Search results for "Alunite"
showing 5 items of 5 documents
Geochemistry of REE, Zr and HF in a wide range of pH and water composition: The Nevado del Ruiz volcano hydrothermal system (Colombia)
2015
International audience; The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidic waters are sulphate dominated with different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr and Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters.Y–Ho and Z…
Geochemical processes assessed by Rare Earth Elements fractionation at "Laguna Verde" acidic-sulphate crater lake (Azufral volcano, Colombia)
2017
Abstract The geochemical behaviour of major elements, Fe, Al, Mn, and Rare Earth Elements (REE) was investigated in the “Laguna Verde” acidic crater lake of Azufral volcano (Colombia). The cold lake water (T close to 10 °C) is sulphate-dominated, due to absorption and oxidation of H2S (pH 2.1–2.7, Eh 196–260 mV), and Na-enriched (Total Dissolved Solids 0.79 g L−1). The total amount of REE dissolved in the lake ranges from 3.3 to 9.1 ppb. The REE patterns normalized to the local rocks show a Light Rare Earth Elements (LREE) depletion quite constant in the 15 samples. Similar patterns were already found in the acidic sulphate springs of Nevado del Ruiz volcano-hydrothermal system, caused by t…
Bone remodeling in malunited fractures in children. Is it reliable?
1997
Fracture malunion is not a rare phenomenon in children due to the frequent use of closed reduction treatments. In this article, the processes of bone remodeling in cases of angular and rotational deformities, overriding of bone fragments, and overgrowth are addressed. Critical analyses of the mechanisms to correct these deformities, function of the physis and periosteum, and other related factors are given. The acceptable deformities for complete remodeling to be successful vary at different ages and locations.
Sulfuric acid caves of Italy: A review
2019
Abstract In Italy, especially along the Apennine Chain, numerous active and inactive sulfuric acid speleogenetic (SAS) caves have been documented in the last two decades. Here we present an overview of these peculiar hypogene systems, illustrating their main geomorphological and mineralogical features, and the microbial signatures observed in the active underground environment. SAS caves are widely distributed in the northern and central Apennines, whereas they are less abundant in the southern Apennines, in the Apulian foreland, in Sicily and in Sardinia. Their location is significantly influenced by lithological and structural rock properties, as they occur in carbonate areas where acidic…
Characterisation and origin of hydrothermal waters at São Miguel (Azores) inferred by chemical and isotopic composition
2017
Abstract This study focuses on the characterisation and origin of hydrothermal waters discharging from three main active volcanoes (Furnas, Fogo and Sete Cidades) at Sao Miguel, where 33 water with temperatures ranging between 13 and 97 °C, and 5 precipitate samples were collected. The developed conceptual model for this active hydrothermal system reveals that all waters can be classified by Na-HCO 3 , Na-Cl and Na-SO 4 types and are of meteoric origin. This is confirmed by the stable hydrogen and oxygen isotope data that are positioned close to the local meteoric water line (− 4.1‰ ≤ δ 18 O H2O ≤ 5.2‰; − 17.6‰ ≤ δD H2O ≤ 20.4‰), except for the Na-Cl type water at Ferraria (Sete Cidades a…