Search results for "Arity"

showing 10 items of 2893 documents

Dicopper(II) pyrazolenophanes: Ligand effects on their structures and magnetic properties

2016

Abstract The use of simple pyrazolate anions and related polychelating acyclic or macrocyclic pyrazolate derivatives as bridging ligands, and occasionally additional blocking ligands, has led to the stereospecific Cu II -mediated self-assembly of both homo- and heteroleptic di-μ-pyrazolatodicopper(II) complexes of the metallacyclophane type, so-called dicopper(II) pyrazolenophanes. Besides their unique molecular conformation features and binding abilities toward both neutral molecules and charged anionic species, which have illustrated the putative role of weak intramolecular π–π stacking, hydrogen bonding, and coordinative interactions in the self-assembling process, dicopper(II) pyrazolen…

010405 organic chemistryHydrogen bondStereochemistryChemistryLigandStacking010402 general chemistry01 natural sciencesInductive couplingPlanarity testing0104 chemical sciencesInorganic ChemistryMetalvisual_artIntramolecular forceMaterials Chemistryvisual_art.visual_art_mediumMoleculePhysical and Theoretical ChemistryCoordination Chemistry Reviews
researchProduct

Testing a theoretical resistance law for overland flow on a stony hillslope

2020

Overland flow, sediments, and nutrients transported in runoff are important processes involved in soil erosion and water pollution. Modelling transport of sediments and chemicals requires accurate estimates of hydraulic resistance, which is one of the key variables characterizing runoff water depth and velocity. In this paper, a new theoretical power–velocity profile, originally deduced neglecting the impact effect of rainfall, was initially modified for taking into account the effect of rainfall intensity. Then a theoretical flow resistance law was obtained by integration of the new flow velocity distribution. This flow resistance law was tested using field measurements by Nearing for the …

010504 meteorology & atmospheric sciencesFlow (psychology)rainfall0207 environmental engineering02 engineering and technology01 natural sciencessymbols.namesakeWetted perimeteroverland flowdimensional analysiFroude numberSettore AGR/08 - Idraulica Agraria E Sistemazioni Idraulico-Forestali020701 environmental engineering0105 earth and related environmental sciencesWater Science and Technologyself-similarityReynolds numberLaminar flowstony hillslopeFlow velocityLawsymbolsvelocity profileEnvironmental scienceSurface runoffflow resistanceIntensity (heat transfer)
researchProduct

Spectropolarimetric evidence for a siphon flow along an emerging magnetic flux tube

2016

©2017 The American Astronomical Society. All rights reserved.We study the dynamics and topology of an emerging magnetic flux concentration using high spatial resolution spectropolarimetric data acquired with the Imaging Magnetograph eXperiment on board the sunrise balloon-borne solar observatory. We obtain the full vector magnetic field and the line of sight (LOS) velocity through inversions of the Fe i line at 525.02 nm with the SPINOR code. The derived vector magnetic field is used to trace magnetic field lines. Two magnetic flux concentrations with different polarities and LOS velocities are found to be connected by a group of arch-shaped magnetic field lines. The positive polarity footp…

010504 meteorology & atmospheric sciencesPolarity (physics)photosphere [Sun]FOS: Physical sciencesAstrophysicspolarimetric [Techniques]01 natural sciencesMethods: observational0103 physical sciencesSunriseAstrophysics::Solar and Stellar Astrophysicsobservational [Methods]010303 astronomy & astrophysicsSun: magnetic fieldsSolar and Stellar Astrophysics (astro-ph.SR)0105 earth and related environmental sciencesLine (formation)PhysicsSolar observatoryPolarity symbolsTechniques: polarimetricSun: photosphereAstronomy and AstrophysicsMagnetic fluxMagnetic fieldAstrophysics - Solar and Stellar AstrophysicsFlow (mathematics)magnetic fields [Sun]Space and Planetary Science
researchProduct

Stage–Discharge Relationship for an Upstream Inclined Grid with Transversal Bars

2016

AbstractCheck dams with grids upgrading upstream are often used in mountain rivers, where intense sediment transport and steep slopes occur. In some cases, sloping grids are used in the construction of debris flow breakers. In this paper, the outflow process of an upstream-inclined grid with transversal bars is studied by using the dimensional analysis and the incomplete self-similarity theory. Next, the theoretical analysis shows that a power equation can be used for establishing the stage-discharge equation. The coefficient of the power equation depends on both the slope angle and the void ratio, whereas the exponent depends only on the slope angle. Finally, this deduced stage–discharge r…

