Search results for "Application"

Relativistic DFT Calculation of (119)Sn Chemical Shifts and Coupling Constants in Tin Compounds.

2006

The nuclear shielding and spin-spin coupling constants of (119)Sn in stannane, tetramethylstannane, methyltin halides Me4-nSnXn (X = Cl, Br, I; n = 1-3), tin halides, and some stannyl cations have been investigated computationally by DFT methods and Slater all-electron basis sets, including relativistic effects by means of the zeroth order regular approximation (ZORA) method up to spin-orbit coupling. Calculated (119)Sn chemical shifts generally correlate well with experimental values, except when several heavy halogen atoms, especially iodine, are bound to tin. In such cases, calculated chemical shifts are almost constant at the scalar (spin-free) ZORA level; only at the spin-orbit level i…

Coupling Mechanics of Antikythera Gearwheels

2012

This paper discusses the gear coupling mechanics of the ancient Antikythera mechanism, among whose distinctive characteristics was the triangular shaping of the teeth. The engagement of the tooth pairs is analyzed in detail, estimating the temporal variation of the speed ratio due to the back and forth shifting of the relative instant center. The admissibility of the theoretical contact points is carefully checked, and the magnitude of the successive tooth collisions is calculated together with the energy losses arising from the particular nature of the coupling. Some interesting results are that only one tooth pair turns out to be active at each time instant and the real path may belong on…

A fast BEM for the analysis of damaged structures with bonded piezoelectric sensors

2010

A fast boundary element method for the analysis of three-dimensional solids with cracks and adhesively bonded piezoelectric patches, used as strain sensors, is presented. The piezoelectric sensors, as well as the adhesive layer, are modeled using a 3D state-space finite element approach. The piezoelectric patch model is formulated taking into account the full electro-mechanical coupling and embodying the suitable boundary conditions and it is eventually expressed in terms of the interface variables, to allow a straightforward coupling with the underlying host structure, which is modeled through a 3D dual boundary element method, for accurate analysis of cracks. The technique is computationa…

HIGH-PRECISION MONTE CARLO DETERMINATION OF α/ν IN THE 3D CLASSICAL HEISENBERG MODEL

1994

To study the role of topological defects in the three-dimensional classical Heisenberg model we have simulated this model on simple cubic lattices of size up to 803, using the single-cluster Monte Carlo update. Analysing the specific-heat data of these simulations, we obtain a very accurate estimate for the ratio of the specific-heat exponent with the correlation-length exponent, α/ν, from a usual finite-size scaling analysis at the critical coupling Kc. Moreover, by fitting the energy at Kc, we reduce the error estimates by another factor of two, and get a value of α/ν, which is comparable in accuracy to best field theoretic estimates.

Reconfigurable waveguides defined by selective fluid filling in two-dimensional phononic metaplates

2022

Abstract We investigate two-dimensional phononic metaplates consisting of a periodic array of cups on a thin epoxy plate that is perforated with periodic cross holes. The cups are individually filled with water or remain empty, in view of creating reconfigurable phononic waveguides. Phononic band gaps exist for empty or filled epoxy cups, leading to waveguides defined with either positive or negative contrast. Straight and 90° bent waveguides are considered experimentally. Lamb waves are excited by a piezoelectric patch glued onto the metaplate and are imaged using a scanning laser vibrometer. Experimental results are compared to a three-dimensional finite element model of fluid–structure i…

Functionalization of Graphene with Molecules and/or Nanoparticles for Advanced Applications

2019

Graphene is considered the material of the third millennium, due to its extraordinary electronic and mechanical properties, and due to the possibility to modulate its conductivity, flexibility, elasticity, transparency, and biocompatibility by bottom-up approach. The possibility to gather the proper- ties of graphene and graphene oxide with those of functional moieties or nanoparticles is herein reviewed. The synthetic approaches proposed, either covalent or noncovalent, are aimed to tune appropriately graphene’s properties for the realization of materials for advanced uses, such as bio- medical applications, sensors, catalysis, and energy devices. In particular, methods based on covalent l…

A framework for evaluating Internet-of-Things platforms: Application provider viewpoint

2014

Widespread adoption of Internet of Things (IoT) applications assumes a sustainable ecosystem of firms creating, distributing, and using these applications. Such an ecosystem often forms around a platform that implements commonly used functionality and offers it to the members of the ecosystem for creating applications and services. In IoT, such a platform may be materialized in a form of a cloud platform that supports the management of connected devices, and the development and use of the applications based on them. A number of cloud platforms targeting IoT applications are available in the market; to prosper, they need to assist the providers of the IoT applications in designing and develo…

Measurement of Head Motion during Double-Poling Technique in Cross-Country Ski Classical Race using Kinematic GNSS

2019

Exploiting Cryo-EM Structural Information and All-Atom Simulations To Decrypt the Molecular Mechanism of Splicing Modulators.

2019

Splicing modulators (SMs) pladienolides, herboxidienes, and spliceostatins exert their antitumor activity by altering the ability of SF3B1 and PHF5A proteins, components of SF3b splicing factor, to recognize distinct intron branching point sequences, thus finely calibrating constitutive/alternative/aberrant splicing of pre-mRNA. Here, by exploiting structural information obtained from cryo-EM data, and by performing multiple μs-long all-atom simulations of SF3b in apo form and in complex with selected SMs, we disclose how these latter seep into the narrow slit at the SF3B1/PHF5A protein interface. This locks the intrinsic open/closed conformational transitions of SFB1's solenoidal structure…

The TES-based cryogenic anticoincidence detector for IXO: First results from large area prototypes

2010

The technique which combines high resolution spectroscopy with imaging capability is a powerful tool to extract fundamental information in X-ray Astrophysics and Cosmology. TES (Transition Edge Sensors)-based microcalorimeters match at best the requirements for doing fine spectroscopy and imaging of both bright (high count rate) and faint (poor signal-to-noise ratio) sources. For this reason they are considered among the most promising detectors for the next high energy space missions and are being developed for use on the focal plane of the IXO (International X-ray Observatory) mission. In order to achieve the required signal-to-noise ratio for faint or diffuse sources it is necessary to r…