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showing 10 items of 28370 documents

High pressure crystal structures of orthovanadates and their properties

2020

Pressure-induced phase transitions in orthovanadates have led to interesting physical phenomena. The observed transitions usually involve large volume collapses and drastic changes in the electronic and vibrational properties of the materials. In some cases, the phase transitions implicate coordination changes in vanadium, which has important consequences in the physical properties of vanadates. In this Perspective, we explore the current knowledge of the behavior of MVO4 vanadates under compression. In particular, we summarize studies of the structural, vibrational, and electronic properties and a few illustrative examples of high-pressure research in the compounds of interest are discusse…

010302 applied physicsChemical Physics (physics.chem-ph)Phase transitionCondensed Matter - Materials ScienceMaterials scienceGeneral Physics and AstronomyMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciences02 engineering and technologyApplied Physics (physics.app-ph)Physics - Applied Physics021001 nanoscience & nanotechnology01 natural sciencesEngineering physicsHigh pressurePhysical phenomenaPhysics - Chemical Physics0103 physical sciences0210 nano-technologyElectronic properties
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Insights into Intrinsic Defects and the Incorporation of Na and K in the Cu2ZnSnSe4 Thin-Film Solar Cell Material from Hybrid-Functional Calculations

2016

We have performed density functional theory calculations using the HSE06 hybrid functional to investigate the energetics, atomic, and electronic structure of intrinsic defects as well as Na and K impurities in the kesterite structure of the Cu2ZnSnSe4 (CZTSe) solar cell material. We found that both Na and K atoms prefer to be incorporated into this material as substitutional defects in the Cu sublattice. At this site highly stable (Na–Na), (K–K), and (Na–K) dumbbells can form. While Na interstitial defects are stable in CZTSe, the formation of K interstitial defects is unlikely. In general, the calculated formation energies for Na-related defects are always lower compared to their K-related…

010302 applied physicsChemical substanceChemistryNanotechnology02 engineering and technologyElectronic structureengineering.material021001 nanoscience & nanotechnology01 natural sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialslaw.inventionHybrid functionalGeneral EnergyImpuritylawChemical physics0103 physical sciencesSolar cellengineeringDensity functional theoryKesteritePhysical and Theoretical Chemistry0210 nano-technologyScience technology and societyThe Journal of Physical Chemistry C
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Irradiation effects in CaF2probed by Raman scattering

2016

The formation conditions and dynamics of Ca colloids and point defects that appear in irradiated single crystals of CaF2 were investigated by Raman spectroscopy. The intensity changes in the Raman spectra because of the presence of different concentrations of point defects and Ca colloids that emerged in CaF2 after irradiation with 2.2 GeV Au ions were used to study their distribution and stability under illumination with three laser wavelengths (473, 532 and 633 nm) at different output powers (2 to 200 mW). A damage saturation at a fluence of 6 × 1011 ion cm−2 was observed. The dependence of the spectral changes on the ion fluence can be described by a core/halo damage cross-section model.…

010302 applied physicsChemistryAnalytical chemistry02 engineering and technology021001 nanoscience & nanotechnologyLaser01 natural sciencesCrystallographic defectMolecular physicsFluencelaw.inventionIonsymbols.namesakeSwift heavy ionlaw0103 physical sciencessymbolsGeneral Materials ScienceIrradiation0210 nano-technologyRaman spectroscopySpectroscopyRaman scatteringJournal of Raman Spectroscopy
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Comparative Theoretical Analysis of BN Nanotubes Doped with Al, P, Ga, As, In, and Sb

2013

SUMMARY AND CONCLUDING REMARKS We have performed large-scale first-principles calculations ofthe electronic structure of (5,5) boron nitride nanotubescontaining the following substitutional impurity atoms: Al, P,Ga, As, In, and Sb. Calculations have been performed using thetwo methods: (i) linear combination of atomic orbitals(LCAO) with the atomic-centered Gaussian-type functions asa basis set and (ii) linearized augmented cylindrical wave(LACW) accompanied with the local density functional andmuffin-tin approximations for the electronic potential. In arelatively good qualitative agreement, both methods predict lowformation energies and, thus, relative stability of point defectsthat are assoc…

010302 applied physicsChemistryBand gap02 engineering and technologyElectronic structure021001 nanoscience & nanotechnology01 natural sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsBond lengthchemistry.chemical_compoundGeneral EnergyBoron nitrideLinear combination of atomic orbitals0103 physical sciencesDensity of statesPhysical and Theoretical ChemistryAtomic physics0210 nano-technologyElectronic band structureBasis setThe Journal of Physical Chemistry C
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Analytical description of solid particles kinematics due to a fluid flow and application to the depiction of characteristic kinematics in cold sprayi…

2017

Abstract In several multiphase flow applications such as fluidization, thermal spraying, atomization manufacturing and so on, the Newton's law is widely enacted to formulate the particle/fluid kinematic interaction and then to compute particles kinematics. This paper provides analytical solutions of the Newton's law in its time-dependent formulation or simplified formulation, the latter being a reduction of the time dependent problem into a spatial description of the particle motion. It was found that the velocity solution is strictly similar in both cases so that the simplified formulation is viable. The W_ 1 branch of the Lambert's function yields the analytical particle residence time an…

010302 applied physicsChemistryGeneral Chemical EngineeringMultiphase flow02 engineering and technologyMechanicsKinematics021001 nanoscience & nanotechnologyResidence time (fluid dynamics)01 natural sciencessymbols.namesakeMach number0103 physical sciencesFluid dynamicssymbolsParticleParticle velocity0210 nano-technologyMagnetosphere particle motionPowder Technology
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Numerical Procedures and their Practical Application in PV Module Analyses. Part IV: Atmospheric Transparency Parameters - Application

