Search results for "Arsenate"

Inorganic Phosphate and Arsenate within New Tetranuclear Copper and Zinc Complexes: Syntheses, Crystal Structures, Magnetic, Electrochemical, and The…

2017

Three, PO43–/HPO42– and AsO43–-incorporated, new tetranuclear complexes of copper(II) and zinc(II) ions have been synthesized and fully characterized. In methanol–water, reactions of H3cpdp (H3cpdp = N,N′-Bis[2-carboxybenzomethyl]-N,N′-Bis[2-pyridylmethyl]-1,3-diaminopropan-2-ol) with copper(II) chloride in the presence of either NaOH/Na2HPO4·2H2O or KOH/Na2HAsO4·7H2O lead to the isolation of the tetranuclear complexes Na3[Cu4(cpdp)2(μ4-PO4)](OH)2·14H2O (1) and K2[Cu4(cpdp)2(μ4-AsO4)](OH)·162/3H2O (2), respectively. Similarly, the reaction of H3cpdp with zinc(II) chloride in the presence of NaOH/Na2HPO4·2H2O yields a tetranuclear complex, Na(H3O)2[Zn4(cpdp)2(μ4-HPO4)]Cl3·121/2H2O (3). All c…

Bioaccessibility of inorganic arsenic species in raw and cookedHizikia fusiformeseaweed

2004

Samples of Hizikia fusiforme edible seaweed, a commercially available dried food with high concentrations of total arsenic (t-As) and inorganic arsenic (i-As), both raw and cooked (boiling at 100 °C, 20 min), were selected for the bioaccessibility study. Cooking caused a significant reduction in the concentrations of t-As (30–43%) and i-As (46–50%), despite which the i-As contents in the cooked product were high (42.7–44.6 µg g−1 seaweed). An in vitro gastrointestinal digestion (pepsin, pH 2, and pancreatin–bile extract, pH 7) was applied to the seaweed to estimate arsenic bioaccessibility (maximum soluble concentration in gastrointestinal medium) of t-As, i-As, arsenic(III) and arsenic(V).…

ChemInform Abstract: Synthesis, Structure, and Properties of BaVO2(AsO4): A New Vanadium Arsenate Containing the V2O2+4 Core.

2010

Use of peat-based sorbents for removal of arsenic compounds

2013

Abstract It is important to apply sorbent materials for purification of water from arsenic contamination due to serious arsenic pollution worldwide. We have developed new sorbents based on natural materials that provide a cheap and environmentally friendly alternative. For the first time, peat modified with iron compounds and iron humates were tested for sorption of arsenic compounds. The highest sorption capacity was found in peat modified with iron compounds. We have found that sorption of different arsenic speciation forms was strongly dependent on solution pH, reaction time and temperature. Calculations of the sorption process using thermodynamic parameters indicate the spontaneity of s…