Search results for "Absolute"

showing 10 items of 518 documents

The ALHAMBRA survey: Discovery of a faint QSO at z = 5.41

2013

[Aims]: We aim to illustrate the potentiality of the Advanced Large, Homogeneous Area, Medium-Band Redshift Astronomical (ALHAMBRA) survey to investigate the high-redshift universe through the detection of quasi stellar objects (QSOs) at redshifts higher than 5. [Methods]: We searched for QSOs candidates at high redshift by fitting an extensive library of spectral energy distributions-including active and non-active galaxy templates, as well as stars-to the photometric database of the ALHAMBRA survey (composed of 20 optical medium-band plus the 3 broad-band JHKs near-infrared filters). [Results]: Our selection over ≈1 square degree of ALHAMBRA data (∼1/4 of the total area covered by the sur…

QSOSAbsolute magnitudeCosmology and Nongalactic Astrophysics (astro-ph.CO)active [Galaxies]Young stellar objectContinuum (design consultancy)FOS: Physical sciencesAstrophysicsAstrophysics::Cosmology and Extragalactic AstrophysicsLuminosityhigh-redshift [Galaxies]emission lines [Quasars]Galaxies: distances and redshiftsdistances and redshifts [Galaxies]Astrophysics::Galaxy AstrophysicsPhysicsQuasars: emission linesGalaxies: high-redshiftGalaxies: evolutiongeneral [Quasars]Astronomy and AstrophysicsGalaxies: activeevolution [Galaxies]RedshiftGalaxyQuasars: generalBlack holeSpace and Planetary ScienceAstrophysics - Cosmology and Nongalactic Astrophysics
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Effective approach for calculations of absolute stability of proteins using focused dielectric constants

2009

The ability to predict the absolute stability of proteins based on their corresponding sequence and structure is a problem of great fundamental and practical importance. In this work, we report an extensive, refinement and validation of our recent approach (Roca et al., FEBS Lett 2007;581:2065-2071) for predicting absolute values of protein stability DeltaG(fold). This approach employs the semimacroscopic protein dipole Langevin dipole method in its linear response approximation version (PDLD/S-LRA) while using the best fitted values of the dielectric constants epsilon'(p) and epsilon'(eff) for the self energy and charge-charge interactions, respectively. The method is validated on a divers…

Quantitative Biology::BiomoleculesWork (thermodynamics)ChemistryThermodynamicsDielectricBiochemistryDipoleProtein stabilityProtein structureStructural BiologyComputational chemistryStatic electricityProtein foldingAbsolute stabilityMolecular BiologyProteins: Structure, Function, and Bioinformatics
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Crystal structure of (1S,2R,4S)-1-[(morpholin-4-yl)methyl]-4-(prop-1-en-2-yl)cyclohexane-1,2-diol

2014

Besides intra­molecular O—H⋯N hydrogen bonds, the crystal structure displays inter­molecular O—H⋯O and C—H⋯O hydrogen bonds linking the mol­ecules into undulating layers parallel to the (01) plane.

Quantitative Biology::Biomoleculescrystal structureCrystallographyHydrogen bondDiolCyclohexane conformationAbsolute configurationGeneral ChemistryCrystal structureCondensed Matter Physicschiral ligand for catalytic enantioselective transformationsResearch CommunicationsHexaneCrystalchemistry.chemical_compoundCrystallographychemistryQD901-999Morpholinehydrogen bondschiral ligand for catalytic enanti­oselective transformationsGeneral Materials SciencePhysics::Chemical Physicsamino-12-diolActa Crystallographica Section E: Crystallographic Communications
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Perthamides C-F, potent human antipsoriatic cyclopeptides

2011

Abstract Two new cyclopeptides, perthamides E and F were isolated from the polar extracts of the sponge Theonella swinhoei . The new structures, featuring an unprecedented β-amino acid unit (AHMOA), were determined by interpretation of NMR and MS data. The absolute configuration of the AHMOA residue was proposed on the basis of quantum chemical calculation of NMR chemical shifts. Perthamides were proved to inhibit TNF-α and IL-8 release in primary human keratinocytes cells and therefore could represent potentially leads for the treatment of psoriasis.

Quantum chemicalchemistry.chemical_classificationTheonella swinhoeiStereochemistryChemical shiftOrganic ChemistryAbsolute configurationTheonella swinhoeicyclopeptidesBiochemistryCombinatorial chemistryCyclic peptideResidue (chemistry)Anti-Inflammatory activitychemistryinflammationDrug DiscoveryMarine compoundsCyclic peptidesmarine natural product
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Transition probabilities for BrII lines emitted from a wall-stabilized cascade arc

2000

Abstract Absolute transition probabilities of the eleven Br II lines were measured in emission. A plasma created in a wall-stabilized arc at atmospheric pressure in the mixture of argon and bromine vapors was used as the excitation source. The relative transition probabilities were converted to an absolute scale based on a lifetime value measured by the electron impact method. The results were compared with experimental data. Discrepancies have been found to be outside the experimental uncertainties.

