Search results for "Azulen"

showing 10 items of 24 documents

CCDC 1937082: Experimental Crystal Structure Determination

2019

Related Article: Stephen S. Nyandoro, Gasper Maeda, Joan J.E. Munissi, Amra Gruhonjic, Paul A. Fitzpatrick, Sofia Lindblad, Sandra Duffy, Jerry Pelletier, Fangfang Pan, Rakesh Puttreddy, Vicky M. Avery, Máté Erdélyi|2019|Molecules|24|2746|doi:10.3390/molecules24152746

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2-(38-dimethyl-12345678-octahydroazulen-5-yl)propan-2-olExperimental 3D Coordinates
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CCDC 1048445: Experimental Crystal Structure Determination

2015

Related Article: Í. Çelik, M. Akkurt, H. Akşit, R. Erenler, S. García-Granda|2015|Acta Crystallogr.,Sect.E:Cryst.Commun.|71|1425|doi:10.1107/S2056989015019623

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters34-Dihydroxy-3-(hydroxymethyl)-9-methyl-6-methyleneoctahydroazuleno[45-b]furan-28(3H4H)-dioneExperimental 3D Coordinates
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CCDC 1029369: Experimental Crystal Structure Determination

2015

Related Article: Adrian E. Ion, Simona Nica, Augustin M. Madalan, Sergiu Shova, Julia Vallejo, Miguel Julve, Francesc Lloret, Marius Andruh|2015|Inorg.Chem.|54|16|doi:10.1021/ic5025197

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-44'-Azulene-13-diyldipyridine)-bis(mu2-44'-bipyridine)-bis(NN-dimethylformamide)-tetrakis(isothiocyanato)-di-cobalt methanol solvate dihydrate]Experimental 3D Coordinates
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CCDC 1029370: Experimental Crystal Structure Determination

2015

Related Article: Adrian E. Ion, Simona Nica, Augustin M. Madalan, Sergiu Shova, Julia Vallejo, Miguel Julve, Francesc Lloret, Marius Andruh|2015|Inorg.Chem.|54|16|doi:10.1021/ic5025197

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-44'-Azulene-13-diyldipyridine)-bis(mu2-44'-ethene-12-diyldipyridine)-bis(NN-dimethylformamide)-tetrakis(isothiocyanato)-di-cobalt hydrate]Experimental 3D Coordinates
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CCDC 949947: Experimental Crystal Structure Determination

2013

Related Article: Adrian E. Ion, Simona Nica, Augustin M. Madalan, Catalin Maxim, Miguel Julve, Francesc Lloret, Marius Andruh|2014|CrystEngComm|16|319|doi:10.1039/C3CE41592A

Space GroupCrystallographycatena-[(mu~2~- 44'-Azulene-13-diyldipyridine)-(22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(nitrato)-gadolinium-nickel acetonitrile solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 910383: Experimental Crystal Structure Determination

2013

Related Article: Y.Inokuma,S.Yoshioka,J.Ariyoshi,T.Arai,Y.Hitora,K.Takada,S.Matsunaga,K.Rissanen,M.Fujita|2013|Nature (London)|495|461|doi:10.1038/nature11990

Space GroupCrystallographycatena-[bis(bis(mu~3~-246-tris(Pyridin-4-yl)-135-triazine)-hexakis(iodo)-tri-zinc(ii)) 7-isopropyl-14-dimethylazulene clathrate unknown solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 910382: Experimental Crystal Structure Determination

2013

Related Article: Y.Inokuma,S.Yoshioka,J.Ariyoshi,T.Arai,Y.Hitora,K.Takada,S.Matsunaga,K.Rissanen,M.Fujita|2013|Nature (London)|495|461|doi:10.1038/nature11990

Space GroupCrystallographycatena-[bis(mu3-246-tris(Pyridin-4-yl)-135-triazine)-hexakis(iodo)-tri-zinc(ii) 7-isopropyl-14-dimethylazulene clathrate unknown solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Protonenvermittelter Ringschluss eines negativ photochromen, Azulen‐basierten Diarylethens

2020

Auf Protonen ansprechende photochrome Moleküle sind aufgrund ihrer Fähigkeit, auf nicht-invasive schnelle optische Stimuli zu reagieren, und wegen der ubiquitären Bedeutung von Protonierungs- und Deprotonierungsprozessen, sehr interessant. Üblicherweise befinden sich die sauren/basischen Stellen dieser Moleküle an Heteroatomen, die orthogonal zum photoaktiven π-Zentrum ausgerichtet sind. In dieser Arbeit wird Azulen, ein protonensensitiver reiner Kohlenwasserstoff, in das Gerüst eines Diarylethen-Photoschalters eingebaut. Dieser zeigt einen bisher ungekannten, protonenvermittelten, negativ photochromen Ringschluss. Veränderungen seiner optischen Eigenschaften durch Protonierung, sowohl in d…

Säure-Base-Gleichgewicht010405 organic chemistryChemistryGeneral Medicine010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesAzulen540 Chemie und zugeordnete WissenschaftenNegative Photochromieddc:540ddc:660PhotochemieDiarylethen
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Chamazulene-Rich Artemisia arborescens Essential Oils Affect the Cell Growth of Human Melanoma Cells

2020

Artemisia arborescens is an aromatic shrub whose essential oils are considered a potential source of molecules with industrial and pharmaceutical interest. The chemical profile of A. arborescens essential oils (EOs) was shown to be quite variable and various chemotypes have been identified. In this study, we compared the EOs composition of A. arborescens leaves and flowers collected from four different locations in Sicily. The EOs were assayed for their antiproliferative activity against A375 human malignant melanoma cells, also testing cell viability and cell membrane integrity. The evaluation of DNA fragmentation and caspase-3 activity assay was employed for the detection of apoptosis. Th…

antiproliferative activitymelanoma cancer cellArtemisia arborescensPlant ScienceArticleessential oillaw.inventionSuperoxide dismutase03 medical and health scienceschemistry.chemical_compound0302 clinical medicinemelanoma cancer cellslawcamphor<i>Artemisia arborescens</i>Viability assayEcology Evolution Behavior and SystematicsEssential oil030304 developmental biology0303 health sciencesEcologybiologyChemistryCell growthChamazuleneBotanychamazuleneArtemisia arborescensbiology.organism_classificationBiochemistryApoptosis030220 oncology & carcinogenesisQK1-989Artemisia arborescenbiology.proteinDNA fragmentationPlants
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Proton‐Gated Ring‐Closure of a Negative Photochromic Azulene‐Based Diarylethene

2020

Abstract Proton‐responsive photochromic molecules are attractive for their ability to react on non‐invasive rapid optical stimuli and the importance of protonation/deprotonation processes in various fields. Conventionally, their acidic/basic sites are on hetero‐atoms, which are orthogonal to the photo‐active π‐center. Here, we incorporate azulene, an acid‐sensitive pure hydrocarbon, into the skeleton of a diarylethene‐type photoswitch. The latter exhibits a novel proton‐gated negative photochromic ring‐closure and its optical response upon protonation in both open and closed forms is much more pronounced than those of diarylethene photoswitches with hetero‐atom based acidic/basic moieties. …

azulenenegative photochromismProtonation010402 general chemistryPhotochemistry01 natural sciencesCatalysischemistry.chemical_compoundPhotochromismDeprotonationDiaryletheneMoleculeMolecular switchphotochemistryPhotoswitch010405 organic chemistryCommunicationPhotoswitchesGeneral ChemistryAzuleneCommunications3. Good health0104 chemical sciences540 Chemie und zugeordnete Wissenschaftenchemistryacid-base equilibriaddc:540diarylethene
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