Search results for "BAND"
showing 10 items of 2610 documents
Electronic properties and high-pressure behavior of wolframite-type CoWO4
2021
In this work we characterize wolframite-type CoWO4 under ambient conditions and under compression up to 10 GPa, with emphasis on its electronic structure. X-Ray diffraction and vibrational experiments, supported by ab initio calculations, show that CoWO4 is stable under high-pressure conditions, as no structural changes are detected in the studied pressure range. Interesting findings come from optical absorption spectroscopy. On the one hand, CoWO4 is confirmed to have one of the lowest band gaps among similar wolframites, around 2.25 eV. This makes CoWO4 suitable for use in applications such as the photocatalysis of organic pollutants and water splitting. Additionally, a monotonic decrease…
Intrinsic Nature of the Excess Electron Distribution at theTiO2(110)Surface
2012
The gap state that appears upon reduction of TiO2 plays a key role in many of titania's interesting properties but its origin and spatial localization have remained unclear. In the present work, the TiO2(110) surface is reduced in a chemically controlled way by sodium adsorption. By means of resonant photoelectron diffraction, excess electrons are shown to be distributed mainly on subsurface Ti sites strikingly similar to the defective TiO2(110) surface, while any significant contribution from interstitial Ti ions is discarded. In agreement with first principles calculations, these findings demonstrate that the distribution of the band gap charge is an intrinsic property of TiO2(110), indep…
<title>Coumarin fluorescent probes by electro-optical and laser spectrofluorimetry methods</title>
1997
Modified electro-optical absorption and emission methods were used to measure the dipole moments of six coumarin fluorescent probes (CU1, CU4, CU7, CU30, CU120, CU334) in the equilibrated ground, excited Franck-Condon and equilibrated excited states. The measurements were performed in cyclohexane and dioxane at room temperature. The equilibrated ground and excited states dipole measured by electro-optical methods are compared with those derived from other measurements techniques and from semiempirical calculations. Experiments and calculations performed in this work reveal a set of anomalous and interesting properties of CU7 and CU30 in solutions. The spectral dependence of some electro-opt…
Elongated push–pull diphenylpolyenes for nonlinear optics: molecular engineering of quadratic and cubic optical nonlinearities via tuning of intramol…
1999
Abstract Push–pull polyenes are of particular interest for nonlinear optics (NLO) as well as model compounds for long-distance intramolecular charge transfer (ICT). In order to tune the ICT phenomenon and control the linear and nonlinear optical properties, we have synthesized and investigated several series of soluble push–pull diphenylpolyenes of increasing length and having various donor (D) and acceptor (A) end groups. Their linear and NLO properties have been studied by performing electro-optical absorption measurements (EOAM) and third-harmonic generation (THG) experiments in solution. Each push–pull molecule exhibits an intense ICT absorption band in the visible characterized by an i…
I traffici illeciti nel Mediterraneo. Persone, stupefacenti, tabacco. Report Germania
2019
Il Report analizza il diritto penale tedesco relativo a quattro diversi tipi di traffico: il traffico di migranti, la tratta di esseri umani, il traffico di stupefacenti e il contrabbando di sigarette. Il Report fa parte di una più ampia ricerca ("The New Era of Smuggling in the Mediterranean Sea", NESMeS) volta ad analizzare i suddetti traffici illeciti nell'area del Mediterraneo, con particolare riguardo ai seguenti paesi: Germania, Grecia, Italia, Portogallo e Spagna. Insieme al Rapporto tedesco e ai Report dei singoli ordinamenti giuridici interessati, la ricerca NESMeS ha prodotto un Report criminologico e un libro finale ("I traffici illeciti nel Mediterraneo. Persone, stupefacenti, t…
Distance graphs and the T-coloring problem
1999
Abstract The T-coloring problem is, given a graph G = (V, E), a set T of nonnegative integers containing 0, and a ‘span’ bound s ⩾ 0, to compute an integer coloring f of the vertices of G such that |f(ν) − f(w)| ∉ T ∀νw ∈ E and max f − min f ⩽ s. This problem arises in the planning of channel assignments for broadcast networks. When restricted to complete graphs, the T-coloring problem boils down to a number problem which can be solved efficiently for many types of sets T. The paper presents results indicating that this is not the case if the set T is arbitrary. To these ends, the class of distance graphs is introduced, which consists of all graphs G : G ≅ G(A) for some (finite) set of posi…
Relatively Orthocomplemented Skew Nearlattices in Rickart Rings
2015
AbstractA class of (right) Rickart rings, called strong, is isolated. In particular, every Rickart *-ring is strong. It is shown in the paper that every strong Rickart ring R admits a binary operation which turns R into a right normal band having an upper bound property with respect to its natural order ≤; such bands are known as right normal skew nearlattices. The poset (R, ≤) is relatively orthocomplemented; in particular, every initial segment in it is orthomodular.The order ≤ is actually a version of the so called right-star order. The one-sided star orders are well-investigated for matrices and recently have been generalized to bounded linear Hilbert space operators and to abstract Ric…
The Use of the Wavelet Approximation Signal as a Tool for the Diagnosis of Rotor Bar Failures
2005
[EN] The aim of this paper is to present a new approach for rotor bar failure diagnosis in induction machines. The method focuses on the study of an approximation signal resulting from the wavelet decomposition of the startup stator current. The presence of the left sideband harmonic is used as evidence of the rotor failure in most diagnosis methods based on the analysis of the stator current. Thus, a detailed description of the evolution of the left sideband harmonic during the startup transient is given in this paper; for this purpose, a method for calculating the evolution of the left sideband during the startup is developed, and its results are physically explained. This paper also show…
Regularization of optical flow with M-band wavelet transform
2003
The optical flow is an important tool for problems arising in the analysis of image sequences. Flow fields generated by various existing solving techniques are often noisy and partially incorrect, especially near occlusions or motion boundaries. Therefore, the additional information on the scene gained from a sequence of images is usually worse. In this paper, discrete wavelet transform has been adopted in order to enhance the reliability of optical flow estimation. A generalization of the well-known dyadic orthonormal wavelets to the case of the dilation scale factor M > 2 with N vanishing moments has been used, and it has proved to be a useful regularizing tool. The advantages in the comp…
Effect of parametric variation of center frequency and bandwidth of morlet wavelet transform on time-frequency analysis of event-related potentials
2017
Time-frequency (TF) analysis of event-related potentials (ERPs) using Complex Morlet Wavelet Transform has been widely applied in cognitive neuroscience research. It has been widely suggested that the center frequency (fc) and bandwidth (σ) should be considered in defining the mother wavelet. However, the issue how parametric variation of fc and σ of Morlet wavelet transform exerts influence on ERPs time-frequency results has not been extensively discussed in previous research. The current study, through adopting the method of Complex Morlet Continuous Wavelet Transform (CMCWT), aims to investigate whether time-frequency results vary with different parametric settings of fc and σ. Besides, …