Search results for "Annihilator"
showing 2 items of 2 documents
Purely organic Vis-to-UV upconversion with an excited annihilator singlet beyond 4 eV
2022
The conversion of visible light into high-energy UV photons via sensitized triplet–triplet annihilation (TTA-UC) could pave the way for several energy-demanding applications. However, only a handful of annihilator chromophores for Vis-to-UV upconversion are known and the current limit for the excited-state energy of the UV emitter in TTA-UC schemes is below 4 eV, i.e., in the spectral region (>310 nm) where the sun still provides a considerable photon flux. Herein, we present a novel biphenyl-based annihilator with a highly fluorescent singlet state at 4.04 eV. This annihilator can be combined with a widely-used TADF sensitizer to yield an efficient blue-light (2.77 eV) driven upconversion …
An annihilator-based strategy for the automatic detection of exponential polynomial spaces in subdivision
2021
Abstract Exponential polynomials are essential in subdivision for the reconstruction of specific families of curves and surfaces, such as conic sections and quadric surfaces. It is well known that if a linear subdivision scheme is able to reproduce a certain space of exponential polynomials, then it must be level-dependent, with rules depending on the frequencies (and eventual multiplicities) defining the considered space. This work discusses a general strategy that exploits annihilating operators to locally detect those frequencies directly from the given data and therefore to choose the correct subdivision rule to be applied. This is intended as a first step towards the construction of se…