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showing 10 items of 2898 documents

Synthesis, NMR spectral and structural studies on mixed ligand complexes of Pd(II) dithiocarbamates: First structural report on palladium(II) dithioc…

2016

Abstract Three new mixed ligand complexes of palladium(II) dithiocarbamates; [Pd(4-dpmpzdtc)(PPh3)(SCN)] (1), [Pd(4-dpmpzdtc)(PPh3)Cl] (2) and [Pd(bzbudtc)(PPh3)Cl] (3), (where, 4-dpmpzdtc = 4-(diphenylmethyl)piperazinecarbodithioato anion, bzbudtc = N-benzyl-N-butyldithiocarbamato anion and PPh3 = triphenylphosphine) have been synthesized from their respective parent dithiocarbamates by ligand exchange reactions and characterized by IR and NMR (1H, 13C and 31P) spectroscopy. IR and NMR spectral data support the isobidentate coordination of the dithiocarbamate ligands in all complexes (1–3) in solid and in solution, respectively. Single crystal diffraction analysis of complexes 1–3 evidence…

palladium(II)synthesisStereochemistrychemistry.chemical_element010402 general chemistry01 natural sciencesSingle Crystal DiffractionAnalytical ChemistryIonInorganic Chemistryligand exchange reactionsDithiocarbamateSpectral dataSpectroscopyta116Spectroscopysingle crystal X-ray diffractionchemistry.chemical_classification010405 organic chemistryChemistryLigandOrganic ChemistryMixed ligandNMR0104 chemical sciencesCrystallographyPalladiumJournal of Molecular Structure
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Evolutionary Dynamics of Pathoadaptation Revealed by Three Independent Acquisitions of the VirB/D4 Type IV Secretion System in Bartonella

2017

The α-proteobacterial genus Bartonella comprises a group of ubiquitous mammalian pathogens that are studied as a model for the evolution of bacterial pathogenesis. Vast abundance of two particular phylogenetic lineages of Bartonella had been linked to enhanced host adaptability enabled by lineage-specific acquisition of a VirB/D4 type IV secretion system (T4SS) and parallel evolution of complex effector repertoires. However, the limited availability of genome sequences from one of those lineages as well as other, remote branches of Bartonella has so far hampered comprehensive understanding of how the VirB/D4 T4SS and its effectors called Beps have shaped Bartonella evolution. Here, we repor…

parallel evolution0301 basic medicineBartonellaAMPylation; bacterial effector; filamentation induced by cAMP; parallel evolutionVirulence FactorsIn silico030106 microbiologyBiologyfilamentation induced by cAMPGenomeEvolution MolecularType IV Secretion Systems03 medical and health sciencesBacterial ProteinsBartonella InfectionsGeneticsAMPylationHumansEvolutionary dynamicsBacterial Secretion SystemsPhylogenyEcology Evolution Behavior and SystematicsPhylogenetic treeEffectorbiology.organism_classificationbacterial effectorVirology030104 developmental biologyEvolutionary biologyFilamentation induced by cAMP; AMPylation; Parallel evolution; Bacterial effectorHost-Pathogen InteractionsParallel evolutionAdaptationBartonellaResearch Article
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Predictions of exclusive $\Upsilon$ photoproduction at the LHC and future colliders

2022

The cross section for exclusive $\Upsilon$ ultraperipheral photoproduction at present and future colliders is determined using the low $x$ gluon PDF extracted from an analysis of exclusive $J/\psi$ measurements performed at HERA and the LHC. Predictions are given at next-to-leading order in collinear factorisation over a wide $\gamma p$ centre-of-mass energy range, calculated assuming the non-relativistic approximation for the $\Upsilon$ wave function, and with skewing corrections incorporated.

particle interactionsHigh Energy Physics - PhenomenologyHigh Energy Physics::PhenomenologyNuclear Theoryquantum chromodynamicskvanttiväridynamiikkaHigh Energy Physics::ExperimenthiukkasfysiikkaNuclear Experiment114 Physical sciences
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Open-source QCD analysis of nuclear parton distribution functions at NLO and NNLO

2019

We present new sets of nuclear parton distribution functions (nPDFs) at next-to-leading order (NLO) and next-to-next-to-leading order (NNLO). Our analyses are based on deeply inelastic scattering data with charged-lepton and neutrino beams on nuclear targets. In addition, a set of proton baseline PDFs is fitted within the same framework with the same theoretical assumptions. The results of this global QCD analysis are compared to existing nPDF sets and to the fitted cross sections. Also, the uncertainties resulting from the limited constraining power of the included experimental data are presented. The published work is based on an open-source tool, xFitter, which has been modified to be ap…

particle interactionsParticle physicsHEAVY FLAVOR PRODUCTIONProtonPREDICTIONSFOS: Physical sciencesPartonhiukkasfysiikkaInelastic scatteringPROTON114 Physical sciences01 natural sciencesUNCERTAINTIESnucleus-neutrino interactionsCROSS-SECTIONSSet (abstract data type)High Energy Physics - Phenomenology (hep-ph)DEPENDENCEquantum chromodynamics0103 physical sciencesnonperturbative effects in field theory010306 general physicsNuclear Experimentquantum field theoryperturbation theoryDEEP-INELASTIC-SCATTERINGQuantum chromodynamicsPhysics010308 nuclear & particles physics3-LOOP SPLITTING FUNCTIONSnucleon distributionSTRUCTURE-FUNCTION RATIOSDeep inelastic scatteringEVOLUTIONHigh Energy Physics - PhenomenologyDistribution functionQCD in nuclear reactionsnuclear matterHigh Energy Physics::ExperimentNeutrinoydinfysiikka
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Next-to-leading order Balitsky-Kovchegov equation beyond large Nc

