Search results for "Amide"

showing 10 items of 3119 documents

Synthesis, crystal structure and Hirshfeld analysis of a crystalline compound comprising a 1/1 mixture of 1-[(1R,4S)- and 1-[(1S,4R)-1,7,7-trimethyl-…

2020

A racemic mixture of (R)- and (S)-camphor thio­semicarbazone, which crystallizes in the centrosymmetric space group C2/c, is reported.

crystal structurechiral thiosemicarbazonechiral thio­semicarbazonecamphor derivativeThio-Crystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesResearch Communicationsracemic mixtureCrystalchemistry.chemical_compoundGroup (periodic table)AmideGeneral Materials ScienceCrystallographyChemistryGeneral ChemistryCondensed Matter Physics0104 chemical sciencesCrystallographyAsymmetric carbonQD901-999Racemic mixtureChirality (chemistry)Acta Crystallographica Section E: Crystallographic Communications
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N,1-Bis(4-ethoxyphenyl)-2,6-dimethyl-4-oxo-1,4-dihydropyridine-3-carboxamide

2018

Condensation of ethyl acetoacetate and phenetidine gives the title compound, C24H26N2O4. The planar ethoxyphenyl group attached to the pyridine ring is twisted about 77.96 (11)° out of the plane of the N-ethoxycarboxamidopyridine unit. The carboxamide unit forms a dihedral angle of about 28.1 (2)° with the pyridine ring.

crystal structurehydrogen bondHydrogen bondChemistrymedicine.drug_classnicotinamideCarboxamideCrystal structureDihedral angle010402 general chemistry010403 inorganic & nuclear chemistryRing (chemistry)01 natural sciencesMedicinal chemistryPhenetidine0104 chemical scienceschemistry.chemical_compoundPyridinemedicinelcsh:QD901-999lcsh:CrystallographyheterocycleIUCrData
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Crystal structure of 5-{3-[2,6-dimethyl- 4-(5-methyl-1,2,4-oxadiazol-3-yl)phenoxy]propyl}- N-(11-hydroxyundecyl)isoxazole-3-carboxamide hemihydrate

2015

The crystal structure and supra­molecular features of 5-{3-[2,6-dimethyl-4-(5-methyl-1,2,4-oxa­diazol-3-yl)phen­oxy]prop­yl}-N-(11-hy­droxy­undec­yl)isoxazole-3-carboxamide hemihydrate, a derivative of anti­viral ‘WIN compounds’, are reported.

crystal structuremedicine.drug_classOxadiazoleCarboxamideNanotechnologyCrystal structureDihedral angleRing (chemistry)Medicinal chemistryResearch Communicationschemistry.chemical_compoundmedicinePeptide bondGeneral Materials ScienceIsoxazoleta116oxa­diazoleCrystallographyChemistryHydrogen bondWIN derivativeisoxazoleGeneral ChemistryCondensed Matter PhysicsantiviralQD901-999anti­viraloxadiazoleActa Crystallographica Section E : Crystallographic Communications
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A second solvatomorph of poly[[μ4-N,N′-(1,3,5-oxadiazinane-3,5-diyl)bis(carbamoylmethanoato)]nickel(II)dipotassium] : crystal structure, Hirshfeld su…

2021

The title compound, poly[triaquabis[μ4-N,N′-(1,3,5-oxadiazinane-3,5-diyl)bis(carbamoylmethanoato)]dinickel(II)tetrapotassium], [K4Ni2(C7H6N4O7)2(H2O)3] n , is a second solvatomorph of poly[(μ4-N,N′-(1,3,5-oxadiazinane-3,5-diyl)bis(carbamoylmethanoato)nickel(II)dipotassium] reported previously [Plutenko et al. (2021). Acta Cryst. E77, 298–304]. The asymmetric unit of the title compound includes two structurally independent complex anions [Ni(C7H6N4O7)]2−, which exhibit an L-shaped geometry and consist of two almost flat fragments perpendicular to one another: the 1,3,5-oxadiazinane fragment and the fragment including other atoms of the anion. The central Ni atom is in a square-planar N2O2 co…

crystal structureshape analysischemistry.chemical_elementCrystal structureEnergy minimizationIonpseudomacrocyclic ligandCrystalchemistry.chemical_compoundtemplate reactionSHAPE analysisAmidehirshfeld surface analysisAtomHirshfeld surface analysisGeneral Materials Sciencesemi-empirical geometry optimizationCrystallographynickel(ii) complexGeneral ChemistrykompleksiyhdisteetCondensed Matter Physicsnickel(II) complexkiteetTemplate reactionNickelCrystallographychemistryQD901-999nikkelihydrazide-based ligand
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Drug delivery systems based on polymeric micro and nanoparticles for the treatment of cystic fibrosis

cystic fibrosismucus penetrating nanoparticlesinhalable microparticlestobramycinivacaftorαβ-poly-(N-2-hydroxyethyl)-DL-aspartamide (PHEA)ibuprofen
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CCDC 2153375: Experimental Crystal Structure Determination

