Search results for "Aluminium"

Particle size-related limitations of persistent phosphors based on the doped Y3Al2Ga3O12 system

2021

AbstractCo-doped Ce3+, Cr3+ and Pr3+ yttrium–aluminium–gallium garnet powders of various sizes were obtained by co-precipitation method. The microstructure and morphology were investigated by XRPD, TEM and gas porosimetry. The luminescence properties were studied by excitation and emission spectra, quantum yield and decay times. Thermoluminescence measurements were performed to evaluate the activation energy, traps redistribution and frequency factor. Limitation in the energy transfer between dopant ions in the small particles, traps depth and surface defects were considered and investigated as responsible for the quenching of persistent luminescence. The phosphors annealed at 1100 °C show …

Determination of the stress distribution at the interface metal-oxide: Numerical and theoretical considerations

2005

In this paper we give a brief presentation of the approaches we have recently developed on the oxidation of metals. Firstly, we present an analytical model based on non-equilibrium thermodynamics to describe the reaction kinetics present during the oxidation of a metal. Secondly, we present the molecular dynamics results obtained with a code specially tailored to study the oxidation and growth of an oxide film of aluminium. Our simulations present an excellent agreement with experimental results.

Luminescence, vibrational and XANES studies of AlN nanomaterials

2007

Abstract The paper reports comparative studies on synthesized aluminium nitride nanotubes, nanoparticles and commercially available micron-sized AlN powder using different spectroscopic techniques: cathodoluminescence measurements (CL), X-ray absorption near edge spectroscopy (XANES) and Fourier-transform infrared spectroscopy (FTIR). Crucial distinctions in CL spectra are observed for nano- and microsized aluminium nitride powders; systematic shift of the IR absorption maximum has been detected for nanostructured aluminium nitride as compared to commercial samples. Through XANES experiments on Al K-edge structural differences between nano- and bulk AlN are revealed, intensity of features i…

Numerical Determination of Intrinsic Diffusion Coefficient of Aluminide Coatings on Metals

2009

This paper presents a numerical method to determine the composition dependent diffusivities and to predict the concentration profile during the interdiffusion process. The intrinsic diffusion coefficients in diffusion aluminide coatings (Fe-Al) were determined at 1000oC. The obtained diffusion coefficient for iron in Fe3Al or FeAl is in the range 10-10 to 10-9 cm2.s-1. The aluminum diffusion coefficient varies from 10-11 to 10-7 cm2.s-1 in the same phases.The present approach also permits to model the reactive diffusion in the Fe-Al systems.

Luminescence processes induced by UV radiation in A1N nanotips and nanorods

2008

Abstract The processes of the UV radiation induced photoluminescence, thermoluminescence and optically stimulated luminescence in the AlN nanotips and nanorods are studied in comparison with those in the AlN ceramics. The emission spectra of the UV radiation induced luminescence processes in the AlN nanostructures are similar to those of AlN ceramics, presumably originating from recombination processes with participation of the oxygen-related centres. In the nanostructures the luminescence processes occur mainly through the excitation of the host lattice, probably due to the smaller content of the randomly distributed defects in the lattice. The observed small mutual differences in the lumi…

Reaktionen an Aluminiumoxiden. 1. Mitt.: Umsetzungen von Aceton an Aluminiumoxiden

1972

Die Umsetzungsraten von Aceton (1) an verschiedenen Aluminiumoxiden wurden bei unterschiedlichen Bedingungen untersucht. Die auftretenden Stoffe wurden durch Vergleichssubstanzen identifiziert und durch Dunnschicht- und Gas-Flussig-Chromatographie nachgewiesen. Reactions on Aluminium Oxides The reaction rates of 1 on various aluminium oxides were investigated under different conditions. The resulting products were identified comparing with synthesized compounds and by thin layer and gas liquid chromatography.

Preferential CO oxidation over catalysts with well-defined inverse opal structure in microchannels

2008

Catalyst supports of CeO 2 /SiO 2 and Al 2 O 3 with three-dimensionally ordered macroporous structure were fabricated in microchannels by application of PMMA opals as templates. Pt-Rh supported on CeO 2 /SiO 2 showed high efficiency for CO removal in preferential CO oxidation in the presence of excess hydrogen. Pt-Rh supported on Al 2 O 3 with an inverse opal structure showed higher reactivity than that supported on wash-coated Al 2 O 3 layers in microchannel reactor.

On the Measurement and Prediction of the Out-of-Plane Displacement Surrounding Cold-Expanded Holes

2010

Experimental measurements of the out-of-plane displacement surrounding cold-expanded holes in a 6082-T6 aluminum alloy were made with a 3D optical scanner using the technique of the encoded light-pattern projection in white light. The measured surface profiles have shown the thickness discontinuity along the hole edge due to the effect of the split in the sleeve. An analytical–numerical solution of the out-of-plane displacement is presented based on existing analytical models. Thus, the results given by the analytical model were then compared with the experimental data and with a finite element (FE) model that simulates the cold-expansion process. The location of the elastic–plastic boundar…

Physico-chemical Characterization of Aluminium Oxide Films Grown on Etched Foils for Electrolytic Capacitors

2012

Experimental and Numerical Analysis of the Distribution of Residual Stresses Induced by Laser Shock Peening in a 2050-T8 Aluminium Alloy

2011

Laser shock peening (LSP) is an innovative surface treatment technique successfully applied to improving fatigue performance of metallic material. The specific characteristic of (LSP) is the generation of a low work-hardening and a deep compressive residual stresses mechanically produced by a laser-induced shock wave propagating in the material. The aim of this study is to analyse the residual stress distribution induced by laser peening in 2050-T8 aluminium alloy experimentally by the X-ray diffraction technique (method sin2Y) and numerically, by a finite element numerical modelling. A specific focus was put on the residual stress distribution along the surface of the impacted material.