{R}^{2}$ of length one. The classical "worm problem" of L. Moser from 1966 asks for the least area covered by the curves in any Moser family. In 1979, J. M. Marstrand proved that the answer is not zero: the union of curves in a Moser family has always area at least $c$ for some small absolute constant $c > 0$. We strengthen Marstrand's result by showing that for $p > 3$, the $p$-modulus of a Moser family of curves is at least $c_{p} > 0$.
Tanzawaic acid derivatives from freshwater sediment-derived fungus Penicillium sp.
2018
Abstract Chemical investigation of a freshwater sediment-derived fungus, Penicillium sp. (S1a1), led to the isolation of three new tanzawaic acid derivatives, including penitanzchroman (1), tanzawaic acids Y (2) and Z (3), along with six known tanzawaic acid analogues (4-9), three known isochromans (10-12) and two known benzoquinones (13 and 14). The structures of the new compounds were established based on high-resolution mass spectrometry, and detailed analysis of one- and two-dimensional NMR spectroscopy. The relative configuration of the new compounds was assigned on the basis of NMR spectroscopic data including ROESY spectra. The absolute configuration was determined based on the speci…
Chronology of early Archaean granite-greenstone evolution in the Barberton Mountain Land, South Africa, based on precise dating by single zircon evap…
1991
We report precise 207Pb/206Pb single zircon evaporation ages for low-grade felsic metavolcanic rocks within the Onverwacht and Fig Tree Groups of the Barberton Greenstone Belt (BGB), South Africa, and from granitoid plutons bordering the belt. Dacitic tuffs of the Hooggenoeg Formation in the upper part of the Onverwacht Group yield ages between 3445 +/- 3 and 3416 +/- 5 Ma and contain older crustal components represented by a 3504 +/- 4 Ma old zircon xenocryst. Fig Tree dacitic tuffs and agglomerates have euhedral zircons between 3259 +/- 5 and 3225 +/- 3 Ma in age which we interpret to reflect the time of crystallization. A surprisingly complex xenocryst population in one sample documents …