Search results for "Alum"

showing 10 items of 1303 documents

Reaktionen an Aluminiumoxiden. 3. Mitt.: Umsetzungen von Propanal und Benzaldehyd an Aluminiumoxid

1973

Die Umsetzungen von Propanal und Benzaldehyd an verschiedenen Aluminiumoxiden wurden bei unterschiedlichen Bedingungen untersucht. Die dabei entstandenen Stoffe wurden durch Vergleichssubstanzen mit Hilfe der DC und GC nachgewiesen. Reactions on Alumina Oxides The reactions of propanal and benzaldehyde on various alumina oxides were investigated under different conditions. The resulting products were identified by synthesized compounds and TLC and GLC.

Benzaldehydechemistry.chemical_compoundChemistryAluminiumDrug DiscoveryPolymer chemistryPharmaceutical Sciencechemistry.chemical_elementAluminum oxideArchiv der Pharmazie
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Influence of a bioceramic root end material and mineral trioxide aggregates on fibroblasts and osteoblasts

2012

The biocompatibility of materials used in endodontic treatment is of high importance, because they can come in contact with periradicular tissues and there is a risk of possible systemic toxicity. The aim of the present study was to investigate the in vitro reaction to a bioceramic based root end material in comparison to mineral trioxide aggregates (MTA) as the established gold standard.The root end materials grey MTA Angelus (GMTA), white MTA Angelus (WMTA), ProRoot MTA, and EndoSequence Root Repair Material (ERRM) were incubated with human periodontal ligament fibroblasts and osteoblasts (10(4)cells/ml) for up to 96h. Cell proliferation (RFU) was determined by means of the Alamar Blue as…

BiocompatibilityPeriodontal LigamentCell Culture TechniquesDentistryBiocompatible MaterialsBioceramicRoot Canal Filling Materialschemistry.chemical_compoundHumansAluminum CompoundsGeneral DentistryCell ProliferationOsteoblastsbusiness.industrySilicatesOxidesCell BiologyGeneral MedicineCalcium CompoundsFibroblastsDrug CombinationsPeriradicularSystemic toxicityOtorhinolaryngologychemistryBiological AssaybusinessTrioxideArchives of Oral Biology
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Molecular Dynamics Simulations of the Initial Adsorption Stages of Fibrinogen on Mica and Graphite Surfaces.

2015

Fibrinogen, a blood glycoprotein of vertebrates, plays an essential role in blood clotting by polymerizing into fibrin when activated. Upon adsorption on material surfaces, it also contributes to determine their biocompatibility and has been implicated in the onset of thrombosis and inflammation at medical implants. Here we present the first fully atomistic simulations of the initial stages of the adsorption process of fibrinogen on mica and graphite surfaces. The simulations reveal a weak adsorption on mica that allows frequent desorption and reorientation events. This adsorption is driven by electrostatic interactions between the protein and the silicate surface as well as the counterion …

BiocompatibilityProtein ConformationSurface PropertiesStatic ElectricityNanotechnologyMolecular Dynamics SimulationAdsorptionDesorptionElectrochemistryGeneral Materials ScienceDenaturation (biochemistry)GraphiteSpectroscopychemistry.chemical_classificationFibrinogenSurfaces and InterfacesCondensed Matter PhysicschemistryChemical engineeringAluminum SilicatesGraphiteMicaAdsorptionCounterionHydrophobic and Hydrophilic InteractionsProtein adsorptionLangmuir : the ACS journal of surfaces and colloids
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Crystalline microstructure of boehmites studied by multi-peak analysis of powder X-ray diffraction patterns

2017

Nanocrystalline boehmite (gamma-aluminium-oxyhydroxide) is a material of industrial importance, the functionality of which follows from its crystalline microstructure. A procedure for preparing boehmite nanoparticles, comprising the formation of a precipitate by the alkalization of an aqueous solution of aluminium nitrate and subsequent hydrothermal aging, was previously elaborated. The application of an additive (maltitol or tartaric acid) to control the sizes and shapes of crystallites in the produced polycrystalline powder of boehmite was developed. The aim of this work is a study of the effect of the hydrothermal treatment time on nanocrystalline characteristics of boehmite, both in abs…

BoehmiteRadiationMaterials scienceScanning electron microscope02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsMicrostructureAluminium nitrate01 natural sciencesHydrothermal circulationNanocrystalline material0104 chemical sciencesCrystallographychemistry.chemical_compoundchemistryChemical engineeringX-ray crystallographyGeneral Materials ScienceCrystallite0210 nano-technologyInstrumentationPowder Diffraction
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One-pot preparation of surface modified boehmite nanoparticles with rare-earth cyclen complexes.