010504 meteorology & atmospheric sciencesSelf-similarity0208 environmental biotechnologyGeometryAstrophysics::Cosmology and Extragalactic Astrophysics02 engineering and technologyGrid01 natural sciencesAgricultural and Biological Sciences (miscellaneous)020801 environmental engineeringDebris flowTransversal (combinatorics)Upstream (networking)OutflowGeotechnical engineeringStage (hydrology)Sediment transportGeology0105 earth and related environmental sciencesWater Science and TechnologyCivil and Structural EngineeringJournal of Irrigation and Drainage Engineering
researchProduct

Introducing the Human Factor in Predictive Modelling: a Work in Progress

2012

International audience; In this paper we present the results of a study into integrating socio-cultural factors into predictive modelling. So far, predictive modelling has largely neglected the social and cultural dimensions of past landscapes. To maintain its value for archaeological research, therefore, it needs new methodologies, concepts and theories. For this study, we have departed from the methodology developed in the 1990s during the Archaeomedes Project. In this project, cross-regional comparisons of settlement location factors were made by analyzing the environmental context of Roman settlements in the French Rhône Valley. For the current research, we expanded the set of variables…

010506 paleontologyOperations researchregional comparison[SHS.ARCHEO]Humanities and Social Sciences/Archaeology and PrehistoryComputer sciencefacteurs socio-culturelsSubject (philosophy)0211 other engineering and technologies02 engineering and technology01 natural sciencesdiachronic comparisonCultural heritage managementcomparaison diachronique0601 history and archaeology0105 earth and related environmental sciences021101 geological & geomatics engineeringcomparaison régionale[SHS.ARCHEO] Humanities and Social Sciences/Archaeology and Prehistory060102 archaeologyPredictive modellingRoman period.Cultural resources managementpériode romaine.06 humanities and the artsWork in processPopularityEpistemologysocio-cultural factors[ SHS.ARCHEO ] Humanities and Social Sciences/Archaeology and PrehistoryCriticismArchaeological heritageModélisation prédictivePredictive modelling
researchProduct

The space-time relationship of taxonomic diversity and morphological disparity in the Middle Jurassic ammonite radiation.

2007

14 pages; International audience; The Middle Jurassic ammonite radiation (from the late Aalenian to the end of the mid-Bathonian) is traced using combined analyses of morphological disparity and taxonomic diversity. The global signals of disparity and diversity are compared. These signals are then broken down by paleogeographical provinces to detect any heterogeneity in the radiation. An examination of the global signals reveals three biodiversity crises (discordances between signals) where morphological disparity grows while taxonomic diversity declines. The subdivision of the signals indicates the radiation was heterogeneous between provinces: the global signal is an aggregate of signals …

010506 paleontologyTaxonomic diversitymedia_common.quotation_subjectBiodiversity[SDV.BID]Life Sciences [q-bio]/BiodiversityJurassic010502 geochemistry & geophysicsOceanography01 natural sciencesPaleontologyAmmonitesPalaeogeographyEcology Evolution Behavior and Systematics0105 earth and related environmental sciencesEarth-Surface ProcessesSubdivisionmedia_common[ SDU.STU.PG ] Sciences of the Universe [physics]/Earth Sciences/PaleontologyAmmonite[ SDV.BID ] Life Sciences [q-bio]/Biodiversitybusiness.industrySpace timePaleontologylanguage.human_languagePaleogeographylanguagebusiness[SDU.STU.PG]Sciences of the Universe [physics]/Earth Sciences/PaleontologyGeologyDiversity (politics)Morphological disparity
researchProduct

Comparing pollen spectra from modified Tauber traps and moss samples: examples from a selection of woodlands across Europe

2010

This paper compares pollen spectra derived from modified Tauber traps and moss samples from a selection of woodland types from Bulgaria, the Czech Republic, Georgia, Greece, Poland, Switzerland and Wales. The study examines the representation of individual taxa in the two sampling media and aims to ascertain the duration of pollen deposition captured by a moss. The latter aim was pursued through the calculation of dissimilarity indexes to assess how many years of pollen deposited in a pollen trap yield percentage values that are most similar to those obtained from the moss. The results are broadly scattered; the majority of moss samples being most similar to several years of pollen depositi…

0106 biological sciences010506 paleontologyArcheologyWoodlandPlant ScienceBiostratigraphy580 Plants (Botany)medicine.disease_causeMoss sample; Modified Tauber trap; Surface pollen deposition; Collecting efficiency; Representation of tree taxa; Dissimilarity measures010603 evolutionary biology01 natural sciencesPollenBotanymedicineHolocene0105 earth and related environmental sciencesbiologyPalaeontologyPaleontologySediment15. Life on landbiology.organism_classificationMossDeposition (aerosol physics)Environmental scienceWoody plant
researchProduct

Gauging scale effects and biogeographical signals in similarity distance decay analyses: an Early Jurassic ammonite case study.