2022

Related Article: María Vicent-Morales, María Esteve-Rochina, Joaquín Calbo, Enrique Ortí, Iñigo J. Vitórica-Yrezábal, Guillermo Mínguez Espallargas|2022|J.Am.Chem.Soc.|144|9074|doi:10.1021/jacs.2c01957

dimethylammonium 4-{2-[45-bis(4-carboxyphenyl)-2H-13-dithiol-2-ylidene]-5-(4-carboxyphenyl)-2H-13-dithiol-4-yl}benzoate NN-dimethylformamide solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Spine and test skeletal matrices of the Mediterranean sea urchinArbacia lixula- a comparative characterization of their sugar signature

2015

15 pages; International audience; Calcified structures of sea urchins are biocomposite materials that comprise a minor fraction of organic macromolecules, such as proteins, glycoproteins and polysaccharides. These macromolecules are thought to collectively regulate mineral deposition during the process of calcification. When occluded, they modify the properties of the mineral. In the present study, the organic matrices (both soluble and insoluble in acetic acid) of spines and tests from the Mediterranean black sea urchin Arbacia lixula were extracted and characterized, in order to determine whether they exhibit similar biochemical signatures. Bulk characterizations were performed by mono-di…

echinoidPolysaccharideBiochemistryMineralization (biology)Calcium Carbonate[SDV.BBM.GTP]Life Sciences [q-bio]/Biochemistry Molecular Biology/Genomics [q-bio.GN]Spectroscopy Fourier Transform InfraredMediterranean SeaAnimalsMonosaccharide[SDV.IB.BIO]Life Sciences [q-bio]/Bioengineering/BiomaterialsMolecular BiologyArbacia lixulaPolyacrylamide gel electrophoresisorganic matrixArbaciachemistry.chemical_classificationsaccharideArbaciabiologyLectinlectin assayCell Biology[ SDV.IB.BIO ] Life Sciences [q-bio]/Bioengineering/Biomaterialsbiomineralizationbiology.organism_classificationchemistryBiochemistry[ SDV.BBM.GTP ] Life Sciences [q-bio]/Biochemistry Molecular Biology/Genomics [q-bio.GN]AgglutininsSea UrchinsMicroscopy Electron Scanningbiology.proteinElectrophoresis Polyacrylamide GelBiomineralizationFEBS Journal
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Optimising Lactic Acid Cheese Packaging Systems

2016

On the basis of a previous research, it seems that foil-wrapped tray solutions are not particularly chosen by lactic acid cheese consumers. With relation to this study, almost half of the respondent population would have expressed the desire of different packages. Parchment packages and poly(ethylene-co-vinyl acetate)/polyvinylidene chloride/poly(ethylene-co-vinyl acetate) laminates would be removed by 25.0 and 12.5% of customers, respectively. Polyamide/polyethylene double and single packaging would be removed from the market only by 5.0% of respondents. Data have shown that cheese and packaging quality are dependent on lactic acid cheese surface microflora. The type of this microflora is …

education.field_of_studyMaterials scienceThin layerPopulationPolyethyleneengineering.materialLactic acidchemistry.chemical_compoundchemistryCoatingPolyamideengineeringFood scienceeducationPolyvinylidene chlorideLactic acid fermentation
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Theoretical study of selective H3 receptor antagonists of histamine

1993

Abstract The conformations and charge distributions of three selective H3 receptor antagonists of histamine were determined using the MNDO approach. The results suggest that the conformational flexibilities of betahistine, N α-(2-phenylacetyl)histamine and thioperamide are different; however, the low-energy conformations of these compounds show closely related spatial orderings. The MNDO calculations predict a significant population of the N1H form in the imidazole systems of N α-(2-phenylacetyl)histamine and thioperamide. Our results indicate that the conformational behaviour of H3 antagonists is closely similar to that reported for H2 antagonists of histamine. These results emphasize the …

education.field_of_studyThioperamideStereochemistryChemistryPopulationAntagonistMNDOCondensed Matter PhysicsBiochemistrychemistry.chemical_compoundComputational chemistrymedicineImidazoleBetahistinePhysical and Theoretical ChemistryHistamine H3 receptoreducationHistaminemedicine.drugJournal of Molecular Structure: THEOCHEM
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Genetically engineered V79 Chinese hamster cells metabolically activate the cytostatic drugs cyclophosphamide and ifosfamide.

1990

V79 cells, genetically engineered to express active cytochromes P450IIB1 and P450IA1, were used to study the cytotoxicity and mutagenicity of cyclophosphamide and ifosfamide. Cyclophosphamide, tested up to a concentration of 2 mM, was not cytotoxic in V79 nor in the P450IA1-expressing V79-derived cell line XEM2. Pronounced cytotoxicity was, however, observed in the P450IIB1-expressing V79-derived cell line SD1. Induction of gene mutations (acquisition of 6-thioguanine resistance) was observed in SD1 cells as well, but the effects were weak. Ifosfamide was inactive in V79 cells, but was cytotoxic in SD1 cells. Ifosfamide mustard, an active metabolite of ifosfamide, was equally cytotoxic and …

endocrine systemCyclophosphamideHealth Toxicology and MutagenesisAntineoplastic AgentsPharmacologyChinese hamsterCell LineBiotransformationCricetinaemedicineAnimalsIfosfamideCytotoxicityCyclophosphamideBiotransformationIfosfamidebiologyGenetically engineeredPublic Health Environmental and Occupational Healthfood and beveragesrespiratory systembiology.organism_classificationCell cultureCytostatic drugsGenetic EngineeringResearch Articlemedicine.drugEnvironmental Health Perspectives
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