2020

Abstract The presented article relates to aspects of PV module testing using natural sunlight in outdoor conditions. It is a continuation of the article Part III: parameters of atmospheric transparency - determining and correlations. This article discusses the practical application of the indexes: atmosphere purity - k Tm , diffused component content - k s/o , beam clear sky index - K b - in testing various modules in outdoor conditions. Their influence on the conversion of modules made from various absorbers and various technologies is demonstrated. Their practical application in module testing in outdoor conditions is described and it - has been demonstrated that the results of the analys…

010302 applied physicsChemistrybusiness.industry020209 energysolar energyAtmospheric transparencysolar radiation spectrum02 engineering and technologysky clearness indexdiffused component content index01 natural sciencesEnergy engineeringPart iiiphotovoltaicsComponent (UML)0103 physical sciences0202 electrical engineering electronic engineering information engineeringGeneral Materials ScienceProcess engineeringbusinessEcological Chemistry and Engineering S
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The influence of AlN buffer over the polarity and the nucleation of self-organized GaN nanowires

2015

We experimentally investigate the influence of AlN buffer growth on the nucleation and the polarity of a self-organized assembly of GaN nanowires (NWs) grown on Si. Two complementary growth mechanisms for AlN buffer deposited on Si are demonstrated. Both emphasize the aggregation of Si on the AlN surface and the growth of large cubic crystallites, namely, AlN pedestals. Further growths of GaN NWs assembly reveal that the GaN 2D layer found at the bottom of the NW assembly is the result of the coalescence of Ga-polar pyramids, whereas AlN pedestals are observed as preferential but not exclusive NW nucleation sites. NWs are N-polar or exhibit inversion domains with a Ga-polar core/N-polar she…

010302 applied physicsCoalescence (physics)[PHYS]Physics [physics]Materials sciencebusiness.industryNucleationWide-bandgap semiconductorNanowireGeneral Physics and AstronomyNanotechnology02 engineering and technology021001 nanoscience & nanotechnology01 natural sciencesBuffer (optical fiber)Nanolithography0103 physical sciencesOptoelectronicsCrystalliteSelf-assembly0210 nano-technologybusinessComputingMilieux_MISCELLANEOUS
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Measurements on partial discharge in on‐site operating power transformer: a case study

2018

This study presents the case study of a substation in-service power transformer referred to the on-site partial discharge (PD) detection and evaluation methods. An original methodology for simultaneous application of three methods is proposed: electrical, acoustic and ultra-high frequency. Transformer is powered by the power grid and no external generator is required according to the proposed methodology. Furthermore, several possibilities of applying these concurrent measurements and benefits of such solution in terms of result interpretation, interference resistance and on-site measurement applicability are indicated. The proposed methodology allows for a fast, accurate and secure PD diag…

010302 applied physicsComputer science020209 energyEnergy Engineering and Power TechnologyHigh voltage02 engineering and technologycomputer.software_genre01 natural sciencesExpert systemlaw.inventionUltra high frequencyControl and Systems Engineeringlaw0103 physical sciencesEvaluation methodsPartial discharge0202 electrical engineering electronic engineering information engineeringElectronic engineeringPower gridElectrical and Electronic EngineeringTransformerInterference resistancecomputerIET Generation, Transmission & Distribution
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FPGA based digital lock-in amplifier for fNIRS systems

2018

Lock-In Amplifiers (LIA) represent a powerful technique helping to improve signals detectability when low signal to noise ratios are experienced. Continuous Wave functional Near Infrared Spectroscopy (CW-fNIRS) systems for e-health applications usually suffer of poor detection due to the presence of strong attenuations of the optical recovering path and therefore small signals are severely dipped in a high noise floor. In this work a digital LIA system, implemented on a Zynq® Field Programmable Gate Array (FPGA), has been designed and tested to verify the quality of the developed solution, when applied in fNIRS systems. Experimental results have shown the goodness of the proposed solutions.

010302 applied physicsComputer scienceAmplifier0206 medical engineeringLock-in amplifierDigital lock-in amplifier02 engineering and technology020601 biomedical engineering01 natural sciencesNoise floorSettore ING-INF/01 - ElettronicaSilicon photomultiplier (SiPM)Quality (physics)0103 physical sciencesElectronic engineeringContinuous waveFunctional near-infrared spectroscopyField-programmable gate arrayFpgaFunctional near-infrared spectroscopy
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The filter and calibration wheel for the ATHENA wide field imager

2016

The planned filter and calibration wheel for the Wide Field Imager (WFI) instrument on Athena is presented. With four selectable positions it provides the necessary functions, in particular an UV/VIS blocking filter for the WFI detectors and a calibration source. Challenges for the filter wheel design are the large volume and mass of the subsystem, the implementation of a robust mechanism and the protection of the ultra-thin filter with an area of 160 mm square. This paper describes performed trade-offs based on simulation results and describes the baseline design in detail. Reliable solutions are envisaged for the conceptual design of the filter and calibration wheel. Four different varian…

010302 applied physicsComputer scienceDetectorFilter wheel mechanism FEM structural and acoustic analysis ATHENA WFIVolume (computing)Blocking (statistics)01 natural sciencesSquare (algebra)Settore FIS/05 - Astronomia E AstrofisicaPosition (vector)Filter (video)0103 physical sciencesElectronic engineeringCalibration010303 astronomy & astrophysicsSimulation
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