2020

We calculate finite-Nc corrections to the next-to-leading order (NLO) Balitsky-Kovchegov (BK) equation. We find analytical expressions for the necessary correlators of six Wilson lines in terms of the two-point function using the Gaussian approximation. In a suitable basis, the problem reduces from the diagonalization of a six-by-six matrix to the diagonalization of a three-by-three matrix, which can easily be done analytically. We study numerically the effects of these finite-Nc corrections on the NLO BK equation. In general, we find that the finite-Nc corrections are smaller than the expected 1/N2c∼10%. The corrections may be large for individual correlators, but have less of an influence…

particle interactionsstrong interactionquantum chromodynamicshiukkasfysiikka
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Predictors of long-term outcomes in patients undergoing periodontal maintenance

2017

Abstract Aim This retrospective study aimed to characterize the baseline status of patients following periodontal maintenance, analysing the association between the long‐term outcome of these patients, smoking, bruxism, and the main clinical and radiographic variables. Material and methods A sample of 174 patients with moderate to severe periodontitis was refined into homogeneous subsamples according to smoking and bruxism and the rate of tooth loss due to periodontal disease (TLPD): 0, 1–2, and >2 teeth. The association and the distribution (χ² test) of the variables within the subsamples were analysed. Results Smoking and bruxism were significantly associated with higher TLPD rates. Verti…

periodontal prognosisabfractionsperiodontal diseaseDentistryCase Report or Case SeriesPeriodontal Therapy03 medical and health sciences0302 clinical medicinePeriodontal diseasetooth lossmedicineTooth lossIn patientPeriodontal maintenancePeriodontitisbruxismbusiness.industryFurcation defectRetrospective cohort study030206 dentistrymedicine.diseasestomatognathic diseases030220 oncology & carcinogenesisPredictive value of testsPeriodonticsmedicine.symptombusinessJournal of Clinical Periodontology
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THE ROLE OF THE CLINICAL PHARMACIST IN THE MANAGEMENT OF ANTIRETROVIRAL THERAPY

2020

Over the last few years, the Hospital Pharmacy has developed in an excellent way in Europe, proposing in many countries the clinical pharmacist as a new professional figure, and adapting its responsibilities to national health systems. The purpose of this study is to evaluate and promote the prescriptive appropriateness through the close collaboration between the pharmacist and the medical team. The aspect of the dispensation of antiretroviral therapy was deepened by providing useful information to the patient on the possible undesired effects and interactions due to the polypharmacy, on the correct way of storing the drugs, and on the importance of the regularity of the polypharmacy intake…

pharmacovigilanceinteraction of antiretroviral drugsADRs (adverse drug reactions)Settore CHIM/08 - Chimica Farmaceuticaclinical pharmacistdrug therapy appropriateness
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Majorana parameters of the interacting boson model of nuclear structure and their implication for 0νββ decay

2021

photonuclear reactionsnuclear spinelectromagnetic transitionsparitylifetimeswidthscollective modelspesonance reactionsneutrinoless double beta decay
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Nucleon dissociation and incoherent J/ψ photoproduction on nuclei in ion ultraperipheral collisions at the CERN Large Hadron Collider

2019

Using the general notion of cross section fluctuations in hadron-nucleus scattering at high energies, we derive an expression for the cross section of incoherent J / ψ photoproduction on heavy nuclei d σ γ A → J / ψ Y / d t , which includes both elastic d σ γ p → J / ψ p / d t and proton-dissociation d σ γ p → J / ψ Y / d t photoproduction on target nucleons. We find that, with good accuracy, d σ γ A → J / ψ Y / d t can be expressed as a product of the sum of the d σ γ p → J / ψ p / d t and d σ γ p → J / ψ Y / d t cross sections, which have been measured at HERA, and the common nuclear shadowing factor, which is calculated using the leading twist nuclear shadowing model. Our prediction for …

photonuclear reactionsphoton lepton and quark productionQCD in nuclear reactionshiukkasfysiikkaydinfysiikkarelativistic heavy-ion collisions
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Shell-model computed cross sections for charged-current scattering of astrophysical neutrinos off 40Ar

2018

Charged-current (anti)neutrino- 40 Ar cross sections for astrophysical neutrinos have been calculated. The initial and final nuclear states were calculated using the nuclear shell model. The folded solar-neutrino scattering cross section was found to be 1.78 ( 23 ) × 10 − 42 cm 2 , which is higher than what the previous papers have reported. The contributions from the 1 − and 2 − multipoles were found to be significant at supernova-neutrino energies, confirming the random-phase approximation (RPA) result of a previous study. The effects of neutrino flavor conversions in dense stellar matter (matter oscillations) were found to enhance the neutrino-scattering cross sections significantly for …

pimeä ainesolar neutrinosshell modelneutriinotHigh Energy Physics::Experimentpimeä energiaauringonsäteilynucleus-neutrino interactions
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