RadiationArgonMaterials scienceBromineAtmospheric pressurechemistry.chemical_elementPlasmaAtomic and Molecular Physics and OpticsArc (geometry)chemistryAtomic physicsAbsolute scaleSpectroscopyExcitationElectron ionizationJournal of Quantitative Spectroscopy and Radiative Transfer
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Radikalpolymerisation von methylmethacrylat im gesamten umsatzbereich. Stationäre und instationäre experimente zur bestimmung von wachstums- und abbr…

1989

Free-radical polymerization of methyl methacrylate in bulk at 0°C over the full range of conversion is reported. Details for stationary and non-stationary experiments are described allowing to measure both kinetically relevant ratios fk/ka and kw/ka, f representing radical efficiency, kw rate constants of propagation and ka rate constant of termination. From these ratios the absolute rate constants kw and ka are available. The photochemical decay of the initiator 1,1′-azodicyclohexanenitrile in connection with the rotating-sector technique and observation of the post-effect after stopping the initiator decay were used. The rate of polymerization and the number- and weight-average molar mass…

Reaction ratechemistry.chemical_compoundMolar massReaction rate constantBulk polymerizationPolymerizationChemistryRadical polymerizationPolymer chemistryAbsolute rateMethyl methacrylateDie Makromolekulare Chemie
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Monitoring Stemness in Long-Term hESC Cultures by Real-Time PCR

2009

Human embryonic stem cells (hESC) involve long-term cultures that must remain undifferentiated. The real-time PCR (RT-PCR) technique allows the relative quantification of target genes, including undifferentiation and differentiation markers when referred to a housekeeping control with the addition of a calibrator that serves as an internal control to compare different lots of reactions during the time. The main aspects will include a minimal number of cells to be analyzed, genes to be tested, and how to choose the appropriate calibrator sample and the reference gene. In this chapter, we present how to apply the RT-PCR technique, protocols for its performance, experimental set-up and softwar…

Real-time polymerase chain reactionCell cultureAbsolute quantificationGene expressionReference geneBase sequenceComputational biologyBiologyBioinformaticsGeneEmbryonic stem cell
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Comparing Recurrent Neural Networks using Principal Component Analysis for Electrical Load Predictions

2021

Electrical demand forecasting is essential for power generation capacity planning and integrating environment-friendly energy sources. In addition, load predictions will help in developing demand-side management in coordination with renewable power generation. Meteorological conditions influence urban area load pattern; therefore, it is vital to include weather parameters for load predictions. Machine Learning algorithms can effectively be used for electrical load predictions considering impact of external parameters. This paper explores and compares the basic Recurrent Neural Networks (RNN); Simple Recurrent Neural Networks (Vanilla RNN), Gated Recurrent Units (GRU), and Long Short-Term Me…

Recurrent neural networkCapacity planningMean absolute percentage errorElectrical loadArtificial neural networkComputer sciencePrincipal component analysisData miningDemand forecastingEnergy sourcecomputer.software_genrecomputer2021 6th International Conference on Smart and Sustainable Technologies (SpliTech)
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Energy-weighted M1 sum rule with explicit δ degrees of freedom

1985

Abstract The influence of Δ degrees of freedom on the energy-weighted M1 sum rule is investigated and applied to 2 H and 4 He. Using π- and ρ-exchange potentials a reduction of the potential contribution of the order of 50% is obtained. The absolute value of the sum rule is strongly dependent on the short-range behaviour of the nuclear wave function. Furthermore, the contribution of c.m. effects is evaluated and found to be of the order of 5–10%.

Reduction (complexity)PhysicsNuclear and High Energy PhysicsLinearity of differentiationRule of sumDegrees of freedomMathematical analysisOrder (group theory)Sum rule in quantum mechanicsAbsolute value (algebra)Wave functionNuclear Physics A
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A cardiovascular educational intervention for primary care professionals in Spain: positive impact in a quasi-experimental study

2015

Background Routine general practice data collection can help identify patients at risk of cardiovascular disease. Aim To determine whether a training programme for primary care professionals improves the recording of cardiovascular disease risk factors in electronic health records. Design and setting A quasi-experimental study without random assignment of professionals. This was an educational intervention study, consisting of an online-classroom 1-year training programme, and carried out in the Valencian community in Spain. Method The prevalence rates of recording of cardiovascular factors (recorded every 6 months over a 4-year period) were compared between intervention and control group. …

Relative risk reductionMalePediatricsmedicine.medical_specialtyEducation ContinuingInservice TrainingCardiologyRisk AssessmentDiabetes mellitushealth educationMedicineElectronic Health RecordsHumansprevention and controlPrimary Health Carebusiness.industryRandom assignmentResearchAbsolute risk reductionregistriesMiddle Agedmedicine.diseaseQuality ImprovementConfidence intervalcardiovascular diseasesBlood pressureBasal (medicine)Cardiovascular DiseasesSpainFemaleEducational MeasurementFamily PracticeRisk assessmentbusiness
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