2007

We report on the one-pot synthetic procedure of cyclen derivatives bearing three acetate groups attached on boehmite nanoparticles, the complexing capabilities of these inorganic–organic hybrid materials with rare earth cations, and the behaviour as contrast agents or fluorescence probes. Delgado Pinar, Estefania, Estefania.Delgado@uv.es ; Frias Martinez, Juan Carlos, Juan.Frias@uv.es ; Albelda Gimeno, Maria Teresa, Teresa.Albelda@uv.es ; Alarcon Navarro, Javier, Javier.Alarcon@uv.es ; Garcia-España Monsonis, Enrique, Enrique.Garcia-Es@uv.es

BoehmiteSurface PropertiesUNESCO::QUÍMICARare earthInorganic chemistryNanoparticleAluminum HydroxideCyclams:QUÍMICA [UNESCO]FluorescenceCatalysischemistry.chemical_compoundSynteticCyclenHeterocyclic CompoundsPolymer chemistryMaterials ChemistryNanoparticles ; Syntetic ; Acetate ; Capabilities ; Inorganic-organic ; FluorescenceAluminum OxideInorganic organicInorganic-organicAcetateSurface modifiedUNESCO::QUÍMICA::Química analíticaMetals and AlloysGeneral ChemistryCapabilitiesFluorescenceSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry:QUÍMICA::Química analítica [UNESCO]Ceramics and CompositesNanoparticlesMetals Rare EarthHybrid materialChemical communications (Cambridge, England)
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Characterization of the Purified Fourth Component of Guinea Pig Complement* *Supported by Deutsche Forschungsgemeinschaft (grant Kl 124/9).

1970

Publisher Summary A strain of rabbits deficient in complement was discovered in Freiburg, Germany in 1961. A second, clearly unrelated, strain was reported in Mexico. Both these strains are deficient in C6. A further complement-deficient rabbit was found by chance in Cambridge. This paper presents some data on the colony bred from this animal. C6 was partially purified from rabbit serum by chromatography on DEAE Cellulose and hydroxyapatite. Antibody to rabbit C6 in deficient rabbits was raised by four weekly injections of alum precipitated C6 with Bordetella pertussis as adjuvant into the knee joints, followed by three intravenous injections of the alum precipitated material without B. per…

Bordetella pertussisLysisbiologyChemistryAlummedicine.medical_treatmentC5 Deficiencybiology.organism_classificationmedicine.diseaseHemolysisMicrobiologyGuinea pigchemistry.chemical_compoundBiochemistrybiology.proteinmedicineAntibodyAdjuvant
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Halloysite nanotubes loaded with peppermint essential oil as filler for functional biopolymer film

2016

Abstract The purpose of this paper is to show how a functional bionanocomposite film with both antioxidant and antimicrobial activities was successfully prepared by the filling of a pectin matrix with modified Halloysite nanotubes (HNT) containing the essential peppermint oil (PO). Firstly, HNT surfaces were functionalized with cucurbit[6]uril (CB[6]) molecules with the aim to enhance the affinity of the nanofiller towards PO, which was estimated by means of HPLC experiments. The HNT/CB[6] hybrid was characterized by several methods (thermogravimetry, FT-IR spectroscopy and scanning electron microscopy) highlighting the influence of the supramolecular interactions on the composition, therma…

