Search results for "Atom"
showing 10 items of 31559 documents
The high overtone and combination levels of SF6 revisited at Doppler-limited resolution: A global effective rovibrational model for highly excited vi…
2017
Abstract Sulfur hexafluoride is an important prototypal molecule for modeling highly excited vibrational energy flow and multi quanta absorption processes in hexafluoride molecules of technological importance. It is also a strong greenhouse gas of anthropogenic origin. This heavy species, however, features many hot bands at room temperature (at which only 30% of the molecules lie in the ground vibrational state), especially those originating from the lowest, v 6 =1 vibrational state. Using a cryogenic long path cell with variable optical path length and temperatures regulated between 120 and 163 K, coupled to Synchrotron Radiation and a high resolution interferometer, Doppler-limited spectr…
Steroid Biomarkers Revisited - Improved Source Identification of Faecal Remains in Archaeological Soil Material.
2017
Steroids are used as faecal markers in environmental and in archaeological studies, because they provide insights into ancient agricultural practices and the former presence of animals. Up to now, steroid analyses could only identify and distinguish between herbivore, pig, and human faecal matter and their residues in soils and sediments. We hypothesized that a finer differentiation between faeces of different livestock animals could be achieved when the analyses of several steroids is combined (Δ5-sterols, 5α-stanols, 5β-stanols, epi-5β-stanols, stanones, and bile acids). We therefore reviewed the existing literature on various faecal steroids from livestock and humans and analysed faeces …
Evaluation of the S-NPP VIIRS land surface temperature product using ground data acquired by an autonomous system at a rice paddy
2018
Abstract The S-NPP VIIRS Land Surface Temperature (LST) product attained the stage V1 of validation maturity (provisional validated) at the end of 2014. This paper evaluates the current VIIRS V1 LST product versus concurrent ground data acquired at a rice paddy site from December 2014 to August 2016. The experimental site has three different seasonal and homogeneous land covers through the year, which makes the site interesting for validation activities. An autonomous and multiangular system was used to record continuous ground data at the site. The data acquired at zenith angles similar to the VIIRS viewing angles were used for the validation to avoid possible differences between satellite…
An expanded model and application of the combined effect of crystal-size distribution and crystal shape on the relative viscosity of magmas
2018
International audience; This study examines the combined effect of crystal-size distributions (CSD) and crystal shape on the rheology of vesicle free magmatic suspensions and provides the first practical application of an empirical model to estimate the relative effect of crystal content and CSD's on the viscosity of magma directly from textural image analysis of natural rock samples in the form of a user-friendly texture-rheology spreadsheet calculator. We extend and apply established relationships between the maximum packing fraction ϕm of a crystal bearing suspension and both its rheological properties and the polydispersity γ of a CSD. By using analogue rotational rheometric experiments…
Remote sensing algorithms for estimation of fractional vegetation cover using pure vegetation index values: A review
2020
Abstract Green fractional vegetation cover ( f c ) is an important phenotypic factor in the fields of agriculture, forestry, and ecology. Spatially explicit monitoring of f c via relative vegetation abundance (RA) algorithms, especially those based on scaled maximum/minimum vegetation index (VI) values, has been widely investigated in remote sensing research. Although many studies have explored the effectiveness of RA algorithms over the past 30 years, a literature review summarizing the corresponding theoretical background, issues, current state-of-the-art techniques, challenges, and prospects has not yet been published. The overall objective of the present study was to accomplish a compre…
High‐resolution stimulated Raman spectroscopy and analysis of line positions and assignments for the ν 2 and ν 3 bands of 13 C 2 H 4
2016
High-resolution stimulated Raman spectra of13C2H4 in the regions of the ν2 and ν3 Raman active modes have been recorded at two temperatures (145 and 296 K) based on the quasi continuous-wave (cw) stimulated Raman spectrometer at Instituto de Estructura de la Materia IEM-CSIC in Madrid. A tensorial formalism adapted to X2Y4 planar asymmetric tops with D2h symmetry (developed in Dijon) and a program suite called D2hTDS (now part of the XTDS/SPVIEW spectroscopic software) were proposed to analyze and calculate the high-resolution spectra. A total of 103 and 51 lines corresponding to ν2 and ν3 Raman active modes have been assigned and fitted in wavenumber with a global root mean square deviatio…
Impulsive coronal heating from large-scale magnetic rearrangements: from IRIS to SDO/AIA
2019
The Interface Region Imaging Spectrograph (IRIS) has observed bright spots at the transition region footpoints associated with heating in the overlying loops, as observed by coronal imagers. Some of these brightenings show significant blueshifts in the Si iv line at 1402.77 A (logT[K] = 4.9). Such blueshifts cannot be reproduced by coronal loop models assuming heating by thermal conduction only, but are consistent with electron beam heating, highlighting for the first time the possible importance of non-thermal electrons in the heating of non-flaring active regions. Here we report on the coronal counterparts of these brightenings observed in the hot channels of the Atmospheric Imaging Assem…
Observation of classically 'forbidden' electromagnetic wave propagation and implications for neutrino detection.
2018
Ongoing experimental efforts in Antarctica seek to detect ultra-high energy neutrinos by measurement of radio-frequency (RF) Askaryan radiation generated by the collision of a neutrino with an ice molecule. An array of RF antennas, deployed either in-ice or in-air, is used to infer the properties of the neutrino. To evaluate their experimental sensitivity, such experiments require a refractive index model for ray tracing radio-wave trajectories from a putative in-ice neutrino interaction point to the receiving antennas; this gives the degree of signal absorption or ray bending from source to receiver. The gradient in the density profile over the upper 200 meters of Antarctic ice, coupled wi…
Nitrogen broadening of SF6 transitions in the nu3 band
2001
Abstract Nitrogen induced pressure-broadened halfwidths of a number of ν3 transitions of SF6 are calculated using the complex Robert–Bonamy (CRB) formalism. The calculations are made at 200, 250, 296 and 350 K and the temperature dependence of the halfwidths are determined. The intermolecular potential is taken as a sum of the leading electrostatic and Lennard-Jones [6] , [7] , [8] , [9] , [10] , [11] , [12] atom–atom components. The dynamics of the collision process are correct to second order in time. The calculated halfwidths are used to simulate the ν3 spectrum, which is compared to a simulation made using the HITRAN96 halfwidths and measurements made at the Universite Pierre et Marie C…
Line parameters and shapes of high clusters: R-branch of the nu3 band of CH4 in He mixtures
2002
International audience; The IR absorption spectra of CH4 in pure gas and in mixture with helium were studied in the region of nu3 band at higher J line clusters R(17)-R(22). The frequencies and intensities of rotation-vibration lines were estimated from the experimental spectra at Doppler shape conditions. The line frequencies and intensities were calculated and used for the attribution of overlapped lines in clusters. The calculated line intensities are close to the experimental values. The calculated frequency structure of the higher J manifolds are somewhat wider than the observed one. The shapes of helium-broadened line clusters were compared with those calculated accounting for line mi…