Search results for "BAND"
showing 10 items of 2610 documents
Optimal band selection for future satellite sensor dedicated to soil science
2009
Hyperspectral imaging systems could be used for identifying the different soil types from the satellites. However, detecting the reflectance of the soils in all the wavelengths involves the use of a large number of sensors with high accuracy and also creates a problem in transmitting the data to earth stations for processing. The current sensors can reach a bandwidth of 20 nm and hence, the reflectance obtained using the sensors are the integration of reflectance obtained in each of the wavelength present in the spectral band. Moreover, not all spectral bands contribute equally to classification and hence, identifying the bands necessary to have a good classification is necessary to reduce …
Forward likelihood-based predictive approach for space-time point processes
2011
Dealing with data from a space–time point process, the estimation of the conditional intensity function is a crucial issue even if a complete definition of a parametric model is not available. In particular, in case of exploratory contexts or if we want to assess the adequacy of a specific parametric model, some kind of nonparametric estimation procedure could be useful. Often, for these purposes kernel estimators are used and the estimation of the intensity function depends on the estimation of bandwidth parameters. In some fields, like for instance the seismological one, predictive properties of the estimated intensity function are pursued. Since a direct ML approach cannot be used, we pr…
Estimation of total electricity consumption curves by sampling in a finite population when some trajectories are partially unobserved
2019
International audience; Millions of smart meters that are able to collect individual load curves, that is, electricity consumption time series, of residential and business customers at fine scale time grids are now deployed by electricity companies all around the world. It may be complex and costly to transmit and exploit such a large quantity of information, therefore it can be relevant to use survey sampling techniques to estimate mean load curves of specific groups of customers. Data collection, like every mass process, may undergo technical problems at every point of the metering and collection chain resulting in missing values. We consider imputation approaches (linear interpolation, k…
Properties of Human Hemoglobins with Increased Polarity in the α- or β-Heme Pocket
1998
The spectroscopic, conformational, and functional properties of mutant carbonmonoxy hemoglobins in which either the β-globin Val67(E11) or the α-globin Val62(E11) is replaced by threonine have been investigated. The thermal evolution of the Soret absorption band and the stretching frequency of the bound CO were used to probe the stereodynamic properties of the heme pocket. The functional properties were investigated by kinetic measurements. The spectroscopic and functional data were related to the conformational properties through molecular analysis. The effects of this nonpolar-to-polar isosteric mutation are: (i) increase of heme pocket anharmonic motions, (ii) stabilization of the A 0 co…
Cooperative effects on the HS→LS relaxation in the [Fe(ptz)6](BF4)2 spin-crossover system
1992
Abstract The high-spin to low-spin (HS→LS) relaxation in the [Fe(ptz) 6 ](BF 4 ) 2 spin-crossover system deviates strongly from first-order kinetics because of cooperative effects of elastic origin. The shift in horizontal and vertical displacement of the potential wells of the initial and final state relative to each other due to the build-up of an “internal” pressure is estimated from spectroscopic measurements. The HS→LS relaxation as such is described by the theory of nonadiabatic multiphonon relaxation in the strong-coupling limit, with a Huang—Rhys factor S ≈ 45 which is much larger than the reduced energy gap p . The sigmoidal relaxation curves in [Fe(ptz) 6 ](BF 4 ) 2 result when a …
Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)40]3+ (X = Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles
2017
Surface ligands play important roles in controlling the size and shape of metal nanoparticles and their surface properties. In this work, we demonstrate that the use of bulky thiolate ligands, along with halides, as the surface capping agent promotes the formation of plasmonic multiple-twinned Ag nanoparticles with high surface reactivities. The title nanocluster [Ag141X12(S-Adm)40]3+ (where X = Cl, Br, I; S-Adm = 1-adamantanethiolate) has a multiple-shell structure with an Ag71 core protected by a shell of Ag70X12(S-Adm)40. The Ag71 core can be considered as 20 frequency-two Ag10 tetrahedra fused together with a dislocation that resembles multiple-twinning in nanoparticles. The nanocluster…
La normale eccezionalità : La mafia, il banditismo, il terrorismo e ancora la mafia
2016
The story of legislative exceptionality in Italian history represents a constant, almost a normality. The essay insists on this normal exceptionality, trying to trace it in the events of the apparto repressive against the terrorism of the seventies and in that used for fight the mafia of the following decades. Here it is assumed that the connection between these two phenomena is inseparable: without the fight against terrorism there would not have been the mafia; both in the legal field and in that of investigative, penitentiary, political and administrative institutions. In turn, the emergency legislation against terrorism inherits, as we will try to see, the characters of the fight agains…
Micro- to macro-scale internal structures, diagenesis and petrophysical evolution of injectite networks in the Vocontian Basin (France): implications…
2015
27 pages; International audience; This study discusses the characteristics of two Lower Cretaceous injectite networks in the Vocontian Basin (SE France) using combined structural, sedimentary, diagenetic, and petrophysical analyses. Internal structures, at both the macro- and micro-scale, and diagenetic phases characterising these injectite networks have been described. Simultaneously, precementation porosity values were estimated and parameters controlling the geographical distributions of these values were analysed and statistically tested. All of the data were integrated so as to reconstruct the spatial evolution of the porosity from the time of injection to modern times through five maj…
Formation of dislocation patterns: Computer simulations
1996
Dislocations patterns have been extensively studied by means of TEM. In parallel, theoretical approaches have been developed by using two methods; reaction diffusion schemes and computer simulation models. This distinction is not rigid since some computer models include the former approach in their evolution equations. Independently from the difficulties each approach presents in formulating the collective behavior of dislocations, the aim of these studies is to exhibit simple dislocation patterns as persistent slip bands and/or cellular organization. In this context, computer simulations brought a methodology which undoubtedly is a complement to the existing approaches for dislocations. Ne…
High-pressure studies of topological insulators Bi2Se3, Bi2Te3, and Sb2Te3
2013
Bi2Se3, Bi2Te3, and Sb2Te3 are narrow bandgap semiconductors with tetradymite crystal structure (R-3m) which have been extensively studied along with their alloys due to their promising operation as thermoelectric materials in the temperature range between 300 and 500¿K. Studies on these layered semiconductors have increased tremendously in the last years since they have been recently predicted and demonstrated to behave as 3D topological insulators. In particular, a number of high-pressure studies have been done in the recent years in these materials. In this work we summarize the main results of the high-pressure studies performed in this family of semiconductors to date. In particular, w…