Search results for "Azolium salt"

showing 8 items of 78 documents

SYNTHESIS AND CHARACTERIZATION OF POSITIVELY CHARGED FUNCTIONALIZED HALLOYSITE/CURCUMIN SYSTEMS AND EVALUATION OF THEIR ANTICANCER ACTIVITY

2014

Phenolic compound originated from one of the main class of secondary metabolites, as curcumin and its derivatives have been studied and their biological and pharmacological activities have been evaluated, too [1,2]. Unfortunately, curcumin exhibits poor bioavailability after oral or topic administration [3]. Therefore a carefully designed carrier could significantly facilitate curcumin delivery and broaden the range of its possible pharmaceutical applications. Halloysite was found to be a viable and inexpensive nanoscale container for the encapsulation of biological active molecules [4]. In this communication we report data about a new potential curcumin carrier based on positively charged …

halloysite triazolium salt curcumin anticancer activity
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Fluorescent supramolecular hydrogels for biomedical applications

2019

hydrogels imidazolium salts supramolecular gels bioimaging anticancer activity
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Organogel formed by imidazolium salts: molecular recognition processes

imidazolium salts organogel supramolecular chemistrySettore CHIM/06 - Chimica Organica
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Cross-Linked Imidazolium Salts as Scavengers for Palladium.

2014

Five imidazolium-based materials have been synthesised and used for the first time as palladium scavengers. Radical reactions of suitable bis-vinylimidazolium salts led to a series of insoluble materials through homo-polymerisation, immobilisation with a 3-mercaptopropyl-modified silica gel or co-polymerisation with ethylene glycol dimethylacrylate. These materials were screened as palladium scavengers with a set of palladium(0) and palladium(II) compounds in different solvents and at different starting amounts of palladium. In many cases, residual amounts of palladium were lower than 5 ppm, as requested for the manufacture of active pharmaceutical ingredients and fine chemicals. The applic…

inorganic chemicalsActive ingredientSilica gelchemistry.chemical_elementGeneral ChemistrySettore CHIM/06 - Chimica OrganicaScavenger (chemistry)chemistry.chemical_compoundchemistrySuzuki reactionIonic liquidOrganic chemistryEthylene glycolcross-coupling imidazolium salts ionic liquids palladium supported catalystsPalladiumChemPlusChem
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Antifouling Systems Based on a Polyhedral Oligomeric Silsesquioxane-Based Hexyl Imidazolium Salt Adsorbed on Copper Nanoparticles Supported on Titania

2023

The reaction of octakis(3-chloropropyl)octasilsesquioxane with four equivalents of 1-hexylimidazole or 1-decylimidazole gave two products labelled as HQ-POSS (hexyl-imidazolium quaternized POSS) and DQ-POSS (decyl-imidazolium quaternized POSS) as regioisomer mixtures. An investigation of the biological activity of these two compounds revealed the higher antimicrobial performances of HQ-POSS against Gram-positive and Gram-negative microorganisms, proving its broad-spectrum activity. Due to its very viscous nature, HQ-POSS was adsorbed in variable amounts on the surface of biologically active oxides to gain advantages regarding the expendability of such formulations from an applicative perspe…

marine biofouling; polyhedral oligomeric silsesquioxane; imidazolium salt; copper nanoparticles; titaniaGeneral Chemical Engineeringpolyhedral oligomeric silsesquioxanecopper nanoparticlesmarine biofoulingGeneral Materials SciencetitaniaSettore CHIM/06 - Chimica OrganicaSettore BIO/19 - Microbiologia Generaleimidazolium salt
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Dexrazoxane shows cytoprotective effects in zoledronic acid-treated human cells in vitro and in the rabbit tibia model in vivo

2012

Abstract Introduction Bisphosphonates are important and effective drugs in oncology and osteoporosis therapy. They accumulate in the bone matrix becoming released and active by bone resorption. This leads to effective inhibition of tumor cells and bone degradation. A side effect of bisphosphonates similar to other drugs like denosumab is osteonecrosis of the jaws (ONJ). This problem mostly occurs after tooth extraction. We studied the cytoprotectant dexrazoxane known from anthracycline chemotherapy for cytoprotection in nitrogen-containing bisphosphonate treated cells and in the rabbit tibia model to evaluate a possible value in ONJ management. Materials & methods Human osteoblasts (HOB) P2…

medicine.medical_treatmentOsteoporosisCell Culture TechniquesGingivaTetrazolium SaltsApoptosisPharmacologyCell morphologyZoledronic AcidOsteogenesisColoring AgentsDrug CarriersBone Density Conservation AgentsDiphosphonatesImidazolesFluoresceinsResorptionDenosumabModels AnimalFemaleCollagenRabbitsOral SurgeryRazoxanemedicine.drugmedicine.medical_specialtyCell SurvivalProtective AgentsBone resorptionCell LinemedicineAnimalsHumansBone ResorptionCell ShapeFluorescent DyesOsteoblastsTibiabusiness.industryFibroblastsBisphosphonatemedicine.diseaseSurgeryThiazolesDurapatiteZoledronic acidOtorhinolaryngologyCytoprotectionSurgeryDexrazoxanebusinessJournal of Cranio-Maxillofacial Surgery
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Two component chiral gels: a study of properties and behavior as recognition systems

organogels diimidazolium salts chiral recognitionSettore CHIM/06 - Chimica Organica
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Host-guest interactions between DMpillar[5]arene and fluorescent imidazolium salts

pillar[n]arenes imidazolium salts host-guest complexesSettore CHIM/06 - Chimica Organica
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