Search results for "Acicular"
showing 10 items of 10 documents
Eleocharis bonariensis Nees en el suroccidente europeo : distribución y diferencias frente a Eleocharis acicularis (L.) Roemer & Schultes
1995
Se hace un estudio comparativo entre los caracteres morfológicos de Eleocharis bonariensis Nees y Eleocharis acicularis (L.) Roemer & Schultes. Así mismo, se indica el área de distribución en Europa del primero, aportando nuevas citas en la vertiente mediterránea. A comparison between the morphological characters of Eleocharis bonariensis Nees and Eleocharis acicularis (L.) Roemer & Schultes is reported. The distribution of Eleocharis binariensis Nees in Southwestern Europe is comented, pointing out new records of this species for the Mediterranean area. Pilar.Soriano@uv.es
Thermal stability of transition alumina nanocrystals with different microstructures
2018
Abstract The preparation of well-crystallized boehmite nanoparticles with different morphologies, encompassing from aciculae or rods of 320, 150 and 70 nm of length to platelets of 50 nm in diameter, allowed a comparative study of their respective thermal evolutions as alumina precursors. Static thermal treatments of boehmite nanocrystals at 600, 1000 and 1200 °C and a dynamic, in situ synchrotron study between 100 and 1000 °C revealed that original boehmite microstructures, i.e. size and shape of the nanoparticles, were kept not only in γ-Al 2 O 3 but also in transitional aluminas up to 1000 °C. Specifically, at that temperature, acicular samples presented θ-Al 2 O 3 structure, while in pl…
The Bi sulfates from the Alfenza Mine, Crodo, Italy: An automatic electron diffraction tomography (ADT) study
2014
We report about three bismuth sulfates from mineralized quartz dikes from Alfenza (Crodo, Italy), two new phases and a rare mineral, cannonite, all growing on bismuthinite. The first new phase occurs as white, "hortensia-like" aggregates of pseudo-hexagonal platelets, with perfect basal cleavage, similar to 20 mu m wide and few micrometers thick. The approximate composition is Bi2O2(SO4), and cell parameters and symmetry, as determined by automatic diffraction tomography, are a = 22.0(4), b = 16.7(3), c = 15.9(3) angstrom, beta = 102.9(5)degrees, space group Pc or P2/c. A major stacking disorder is detected by HR-SEM images and electron diffraction data.The second new phase was detected onl…
Mechanism of crystallization of fast fired mullite-based glass–ceramic glazes for floor-tiles
2006
Abstract The mechanism of crystallization from a B 2 O 3 -containing glass, with composition based in the CaO–MgO–Al 2 O 3 –SiO 2 system, to a glass–ceramic glaze was studied by different techniques. Glass powder pellets were fast heated, simulating current industrial tile processing methods, at several temperatures from 700 to 1200 °C with a 5 min hold. Microstructural study by field emission scanning electron microscopy revealed that a phase separation phenomenon occurred in the glass, which promoted the onset of mullite crystallization at 900 °C. The amount of mullite in the glass heated between 1100 and 1200 °C was around 20 wt%, as determined by Rietveld refinement. The microstructure …
Effect of boron oxide on the microstructure of mullite-based glass-ceramic glazes for floor-tiles in the CaO–MgO–Al2O3–SiO2 system
2006
Abstract The effect of increasing replacement of Al2O3 by B2O3 in a parent glass on the sintering and further crystallization of mullite was investigated. The composition of the parent glass was chosen in the mullite primary phase field of the CaO–MgO–Al2O3–SiO2 quaternary system. Glass powder pellets were heated under standard (10 °C/min and 2 h of hold time) and fast heatings (25 °C/min and 5 min of hold time) at different temperatures from 700 to 1190 °C. Sintering of B2O3-containing glasses took place in the range between 850 and 1050 °C. X-ray diffraction results showed that mullite formed as unique crystalline phase for glasses containing amounts of B2O3 larger than 6 wt%. For lower a…
Ferro-pedrizite, NaLi2(Fe2+ 2Al2Li)Si8O22(OH)2, a new amphibole-supergroup mineral from the Sutlug pegmatite, Tyva Republic, Russia
