Search results for "Aluminium"
showing 10 items of 548 documents
Porous Aluminium Oxide Coating for the Development of Spectroscopic Ellipsometry Based Biosensor: Evaluation of Human Serum Albumin Adsorption
2020
An electrochemically synthesised porous anodic aluminium oxide (pAAO) layer has been analysed by means of spectroscopic ellipsometry. The determined thickness of the formed pAAO layer obtained from spectroscopic ellipsometry measurements and modelling was 322.75 ±
Optical and electronic properties of graphene nanoribbons upon adsorption of ligand-protected aluminum clusters
2014
We have carried out first-principles calculations to investigate how the electronic and optical features of graphene nanoribbons are affected by the presence of atomic clusters. Aluminum clusters of different sizes and stabilized by organic ligands were deposited on graphene nanoribbons from which the energetic features of the adsorption plus electronic structure were treated within density-functional theory. Our results point out that, depending on their size and structure shape, the clusters perturb distinctively the electronic properties of the ribbons. We suggest that such selective response can be measured through optical means revealing that graphene nanoribbons can work as an efficie…
Projected fringes for the measurement of large aluminum ingots
2010
The method of projected fringes is applied to the measurement of the surface topography of aluminum ingots with surface areas of several square meters. The measurements are performed inside the casting hall of an aluminum factory. To meet the challenges encountered in such a demanding environment, it is important to keep the equipment as simple and robust as possible. Therefore a method for locating the fringe positions with sub-pixel accuracy without using for example phase shifting techniques is applied. Also the nonlinearity of the phase when using divergent illumination is discussed. The developed measuring system is tested measuring eight different aluminum ingots, and the results agre…
The Effect of Pesticides on the Tomato Bacterial Speck Disease Pathogen Pseudomonas Syringae pv. Tomato
2020
A significant part of the used pesticides does not reach the target organisms and, while remaining in the agrophytocenosis, influences all living organisms in it. Having a toxic and often mutagenic effect, pesticides induce morphological and physiological changes in the cells of microorganisms and are the cause of phenotypic heterogeneity of their populations. However, the effect of pesticides on phytopathogenic bacteria as non-target microorganisms remains out of the field of view for most researchers. However, the use of pesticides can lead to expansion of the diversity of existing phytopathogens and, as a consequence, complications of identification of the pathogens, loss of resistance b…
Influence of aeration on the localized trenching on aluminium alloys
2010
This paper aims to make the difference between alcalinisation and micro-galvanic corrosion in the mechanism of the corrosion of Al alloys. Using a pH microprobe, the pH changes inside a pure water droplet deposited on a thermal aged 2011 aluminium alloy were scanned. These pH variations, depending on the position inside the droplet, were related to the heterogeneous corrosion attacks of the aluminium surface quantified by AFM measurements. A modelling investigation is proposed to evaluate the distinct roles of alcalinisation, due to the oxygen reduction reaction (ORR), and the galvanic coupling between intermetallic particles and the surrounding matrix. It can be concluded that the former c…
Application of differently treated illite and illite clay samples for the development of ceramics
2017
Abstract This study represents the results of investigations on the possible geopolymer formation of an alkali, mechanically and thermally (including hydrothermally) activated 2:1 layer silicate, namely, illite and illite clay, for low-temperature ceramic products. The main starting materials were Quaternary illite clay samples taken from the Apriki–Laza pit in Latvia. For the investigations, an intermediate composition of illite clay and separated illite were used. The following research methods for the treated illite and illite clay were used: the phase transition was analysed by differential thermal analysis, while the phase compositions, microstructures and structures were analysed by X…
Structural insights into the GTPase domain of Escherichia coli MnmE protein
2007
The Escherichia coli MnmE protein is a 50-kDa multidomain GTPase involved in tRNA modification. Its homologues in eukaryotes are crucial for mitochondrial respiration and, thus, it is thought that the human protein might be involved in mitochondrial diseases. Unlike Ras, MnmE shows a high intrinsic GTPase activity and requires effective GTP hydrolysis, and not simply GTP binding, to be functionally active. The isolated MnmE G-domain (165 residues) conserves the GTPase activity of the entire protein, suggesting that it contains the catalytic residues for GTP hydrolysis. To explore the GTP hydrolysis mechanism of MnmE, we analyzed the effect of low pH on binding and hydrolysis of GTP, as well…
Diffusion processes and growth on aluminum cluster surfaces
1997
Diffusion processes of adatoms on icosahedral and Wulff polyhedral aluminum cluster surfaces have been studied by molecular dynamics simulations using the effective medium theory. Activation energies of diffusion mechanisms along {111} and {100} facets and from one facet to another, including different hopping and exchange processes as well as more exotic events, have been calculated. Exchange diffusion of an adatom by a chain mechanism through a {100} facet between two {111} facets and hopping diffusion across the edge between two {111} facets via a pull of another adatom on the neighbour facet are shown to play an important role. Adatoms on {111} facets are mobile already at very low temp…
Aluminum-27 double-rotation NMR investigations of SAPO-5 with variable silicon content
1995
Summary Double-rotation NMR (DOR) studies of 27 Al species in SAPO-5, a silicon aluminophosphate molecular sieve with a one dimensional channel system, have revealed a minimum of three aluminum sites resulting from the synthesis. The DOR technique was used specifically to increase the spectral resolution by removing the broadening influences from second-order quadrupolar interactions associated with the spin 5/2 27 Al nuclei. The DOR investigations of SAPO-5 crystals with variable Si/Al ratios resulted in the identification of three aluminum species, two consistent with the reported isotropic shift values for AlPO 4 -5; however, these two resonances are only observable when small quantities…
A Novel Plasmonic Nanoantenna for High Efficiency Energy Harvesting Applications
2020
In this paper, the results of a geometric investigation of plasmonic nanoantennas for energy harvesting applications in terms of field enhancement and available power are presented. Optimum performances are obtained by a particular arrow-shaped bowtie nanoantennas geometry. The novel nanoantenna geometry is here presented. The simulations of the novel nanoantennas made of aluminium, on a three-layers substrate, composed by silicon, silicon oxide, and aluminium, carried out with CST 2018 tool, are reported and compared with the classical bowtie nanoantennas ones. This study can guide both the engineering and the fabrication of plasmonic nanoantennas.