Search results for "Absorption"
showing 10 items of 2701 documents
Apparent absorption of solar spectral irradiance in heterogeneous ice clouds
2010
[1] Coordinated flight legs of two aircraft above and below extended ice clouds played an important role in the Tropical Composition, Cloud and Climate Coupling Experiment (Costa Rica, 2007). The Solar Spectral Flux Radiometer measured up- and downward irradiance on the high-altitude (ER-2) and the low-altitude (DC-8) aircraft, which allowed deriving apparent absorption on a point-by-point basis along the flight track. Apparent absorption is the vertical divergence of irradiance, calculated from the difference of net flux at the top and bottom of a cloud. While this is the only practical method of deriving absorption from aircraft radiation measurements, it differs from true absorption when…
Early detection of volcanic hazard by lidar measurement of carbon dioxide
2016
Volcanic gases give information on magmatic processes. In particular, anomalous releases of carbon dioxide precede volcanic eruptions. Up to now, this gas has been measured in volcanic plumes with conventional measurements that imply the severe risks of local sampling and can last many hours. For these reasons and for the great advantages of laser sensing, the thorough development of volcanic lidars has been undertaken at ENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development). In fact, lidar profiling allows one to scan remotely volcanic plumes in a fast and continuous way, and with high spatial and temporal resolution. A differential absorption lid…
Gas emission strength and evolution of the molar ratio of BrO/SO2in the plume of Nyiragongo in comparison to Etna
2015
Airborne and ground-based differential optical absorption spectroscopy observations have been carried out at the volcano Nyiragongo (Democratic Republic of Congo) to measure SO2 and bromine monoxide (BrO) in the plume in March 2004 and June 2007, respectively. Additionally filter pack and multicomponent gas analyzer system (Multi-GAS) measurements were carried out in June 2007. Our measurements provide valuable information on the chemical composition of the volcanic plume emitted from the lava lake of Nyiragongo. The main interest of this study has been to investigate for the first time the bromine emission flux of Nyiragongo (a rift volcano) and the BrO formation in its volcanic plume. Mea…
Reactive halogen chemistry in volcanic plumes
2007
[1] Bromine monoxide (BrO) and sulphur dioxide (SO2) abundances as a function of the distance from the source were measured by ground-based scattered light Multiaxis Differential Optical Absorption Spectroscopy (MAX-DOAS) in the volcanic plumes of Mt. Etna on Sicily, Italy, in August–October 2004 and May 2005 and Villarica in Chile in November 2004. BrO and SO2 spatial distributions in a cross section of Mt. Etna's plume were also determined by Imaging DOAS. We observed an increase in the BrO/SO2 ratio in the plume from below the detection limit near the vent to about 4.5 × 10−4 at 19 km (Mt. Etna) and to about 1.3 × 10−4 at 3 km (Villarica) distance, respectively. Additional attempts were …
Application of aerosol optical properties to estimate aerosol type from ground-based remote sensing observation at urban area of northeastern China
2015
Abstract Aerosol optical properties were derived from ground-based sunphotometer observations between 2009-2013 at three urban sites of Shenyang, Anshan, Fushun in northeastern China. The annual means for extinction aerosol optical depths (EAOD) at 500 nm were 0.57±0.38, 0.52±0.35, and 0.41±0.31 at Shenyang, Anshan, Fushun, respectively. The corresponding annual means for the extinction Angstrom exponents (EAE) computed for the wavelengths of 440 and 870 nm were 0.86±0.32, 0.86±0.34 and 0.91±0.35, respectively, indicating that urban area of Northeast China were affected by both coarse and fine particles. Hygroscopic growth in summer and incursions of dust aerosols in spring were evidently r…
Saharan dust absorption and refractive index from aircraft-based observations during SAMUM 2006
2009
During the Saharan Mineral Dust Experiment (SAMUM) conducted in summer 2006 in southeast Morocco, the complex refractive index of desert dust was determined from airborne measurements of particle size distributions and aerosol absorption coefficients at three different wavelengths in the blue (467 nm), green (530 nm) and red (660 nm) spectral regions. The vertical structure of the dust layers was analysed by an airborne high spectral resolution lidar (HSRL). The origin of the investigated dust layers was estimated from trajectory analyses, combined with Meteosat 2nd Generation (MSG) scenes and wind field data analyses. The real part n of the dust refractive index was found almost constant w…
Temperature and Emissivity Separation From MSG/SEVIRI Data
2014
In this paper, we analyze the feasibility of applying the temperature and emissivity separation (TES) algorithm to thermal-infrared data acquired with three bands of the Spinning Enhanced Visible and Infrared Imager (SEVIRI) onboard the Meteosat Second Generation platform (SEVTES). The performance of the SEVTES algorithm was tested using data simulated over different atmospheric conditions and surface emissivities, with errors around 1.5% for emissivity and 1.5 K for temperature when atmospheric correction is accurate enough. In contrast, errors on land-leaving radiances higher than 2% or uncertainties on total atmospheric water vapor amount higher than 5% lead to errors on emissivity highe…
First-principles nonequilibrium Green's-function approach to transient photoabsorption: Application to atoms
2015
We put forward a first-principle NonEquilibrium Green's Function (NEGF) approach to calculate the transient photoabsorption spectrum of optically thin samples. The method can deal with pump fields of arbitrary strength, frequency and duration as well as for overlapping and nonoverlapping pump and probe pulses. The electron-electron repulsion is accounted for by the correlation self-energy, and the resulting numerical scheme deals with matrices that scale quadratically with the system size. Two recent experiments, the first on helium and the second on krypton, are addressed. For the first experiment we explain the bending of the Autler-Townes absorption peaks with increasing the pump-probe d…
Ca impurity in small mixed He-4-He-3 clusters
2009
The structure of small mixed helium clusters doped with one calcium atom has been determined within the diffusion Monte Carlo framework. The results show that the calcium atom sits at the He-4-He-3 interface. This is in agreement with previous studies, both experimental and theoretical, performed for large clusters. A comparison between the results obtained for the largest cluster we have considered for each isotope shows a clear tendency of the Ca atom to reside in a deep dimple at the surface of the cluster for He-4 clusters, and to become fully solvated for He-3 clusters. We have calculated the absorption spectrum of Ca around the 4s4p <- 4s(2) transition and have found that it is bluesh…
Metal-support and preparation influence on the structural and electronic properties of gold catalysts
2006
Abstract Nanostructured gold catalysts supported on CeO2 and SiO2 were prepared by the deposition–precipitation (DP) and the solvated metal atom dispersion (SMAD) techniques. The structural and electronic properties of the catalysts were investigated by X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS). Gold was found as small metal nanoparticles (cluster size ∼2 nm) in the SMAD-prepared samples and in ionic state in the DP catalysts. The catalytic activity of the samples was tested in the reaction of low temperature CO oxidation. Gold nanosized particles in a pure metallic state exhibited a worse catalytic performance, both on ceria and…