2015
Ferro-pedrizite, a new amphibole-supergroup mineral was discovered in the Sutlug pegmatite occurrence situated in the Targi River Basin, Tyva Republic, Eastern Sibera, Russia. The associated minerals are quartz, albite, microcline, spodumene, cassiterite, beryl, columbite-(Mn), fergusonite-β-(Y), fluorapatite, schorl, trilithionite and fluorite. Ferro-pedrizite forms dark grey-blue to violet-blue acicular and long prismatic crystals up to 2 × 5 × 50 mm and their aggregates. D meas = 3.16(1) g/cm3 (by hydrostatic weighing), 3.13(1) g/cm3 (by flotation in heavy liquids); D calc = 3.135 g/cm3. Ferro-pedrizite is optically biaxial (−), α = 1.614(3), β = 1.638(3), γ = 1.653(3), 2 V meas = 75(5)°…
Crystal fabrics and element impurities (Sr/Ca, Mg/Ca, and Ba/Ca) in shells of Arctica islandica—Implications for paleoclimate reconstructions
2013
Sr/Ca, Mg/Ca and Ba/Ca values are heterogeneously distributed in shells of Arctica islandica. These patterns are largely associated with crystal fabrics (size, habit and orientation of crystals) or the processes controlling them. The outer sublayer of the outer shell layer (oOSL; homogenous and irregular simple prismatic crystal fabrics,) contained element/Ca values up to 62% higher than the inner sublayer (iOSL; crossed-acicular, crossed-lamellar, fine crossed-lamellar and irregular simple prismatic crystal fabrics). A gradual decrease in Sr/Ca and Mg/Ca values was observed from the outer portions of the oOSL toward the oOSL/iOSL transition zone. This chemical shift was accompanied by a gr…
Assessment of the mechanism of elemental incorporation into bivalve shells (Arctica islandica) based on elemental distribution at the microstructural…
2014
Abstract To address the mechanism of elemental incorporation into shells of the bivalve Arctica islandica , we performed two-dimensional elemental mapping of Sr, Mg, and S at a ∼3 μm spatial resolution using electron microprobe. These elemental distributions were precisely compared to the shell microstructure. The Sr distribution was intimately linked to the S concentration and/or shell microstructure. Sr showed a clear annual pattern with higher values at the annual growth lines and lower values in annual growth increments. The Sr and S concentrations were higher near sub-annual growth lines than in the adjacent regions, which were dominated by acicular microstructure (middle shell layer) …
Spherulites in Calcrete Laminar Crusts: Biogenic CACO3 Precipitation as a Major Contributor to Crust Formation
1995
ABSTRACT Spherulites (calcitic fibro-radial spherulitic polycrystals) are a major component of calcite layers in Quaternary calcrete laminar crusts. To explain the formation of spherulites, petrographic and chemical studies were performed on Pleistocene calcrete laminar crusts, Holocene biological crusts, and laboratory (in vitro) cultures of cyanobacterial strains. Spherulites were found to be formed of acicular and radiating crystals, either smooth and regular-edged, or twisted and irregular-edged. Spherulites were composed of low-Mg calcite, the concentration of Mg in the spherulites increasing from nucleus to periphery. The shape and chemistry of the in vitro spherulites and laminar cru…
Morphological Control of Hydrothermal Ni(OH)2 in the Presence of Polymers and Surfactants: Nanocrystals, Mesocrystals, and Superstructures
2008
International audience; Polymers with different hydrophilic groups [polyvinylpyrrolidone (PVP), ammonium polyacrylate (APA), and hydroxypropylmethyl cellulose (HPMC)] and surfactants [cetyltrimethylammonium bromide (CTAB) and sodium dodecylbenzensulfonate (SDBS)] were used as additives to modify the crystallization of β-Ni(OH)2 in hydrothermal conditions. Marked morphological changes in the β-Ni(OH)2 particles were observed depending on the additive concentration and on the duration of the hydrothermal treatment. The final morphology is the result of a complex, time-dependent self-assembly and growth process. Well-defined particles with sizes from submicrometer range to a few micrometers co…