Search results for "Alum"

Properties of native ultrathin aluminium oxide tunnel barriers

2003

We have investigated planar metal–insulator–metal tunnel junctions with aluminium oxide as the dielectricum. These oxide barriers were grown on an aluminium electrode in pure oxygen at room temperature till saturation. By applying the Simmons model we derived discrete widths of the tunnelling barrier, separated by Δs ≈ 0.38 nm. This corresponds to the addition of single layers of oxygen atoms. The minimum thickness of s0 ≈ 0.54 nm is then due to a double layer of oxygen. We found a strong and systematic dependence of the barrier height on the barrier thickness. Breakdown fields up to 5 GV m−1 were reached. They decreased strongly with increasing barrier thickness. Electrical breakdown could…

Cu–Cu interactions in the transparent p-type conductors: CuAlO2 and SrCu2O2

2003

Abstract Electronic structures of the p-type Transparent Conducting Oxides (TCO): CuAlO2 and SrCu2O2 are calculated using the Tight Binding Linearized Muffin Tin Orbital within the Atomic Sphere Approximation method (TB-LMTO-ASA). The band structures indicate two gaps for CuAlO2 (an indirect one with ΔE≈0.45 eV and a direct one with ΔE≈1.25 eV) and one direct gap for SrCu2O2 (with ΔE≈2 eV). In both oxides the Cu states are dominant at the top of the valence band, close to the Fermi level and the existence of weak Cu–Cu bonding interactions is revealed through the Integrated Crystal Orbital Hamiltonian Population (ICOHP). The presence of such interactions suggests that for the hole doped oxi…

On the nature of phase separation in a commercial aluminium-lithium alloy

1996

Abstract The formation of lithium-rich precipitate particles, known as δ′ phase, is responsible for the particularly desirable mechanical properties which make aluminium-lithium alloys interesting for different industrial applications. The structure and the kinetics of the phase separation process are conveniently studied by small-angle X-ray scattering, though uncertainties remain on the actual shape of the phase diagram of the system, particularly in the region of interest. In this paper are reported small-angle X-ray scattering measurements on a commercial AlLi (8.49% Li atoms) both in the region of formation of the precipitate and during its successive growth. Modelling of the experime…

Characterization of friction stir consolidated recycled billet by uniaxial compression tests with miniaturized cylindrical specimen

2023

Abstract. Friction stir consolidation (FSC) is a solid-state recycling method that directly converts machining scraps into semifinished billets. This process has been proven to be a more energy efficient and environmentally friendly technique compared to remelting based conventional recycling methods. During FSC, machining chips are transformed into a solid billet by the stirring action and friction heat of the rotating tool. Due to process mechanics, especially temperature gradient and strain rate, billets have shown different hardness values and grain size distribution across their sections. Therefore, in this research, miniaturized upsetting samples are extracted from the FSC billet. The…

Fabrication of Billet from Aluminum Alloys AA 2011-T3/7075 Chips through Friction Stir Consolidation

2022

Recently evolving Solid-State Recycling (SSR) techniques have shown promising features to recycle metals scraps more efficiently compared to remelting-based approaches. Among these SSR methods, Friction Stir Consolidation (FSC) has been successfully tested to transform metals chips directly into semi or final solid products. Therefore, researchers explored FSC critical process parameters and their subsequent effects on quality in terms of the mechanical and metallurgical properties of the billet. All the previous studies of FSC were limited to developing billet of mono materials. Therefore, in this research, an attempt was made to go beyond the idea of recycling; in fact, a billet of two di…

The Effect of Electronic Properties of Anodized and Hard Anodized Ti and Ti6Al4V on Their Reactivity in Simulated Body Fluid

2022

The electronic properties of barrier and porous layers on Ti and Ti6Al4V were studied. Barrier anodic oxides grown to 40 V on Ti and on Ti6Al4V are both n-type semiconductors with a band gap of 3.3 eV and 3.4 eV respectively, in agreement with the formation of amorphous TiO2. Anodizing to 200 V at 20 mA cm−2 in calcium acetate and β-glycerol phosphate disodium pentahydrate leads to the formation of Ca and P containing porous films with a photoelectrochemical behaviour dependent on the metallic substrate. A band gap of 3.2 eV and the flat band potential of −0.5 V vs Ag/AgCl were measured for the porous oxide on Ti, while optical transitions at 2.15 eV and a significantly more positive flat b…

Friction based solid state welding techniques for transportation industry applications

2014

Life Cycle Assessment of aluminum alloys chips recycling through single and multi-step Friction Stir Consolidation processes

2023

Manufacturing scientists have to find new processes enabling energy and resource efficient circular economy strategies. Solid state recycling processes have proved to be environmentally friendly alternatives to recycle aluminum alloys process scraps like chips. In this paper the environmental characterization of a solid state recycling process named Friction Stir Consolidation (FSC) is presented. A full Life Cycle Assessment (LCA) comparative analysis is developed: the environmental performance of new and different variants of FSC processes and remelting based routes are quantified and compared to one another. Also, different scenarios are analysed to provide guidelines for the correct impl…

Qualitative-portable to quantitative-laboratory LIBS

2012

No abstract

Influence of Joint Geometry on Micro and Macro Mechanical Properties of Friction Stir Spot Welded Joints

2014

AbstractSpot welding can be considered a very common joining technique in automotive and transportation industries as it permits to obtain effective lap-joints with short process times and what is more it is easily developed through robots and automated systems. Recently, Friction Stir Spot Welding (FSSW) has been proposed as a natural evolution of the already known Friction Stir Welding (FSW) process, allowing to obtain sound spot joints that do not suffer from the insurgence of typical welding defects due to the melting of the base material. Similarly to FSW, both geometrical and technological parameters must be considered as they affect the material flow and the heat flux generated durin…