2016

17 pages; International audience; In biogeography, the similarity distance decay (SDD) relationship refers to the decrease in compositional similarity between communities with geographical distance. Although representing one of the most widely used relationships in biogeography, a review of the literature reveals that: (1) SDD is influenced by both spatial extent and sample size; (2) the potential effect of the phylogenetic level has yet to be tested; (3) the effect of a marked biogeographical structuring upon SDD patterns is largely unknown; and (4) the SDD relationship is usually explored with modern, mainly terrestrial organisms, whereas fossil taxa are seldom used in that perspective. U…

0106 biological sciences010506 paleontologyBiogeographyscale effectsContext (language use)Biology010603 evolutionary biology01 natural sciences[ SDE ] Environmental SciencesPaleontologySimilarity (network science)Geographical distanceprovincialismEcology Evolution Behavior and Systematicsbiogeography0105 earth and related environmental sciences[ SDU.STU.PG ] Sciences of the Universe [physics]/Earth Sciences/PaleontologyAmmoniteammonitesPhylogenetic treePaleontologyPliensbachianlanguage.human_languageTaxonsimilarity distance decay[SDE]Environmental ScienceslanguageBiological dispersal[SDU.STU.PG]Sciences of the Universe [physics]/Earth Sciences/Paleontology
researchProduct

Categorical versus geometric morphometric approaches to characterizing the evolution of morphological disparity in Osteostraci (Vertebrata, stem Gnat…

2020

Morphological variation (disparity) tends to be evaluated through two non-mutually exclusive approaches: (i) quantitatively, through geometric morphometrics, and (ii) in terms of discrete, ‘cladistic’, or categorical characters. Uncertainty over the comparability of these approaches diminishes the potential to obtain nomothetic insights into the evolution of morphological disparity, and the few benchmarking studies conducted so far show contrasting results. Here, we apply both approaches to characterising morphology in the stem-gnathostome vertebrate clade Osteostraci, in order to assess congruence between these alternative methods as well as to explore the evolutionary patterns of the grou…

0106 biological sciences010506 paleontologyMSci Palaeontology and Evolution/dk/atira/pure/core/keywords/msci_palaeontology_and_evolutionPaleontologia010603 evolutionary biology01 natural sciencesPaleontologyF600 GeologyCladegeometric morphometricsCategorical variableEcology Evolution Behavior and Systematics0105 earth and related environmental sciencesMorphometricsC181 BiodiversityC300 ZoologybiologyPhylogenetic treeC182 EvolutionPaleontologyGnathostomataF641 PalaeontologyC191 Biometrybiology.organism_classificationOsteostraciOsteostracimorphospaceOrder (biology)disparityEvolutionary biologycategorical dataNomotheticPalaeontology
researchProduct

Assessing metabolic constraints on the maximum body size of actinopterygians: locomotion energetics of Leedsichthys problematicus (Actinopterygii, Pa…

2018

Maximum sizes attained by living actinopterygians are much smaller than those reached by chondrichthyans. Several factors, including the high metabolic requirements of bony fishes, have been proposed as possible body‐size constraints but no empirical approaches exist. Remarkably, fossil evidence has rarely been considered despite some extinct actinopterygians reaching sizes comparable to those of the largest living sharks. Here, we have assessed the locomotion energetics of Leedsichthys problematicus, an extinct gigantic suspension‐feeder and the largest actinopterygian ever known, shedding light on the metabolic limits of body size in actinopterygians and the possible underlying factors th…

0106 biological sciences010506 paleontologyPachycormiformesbiologyRange (biology)Lineage (evolution)EnergeticsActinopterygiiPaleontologyPaleontologiamedicine.diseasebiology.organism_classification010603 evolutionary biology01 natural sciencesGigantismPaleontologyLeedsichthysEvolutionary biologymedicineOviparityEcology Evolution Behavior and Systematics0105 earth and related environmental sciences
researchProduct