Search results for "Argon"

Spatial Diagnostics of Hg/Ar and Hg/Xe Discharge Lamps by Means of Tomography

2011

In this work, the diagnostics using tomography in Hg/Xe and Hg/Ar capillary lamps is presented. First, the imaging of the lamps was performed using selected emission lines of mercury, argon and xenon in different operation conditions. Thus the tomographic reconstruction was made, to determine the spatial distribution of the emitting Hg and rare gas atoms. Significant differences of the distribution of the emitting atoms have been found in vertical and horizontal operation positions. The emitting mercury atoms in the state 73S1 were differently distributed within the lamp in the vertical and horizontal lamp positions. The radial profile has demonstrated a substantial depletion of the popula…

UV laser induced photolysis of glycolic acid isolated in argon matrices

2021

The photochemistry of matrix-isolated glycolic acid, induced by UV light, was studied by FTIR spectroscopy and B3LYPD3/6-311++G(3df,3pd) calculations. Several decomposition pathways were found to take place upon 212 nm and 226 nm wavelengths irradiation. A number of complexes formed between photoproducts were identified, among them those of formaldehyde with water, carbon monoxide and carbon dioxide as well as the H2O-CO complexes. The structure and spectroscopic assignment of the photoproducts were made comparing the experimental results with the theoretical predictions and available literature data. The observed formation of different complexes indicates various pathways for their formati…

RNA-based regulation of transposon expression

2015

Throughout the domains of life, transposon activity represents a serious threat to genome integrity and evolution has realized different molecular mechanisms that aim to inhibit the transposition of mobile DNA. Small noncoding RNAs that function as guides for Argonaute effector proteins represent a key feature of so-called RNA interference (RNAi) pathways and specialized RNAi pathways exist to repress transposon activity on the transcriptional and posttranscriptional level. Transposon transcription can be diminished by targeted DNA methylation or chromatin remodeling via repressive Histone modifications. Posttranscriptional transposon silencing bases on degradation of transposon transcripts…

2015

Piwi-interacting (pi-) RNAs guide germline-expressed Piwi proteins in order to suppress the activity of transposable elements (TEs). But notably, the majority of pachytene piRNAs in mammalian testes is not related to TEs. This raises the question of whether the Piwi/piRNA pathway exerts functions beyond TE silencing. Although gene-derived piRNAs were described many times, a possible gene-regulatory function was doubted due to the absence of antisense piRNAs. Here we sequenced and analyzed piRNAs expressed in the adult testis of the pig, as this taxon possesses the full set of mammalian Piwi paralogs while their spermatozoa are marked by an extreme fitness due to selective breeding. We provi…

La prima apparizione di Circe nella letteratura greca e il fantasma dell' epos argonautico pre-odissiaco

2020

Si cerca di mostrare che l' epos argonautico pre-odissiaco, che, secondo molti studiosi da Kirchhoff in poi avrebbe influenzato l' Odissea, non è mai esistito.

Diagnostics of capillary light sources by means of line shape measurements and modeling

2012

In this work the Hg visible triplet spectral lines were measured by means of Fourier Transform spectrometer and deconvoluted by Tikhonov's regularisation method and line shape modelling. The lines were collected from Hg/Ar and Hg/Xe high frequency capillary lamps. In our previous work, the spatial plasma homogeneity of isotope Hg/Xe and Hg/Ar capillary lamps was investigated by means of tomography. The lamps were operated in different working positions – horizontally and vertically. In this work the spectral diagnostics of capillary light sources by means of spectral line shape measurements and modelling is presented to obtain plasma temperature. The results are compared with the results fo…

Multinucleon transfer reactions: an overview of recent results

2012

Large acceptance magnetic spectrometers, such as PRISMA installed at Laboratori Nazionali di Legnaro, gave a further boost to the renewed interest for multinucleon transfer reactions in the last decade. The large solid angles of these devices and the high resolving powers of their detection systems allowed to investigate the transfer process around and well below the Coulomb barrier and to perform nuclear structure studies in several mass regions of the nuclide chart when coupled with large γ-ray arrays such as CLARA. Selected results obtained with the PRISMA-CLARA set-up in odd argon isotopes populated by using the multinucleon transfer process and in sub- barrier transfer measurements are…

Strong thermal nonequilibrium in hypersonic CO and CH4 probed by CRDS

2015

A new experimental setup coupling a High Enthalpy Source (HES) reaching 2000 K to a cw-cavity ring-down spectrometer has been developed to investigate rotationally cold hot bands of polyatomic molecules in the [1.5, 1.7] μm region. The rotational and vibrational molecular degrees of freedom are strongly decoupled in the hypersonic expansion produced by the HES and probed by cavity ring-down spectroscopy. Carbon monoxide has been used as a first test molecule to validate the experimental approach. Its expansion in argon led to rotational and vibrational temperatures of 6.7 ± 0.8 K and 2006 ± 476 K, respectively. The tetradecad polyad of methane (1.67 μm) was investigated under similar condit…

Sorption Studies on Large ZSM-5 Crystals: The Influence of Aluminium Content, The Type of Exchangeable Cations and the Temperature on Nitrogen Hyster…

1988

Abstract In comparison to polycrystalline powder large ZSM-5 crystals are best suited for high resolution sorption experiments. The nitrogen isotherms on HZSM-5 at 77 K reveal a pronounced hysteresis loop. The shape and position of the hysteresis relative to the pressure axis has been found to be affected by the aluminium content of the zeolite, the type of framework cation and the sorption temperature. The occurence of the hysteresis and its changes are assigned to a transition from a liquidlike to a solid-like adsorbed phase of nitrogen. The micropore volume v mp derived from the argon and nitrogen isotherm (s. Fig. 2b, first plateau) and calculated according to DUBININ-RADUSHKEVICH was c…

Numerical dating of the Eckfeld maar fossil site, Eifel, Germany: a calibration mark for the Eocene time scale.

2000

Sediments of the Eckfeld maar (Eifel, Germany) bear a well-preserved Eocene fauna and flora. Biostratigraphically, Eckfeld corresponds to the Middle Eocene mammal reference level MP (Mammals Paleogene) 13 of the ELMA (European Land Mammal Age) Geiseltalian. In the maar crater, basalt fragments were drilled, representing explosion crater eruption products. By 40Ar/39Ar dating of the basalt, for the first time a direct numerical calibration mark for an Eocene European mammal locality has been established. The Eckfeld basalt inverse isochron date of 44.3 +/- 0.4 Ma suggests an age for the Geiseltalian/Robiacian boundary at 44 Ma and, together with the 1995 time scale of Berggren et al., a time…