Search results for "Absolute"

Azacoccones F-H, new flavipin-derived alkaloids from an endophytic fungus Epicoccum nigrum MK214079.

2020

Abstract Three new flavipin-derived alkaloids, azacoccones F-H (1–3), along with six known compounds (4–9) were isolated from the endophytic fungus Epicoccum nigrum MK214079 associated with leaves of Salix sp. The structures of the new compounds were established by analysis of their 1D/2D nuclear magnetic resonance (NMR) and high-resolution electrospray ionization mass spectroscopy (HRESIMS) data. The absolute configuration of azacoccones F-H (1–3) was determined by comparison of experimental electronic circular dichroism (ECD) data with reported ones and biogenetic considerations. Epicocconigrone A (4), epipyrone A (5), and epicoccolide B (6) exhibited moderate antibacterial activity again…

Kaemgalangol A: Unusual seco-isopimarane diterpenoid from aromatic ginger Kaempferia galanga.

2018

Abstract A new unusual seco-isopimarane, kaemgalangol A (1) and 12 usual analogs (2−13) were isolated from the rhizomes of Kaempferia galanga (Family: Zingiberaceae). KaemgalangolA (1) represented a rarely isolated 9,10-seco-isopimarane skeleton. The chemical structures of the isolated compounds were mainlyinvestigated by spectroscopic techniques such as 1D, 2D NMR, and HRMS. The absolute configuration of 1–3 was studied by X-ray diffraction analysis as well as experimental and TDDFT-calculated electronic circular dichroism. Among the isolated diterpenoids, 5, 6 and 9 exhibited cytotoxic activity against HeLa (IC50 75.1, 74.2 and 76.5 μM, respectively) and HSC-2 (IC50 69.9, 53.3 and 58.2 μM…

New Austalides from the Sponge-Associated Fungus Aspergillus sp.

2011

Chromatographic separation of a crude extract obtained from the fungus Aspergillus sp., isolated from the Mediterranean sponge Tethya aurantium, yielded five new meroterpenoid metabolites, austalides M–Q (1–5), together with nine known compounds (6–13). The structures of the new compounds were unambiguously elucidated on the basis of extensive 1D and 2D NMR methods and by mass spectral analysis. Furthermore, the absolute configurations of 1 and 4 were determined by time-dependent density functional theory electronic circular dichroism (TDDFT ECD) calculations, allowing the assignment of the absolute configuration of analogous compounds 2, 3, and 5. The calculations revealed that the conform…

Absolute Configurations of Three Naturally Occurring Acetylenic Spiroacetal Enol Ethers

1993

The absolute configurations of three 6,7-oxygenated acetylenic spiroacetal enol ethers were determined by using the kinetic method of Horeau. The results were confirmed by the circular dichroism of the compounds in correlation with the corresponding 6,7-epoxide.

La polis y el polites: orígenes y características de la categoría de ciudadanía | The Polis and the Polites: origins and characteristics of the citiz…

2016

RESUMEN. El autor describe algunos elementos distintivos del estatus y de las funciones del ciudadano en la Atenas del siglo V asi como en el contexto democratico ateniense, en el que nacio la figura del ciudadano. Pone de relieve el caracter excluyente y las instituciones "limitadas" que hacen de la ciudadania un estatus exclusivo, reservado para los hombres, para los hijos de ambos padres atenienses y que de esa manera excluia a los extranjeros residentes (metecos), a los otros griegos y a los barbaros. A partir de la categoria aristotelica de "ciudadano en sentido absoluto", el autor muestra como incluso dentro de la comunidad de los atenienses libres, por varias razones, grupos como el …

A local notion of absolute continuity in IR^n

2005

We consider the notion of p, δ-absolute continuity for functions of several variables introduced in [2] and we investigate the validity of some basic properties that are shared by absolutely continuous functions in the sense of Maly. We introduce the class $δ−BV^p_loc(\Omega,IR^m)$ and we give a characterization of the functions belonging to this class.

A modified applicative criterion of the physical model concept for evaluating plot soil erosion predictions

2015

Abstract In this paper, the physical model concept by Nearing (1998. Catena 32: 15–22) was assessed. Soil loss data collected on plots of different  widths (2–8 m), lengths (11–44 m) and steepnesses (14.9–26.0%), equipped in south and central Italy, were used. Differences in width between plots of given length and steepness determined a lower data correlation and more deviation of the fitted regression line from the identity one. A coefficient of determination between measured, M , and predicted, P , soil losses of 0.77 was representative of the best-case prediction scenario, according to Nearing (1998). The relative differences, Rdiff  = ( P − M ) / ( P + M ), decreased in absolute value a…

Regular subclasses in the Sobolev space

2009

Abstract We study some slight modifications of the class α - A C n ( Ω , R m ) introduced in [D. Bongiorno, Absolutely continuous functions in R n , J. Math. Anal. and Appl. 303 (2005) 119–134]. In particular we prove that the classes α - A C λ n ( Ω , R m ) , 0 λ 1 , introduced in [C. Di Bari, C. Vetro, A remark on absolutely continuous functions in R n , Rend. Circ. Matem. Palermo 55 (2006) 296–304] are independent by λ and contain properly the class α - A C n ( Ω , R m ) . Moreover we prove that α - A C n ( Ω , R m ) = ( α - A C λ n ( Ω , R m ) ) ∩ ( α - A C n , λ ( Ω , R m ) ) , where α - A C n , λ ( Ω , R m ) is the symmetric class of α - A C λ n ( Ω , R m ) , 0 λ 1 .

Normed vector spaces consisting of classes of convex sets

1965

Absolute continuity of mappings with finite geometric distortion

2015

Suppose that ⊂ R n is a domain with n ≥ 2. We show that a continuous, sense-preserving, open and discrete mapping of finite geometric outer distortion with KO(·,f) ∈ L 1/(n 1) loc () is absolutely continuous on almost every line parallel to the coordinate axes. Moreover, if U ⊂ is an open set with N(f,U) 0 depends only on n and on the maximum multiplicity N(f,U).