Search results for "BP"

Long-distance magnetic coupling in dinuclear copper(II) complexes with oligo-para-phenylenediamine bridging ligands

2010

Abstract Two novel dinuclear copper(II) complexes of formulae [Cu2(tren)2(bpda)](ClO4)4 (2) and [Cu2(tren)2(tpda)](ClO4)4 (3) containing the tripodal tris(2-aminoethyl)amine (tren) terminal ligand and the 4,4′-biphenylenediamine (bpda) and 4,4″-p-terphenylenediamine (tpda) bridging ligands have been synthesized and structurally, spectroscopically, and magnetically characterized. Their experimentally available electronic spectroscopic and magnetic properties have been reasonably reproduced by DFT and TDDFT calculations. Single crystal X-ray diffraction analysis of 2 shows the presence of dicopper(II) cations where the bpda bridging ligand adopts a bismonodentate coordination mode toward two …

2021

Arginine-glycine(-glycine) (RG/RGG) regions are highly abundant in RNA-binding proteins and involved in numerous physiological processes. Aberrant liquid-liquid phase separation (LLPS) and stress granule (SGs) association of RG/RGG regions in the cytoplasm have been implicated in several neurodegenerative disorders. LLPS and SG association of these proteins is regulated by the interaction with nuclear import receptors, such as transportin-1 (TNPO1), and by post-translational arginine methylation. Strikingly, many RG/RGG proteins harbour potential phosphorylation sites within or close to their arginine methylated regions, indicating a regulatory role. Here, we studied the role of phosphoryla…

Dual-Mode Chiral Self-Assembly of Cone-Shaped Subphthalocyanine Aromatics

2020

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.0c07291

Trihalomethanes in swimming pool water in four areas of Spain participating in the INMA project

2010

ResumenObjetivoLa natación es uno de los deportes más practicados en España, por personas de todas las edades y condiciones físicas. También es una vía de exposición a subproductos de la desinfección, compuestos potencialmente tóxicos. Su concentración en el agua de las piscinas no está legislada y es poco conocida. El objetivo de este trabajo es describir la concentración de trihalometanos en el agua de piscinas de los municipios de cuatro cohortes del estudio INMA.MétodosEn julio de 2009 se analizaron los trihalometanos en el agua de piscinas (n=27) de Asturias, Granada, Valencia y Sabadell.ResultadosLa concentración media de trihalometanos totales fue de 42,7μg/l (desviación estándar [DE…

Protein-lipid interactions at the air-water interface.

2010

International audience; Protein−lipid interactions play an important role in a variety of fields, for example in pharmaceutical research, biosensing, or food science. However, the underlying fundamental processes that govern the interplay of lipids and proteins are often very complex and are therefore studied using model systems. Here, Langmuir monolayers were used to probe the interaction of a model protein with lipid films at the air−water interface. The protein β-lactoglobulin (βlg) is the major component in bovine milk serum, where it coexists with the milk fat globular membrane. During homogenization of milk, βlg adsorbs to the interface of lipid fat globules and stabilizes the oil-in-…

Trihalomethanes in swimming pool water in four areas of Spain participating in the INMA project

2010

Objetivo: La natación es uno de los deportes más practicados en España, por personas de todas las edades y condiciones físicas. También es una vía de exposición a subproductos de la desinfección, compuestos potencialmente tóxicos. Su concentración en el agua de las piscinas no está legislada y es poco conocida. El objetivo de este trabajo es describir la concentración de trihalometanos en el agua de piscinas de los municipios de cuatro cohortes del estudio INMA. Métodos: En julio de 2009 se analizaron los trihalometanos en el agua de piscinas (n=27) de Asturias, Granada, Valencia y Sabadell. Resultados: La concentración media de trihalometanos totales fue de 42,7µg/l (desviación estándar [D…

Bromēto liesmas slāpētāju noteikšana medību gaļas paraugos ar augstas izšķirtspējas masspektrometrijas metodēm

2017

Bromēto liesmas slāpētāju noteikšanas medību gaļas paraugos ar augstas izšķirtspējas masspektrometrijas metodēm. Bāliņš Rolands, zinātniskais vadītājs: Dr. ķīm., Dzintars Začs, konsultante: Ķīm. maģ., doktorante Jekaterina Rjabova. Maģistra darbs, 47 lappuses, 9 attēli, 21 tabula, 30 literatūras avoti, 2 pielikumi. Latviešu valodā. Maģistra darbā ir apkopota literatūra par analizētajiem savienojumiem, to pielietošanu, toksiskumu, izplatību dabā un to analīžu metodēm. Iegūtie rezultāti ir apkopoti tabulu un diagrammu veidā. Darbā tika veikta bromēto liesmas slāpētāju tetrabrom bisfenola A (TBBPA), heksabromciklododekāna (HBCDD) un polibromēto difenil ēteru (PBDEs) noteikšana medījumu gaļas p…

Recovery of zinc from spent pickling solutions by liquid–liquid extraction using TBP

2019

In this paper, recovery of zinc from real spent pickling solutions by liquid–liquid extraction with tributyl phosphate (TBP) was studied. In particular, the effects of some parameters were investigated, such as the volume ratio between the organic phase and real spent pickling liquor (O/A) (1:2, 1:1, 2:1, 4:1), the stirring time (5–20–30 min) and the TBP concentration (10%–55%–100%), in order to determine the conditions leading to higher zinc extraction efficiency, as well as selectivity in relationships to other metals such as iron. After zinc extraction, TBP was successfully regenerated. Among several tested solutions, water allows zinc recovery higher than 90%, especially at 10% diluted …

Tick-borne pathogens in sheep and goats in Southern Italy

2010

A Regulatory Mechanism Involving TBP-1/Tat-Binding Protein 1 and Akt/PKB in the Control of Cell Proliferation

2011

Abstract TBP-1 /Tat-Binding Protein 1 (also named Rpt-5, S6a or PSMC3) is a multifunctional protein, originally identified as a regulator of HIV-1-Tat mediated transcription. It is an AAA-ATPase component of the 19S regulative subunit of the proteasome and, as other members of this protein family, fulfils different cellular functions including proteolysis and transcriptional regulation. We and others reported that over expression of TBP-1 diminishes cell proliferation in different cellular contexts with mechanisms yet to be defined. Accordingly, we demonstrated that TBP-1 binds to and stabilizes the p14ARF oncosuppressor increasing its anti-oncogenic functions. However, TBP-1 restrains cell…