Search results for "Authigenic"
showing 10 items of 35 documents
Integrative analysis of the mineralogical and chemical composition of modern microbialites from ten Mexican lakes: What do we learn about their forma…
2021
International audience; Interpreting the environmental conditions under which ancient microbialites formed relies upon comparisons with modern analogues. This is why we need a detailed reference framework relating the chemical and mineralogical compositions of modern microbialites to the physical and chemical parameters prevailing in the environments where they form. Here, we measured the chemical, including major and trace elements, and mineralogical composition of microbialites from ten Mexican lakes as well as the chemical composition of the surrounding waters. Saturation states of lakes with different mineral phases were systematically determined and correlations between solution and so…
The behaviour of zirconium, hafnium and rare earth elements during the crystallisation of halite and other salt minerals
2017
Abstract Halite crystals from Messinian and Tortonian evaporites from Sicily and Spain and current precipitated halite crystals and the relative parent brines (active evaporation systems) were investigated in order to evaluate the Zr, Hf and Rare Earth Element (REE) behaviour. Halite crystallisation from evaporating brines fractionates Zr, Hf and REE through a two-step process. During the first step, dissolved complexes of studied elements are scavenged onto the surfaces of crystallising halite. During the second step, elements are co-precipitated into the crystal lattice as it grows. The first step mechanism is determined by the dissolved REE speciation. In saltworks where carbonate-REE co…
North Atlantic Oscillation recorded in carbonate δ18O signature from Lagunillo del Tejo (Spain)
2016
Abstract Oxygen (δ18O) and carbon (δ13C) isotope compositions of authigenic carbonates measured in Lagunillo del Tejo sediment document precipitation variability during the last millennium in the Iberian Range. Modern water samples show that Lagunillo δ18O and δD plot below the Global Meteoric Water Line (GMWL). Sediment samples show a covariant trend between carbonate δ18O and δ13C, indicating that the precipitation/evaporation ratio has largely controlled the isotopic composition of this lake. This covariant trend is used to extract information about past lake level changes. Humid periods occurred around AD 1300–1450, AD 1620–1775 and AD 1950–1980, while the driest periods were concentrat…
Diagenesis of clay minerals and K-bentonites in Late Permian/Early Triassic sediments of the Sichuan Basin (Chaotian section, Central China).
2014
10 pages; International audience; Detailed clay mineralogical analyses were carried out on Late Permian/Early Triassic carbonate sediments exposed on the Chaotian section (Sichuan Basin, Central China). The clay assemblages are dominantly composed of illite in platform carbonates and clay seams, and illite-smectite mixed-layers (I/S) in tuff layers (K-bentonites) intercalated in the carbonate succession. Detrital and authigenic volcanogenic clay minerals have been partially replaced through illitisation processes during burial, raising questions about diagenetic effects. The precise determination of I/S occurring in K-bentonites shows that the sediments reached a temperature of about 180 °C…
Influence of dissolved organic matter on rare earth elements and yttrium distributions in coastal waters
2010
International audience; Data collected during this study indicate that dissolved Y and REE (rare earth element) behaviour can be monitored through shale-normalised ratios. Relationships occurring between these ratios suggest that leaching from lithogenic materials is the main source of REE in the studied area. This process involves riverine detrital matter in the inner area of the Gulf of Palermo. Features of shale-normalised patterns and the relationship recognised between dissolved Fe and Y/Ho suggest that REE are released from Fe-rich coatings of atmospheric dust. Observed similarities between dissolved Fe and chlorophyll- content suggest that leaching of Fe-rich atmospheric particulates…
Carbon, iron and sulphur cycling in the sediments of a Mediterranean lagoon (Ghar El Melh, Tunisia)
2019
Coastal lagoon sediments are important for the biogeochemical carbon cycle at the land-ocean transition, as they form hotspots for organic carbon burial, as well as potential sites for authigenic carbonate formation. Here, we employ an early diagenetic model to quantify the coupled redox cycling of carbon, iron and sulphur in the sediments of the shallow Ghar El Melh (GEM) lagoon (Tunisia). The model simulated depth profiles show a good correspondence with available pore water data (dissolved inorganic carbon, NH 4 + , total alkalinity, Ca 2+ , Fe 2+ and SO 4 2− ) and solid phase data (organic matter, pyrite, calcium carbonate and iron (oxyhydr)oxides). This indicates that the model is abl…
Petrography and carbonate isotope stratigraphy from MIS AND-1B core, Antarctica: Evidence of the early Pliocene warming event
2011
Abstract A large portion of ANDRILL (ANtarctic geological DRILLing) core AND-1B recovered in the Western Ross Sea and spanning the early Pliocene has been investigated in order to obtain a detailed carbonate isotope record from Antarctic margin sediments through the early Pliocene warming event. Petrographic observations and mineralogical analyses reveal the authigenic nature of the carbonate and small proportions of Fe and Mg incorporated within the calcite lattice. High productivity conditions testified by ~ 80 m-thick diatomite interval (383 to 460 mbsf) well fit with the composite nature of the authigenic carbonate generally characterizing organic matter-rich sediments. As is known, sed…
Geochemistry of REE, Zr and HF in a wide range of pH and water composition: The Nevado del Ruiz volcano hydrothermal system (Colombia)
2015
International audience; The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidic waters are sulphate dominated with different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr and Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters.Y–Ho and Z…
Distribution of clay minerals in Early Jurassic Peritethyan seas: palaeoclimatic significance inferred from multiproxy comparisons.
2009
13 pages; International audience; A set of published, unpublished, and new clay mineral data from 60 European and Mediterranean localities allows us to test the reliability of clay minerals as palaeoclimatic proxies for the Pliensbachian–Toarcian period (Early Jurassic) by reconstructing spatial and temporal variations of detrital fluxes at the ammonite biochronozone resolution. In order to discuss their palaeoclimatic meaning, a compilation of low-latitude belemnite δ18O, δ13C, Mg/Ca, and 87Sr/86Sr values is presented for the first time for the whole Pliensbachian– Toarcian period. Once diagenetic and authigenic biases have been identified and ruled out, kaolinite content variation is cons…
Transition from marine to hypersaline conditions in the Messinian Tripoli Formation from the marginal areas of the central Sicilian Basin
2001
Abstract Three sections of the early Messinian Tripoli Formation from the northern and southern margins of the central Sicilian Basin (Serra Pirciata, Torrente Vaccarizzo, and Marianopoli) have been studied with the aim to reconstruct the sedimentary and environmental changes which occurred during the transition between marine conditions and the evaporitic events of the Salinity Crisis recorded in the overlying Calcare di Base Formation. A detailed biostratigraphic and cyclostratigraphic study provided the opportunity of cycle-by-cycle correlations between the marginal sections and the reference section of Falconara. The main paleoenvironmental changes are recorded by: (1) the evolution of …