Bridged-Ring CompoundsStaphylococcus aureusHalloysite nanotubes; Nanocomposite food packaging; Essential oil; Pectin; Antimicrobial and antioxidant propertiesfood.ingredientPolymers and PlasticsPectinHalloysite nanotube02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesHalloysiteEssential oilNanocompositesContact anglefoodNanocomposite food packagingMaterials ChemistryEscherichia coliOrganic chemistryPlant OilsAntimicrobial and antioxidant propertiesAntimicrobial and antioxidant propertieSettore CHIM/02 - Chimica FisicaNanocompositeNanotubesChemistryOrganic ChemistryImidazolesMembranes ArtificialMentha piperitaSettore CHIM/06 - Chimica Organica021001 nanoscience & nanotechnologyPectin0104 chemical sciencesAnti-Bacterial AgentsThermogravimetrySolventChemical engineeringBiofilmsengineeringClayPectinsAluminum SilicatesBiopolymerBiocomposite0210 nano-technology
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Experimental study of Si–Al substitution in calcium-silicate-hydrate (C-S-H) prepared under equilibrium conditions.

2009

International audience; C-A-S-H of varying Al/Si and Ca/(Al+Si) ratios have been prepared introducing C-S-H (Ca/Si=0.66 and 0.95) at different weight concentrations in a solution coming from the hydration of tricalcium aluminate (Ca3Al2O6) in water. XRD and EDX (TEM) analyses show that using this typical synthesise procedure, pure C-A-S-H is obtained only for calcium hydroxide concentrations below 4.5 mmol L−1. Otherwise, calcium carboaluminate or strätlingite is also present beside C-A-S-H. The tobermorite-like structure is maintained for C-A-S-H. A kinetic study has shown that the formation of C-A-S-H is a fast reaction, typically less than a few hours. The Ca/(Al+Si) ratio of C-A-S-H mat…

Calcium hydroxideCalcium-silicate-hydrate (C-S-H)Aluminium hydroxide0211 other engineering and technologiesAnalytical chemistryMineralogychemistry.chemical_elementIonic bonding02 engineering and technologyBuilding and ConstructionCalcium021001 nanoscience & nanotechnologyKinetic energychemistry.chemical_compoundChemistrychemistryAluminium021105 building & constructionAluminiumThermodynamic equilibriaGeneral Materials ScienceTricalcium aluminateCalcium silicate hydrate0210 nano-technology
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Microtomographic Quantification of Hydraulic Clay Mineral Displacement Effects During a CO2 Sequestration Experiment with Saline Aquifer Sandstone

2013

We combined a noninvasive tomographic imaging technique with an invasive open-system core-flooding experiment and compared the results of the pre- and postflooded states of an experimental sandstone core sample from an ongoing field trial for carbon dioxide geosequestration. For the experiment, a rock core sample of 80 mL volume was taken from the 629 m Stuttgart Formation storage domain of a saline sandstone aquifer at the CCS research pilot plant Ketzin, Germany. Supercritical carbon dioxide and synthetical brine were injected under in situ reservoir p/T-conditions at an average flow rate of 0.1 mL/min for 256 h. X-ray computed microtomographic imaging was carried out before and after the…

Carbon SequestrationGeological PhenomenaSalinitySupercritical carbon dioxideTomographic reconstructionMineralogyCore sample550 - Earth sciencesX-Ray MicrotomographyGeneral ChemistryCarbon DioxideCarbon sequestrationPermeabilitySedimentary depositional environmentBriningClayEnvironmental ChemistryAluminum SilicatesSaltsClay mineralsPorosityGroundwaterPorosityGeologyEnvironmental Science & Technology
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Study of tantalum hemicarbide (Ta2C) production by low pressure carburizing

2015

Tantalum is a very dense metal (d = 16.6) and has a very high melting temperature of 2996°C. This material is particularly required for crucibles used for pyrochemical applications. Early studies show that a carburizing treatment enhances corrosion resistance from liquid metals. Indeed, the intergranular attack of tantalum is stopped by Ta2C precipitates, which occupy the grain boundary regions. The production of the carbon saturated tantalum with Ta2C precipitates requires a good understanding of tantalum carburizing.A carburizing treatment on tantalum sample causes the emergence of a TaC layer on surface and Ta2C layer just below. A reduction of carbon flow has enabled the study of the fi…

CarboneCarburesTantalumPrécipitésPrecipitatesCarbonAnnealing[PHYS.PHYS.PHYS-CHEM-PH] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]DiffusionCinétiqueKineticsCémentation basse pressionTantaleLow pressure carburizingCarbidesRecuit
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