Search results for "BREAKING"

Donor–anion interactions at the charge localization and charge ordering transitions of (TMTTF)2AsF6 probed by NEXAFS

2015

High-resolution near-edge X-ray absorption fine structure (NEXAFS) measurements at the As M-edge, F K-edge and S L-edge of the Fabre salt (TMTTF)2AsF6 were performed from room temperature (RT) to 90 K, allowing to reach the charge localization regime below Tρ ≈ 230 K and to cross the charge ordering (CO) transition at TCO ≈ 102 K. The F K-edge and S L-edge spectra exhibit several transitions which have been indexed on the basis of first-principles DFT calculations. Upon cooling from RT significant energy shifts up to +0.8 eV and -0.4 eV were observed in transitions exhibited by the F 1s and S 2p spectra respectively, while the As 3p doublet does not show a significant shift. Opposite energy…

A Discussion of Some Problems Associated with the Quantum Mechanical Treatment of Open-Shell Molecules

2003

Solvatochromy and symmetry breaking in two quadrupolar oligophenylenevinylenes

2020

Electrooptical absorption measurements (EOAM), solvatochromic dependences and quantum chemical simulations testify to large dipole moments change of two quadrupolar oligophenylenevinylenes upon transition to Franck-Condon excited state μeFC. The values of the dipole moments μg and μeFC are in the range [(4.2 - 4.9)1030] C m and (30.8 - 47.0)1030C m, respectively. The relations of dipole moments in the ground and excited states determined by EOAM correlate well with results obtained via the solvatochromic method. Calculations carried out by density functional theory (DFT) show that optimized configuration of the ground state of these molecules is not planar. The results from all methods appl…

Chiral Symmetry And Low Energy Pion Photoproduction

1992

The low energy theorem based on chiral symmetry for the photoproduction of neutral pions from proton at threshold is reviewed in the light of recent experimental results from Saclay and Mainz. There is no appreciable disagreement at threshold but the energy dependence of the threshold amplitude remains unexplained. A critique of the assumptions made in deriving low energy theorems by various methods is presented.

Bag models and hadron structure

2008

We review the fundamental ideas leading to the basic assumptions behind the bag model description of hadron structure and explore in some detail the so called MIT bag model. We discuss the relevance of chiral symmetry and incorporate it in a bag model scheme by adding a pion field. We show perturbative techniques of calculating gluonic and pionic effects. We discuss the consequences of the solitonic nature of the hedgehog solution of the pion field and introduce the skyrmion bag model. We end up by drawing some conclusions of our study and discussing recent developments in this area.

Chiral expansion of the nucleon mass to order q^6

2006

We present the results of a complete two-loop calculation at order q^6 of the nucleon mass in manifestly Lorentz-invariant chiral perturbation theory. The renormalization is performed using the reformulated infrared renormalization, which allows for the treatment of two-loop integrals while preserving all relevant symmetries, in particular chiral symmetry.

The role of resonances in chiral perturbation theory

1989

32 páginas, 2 figuras, 5 tablas.-- BUTP-88-18 ; CERN-TH-5185-88 ; CPT-2158 ; UWTHPH-1988-29.

In-medium pi-pi Correlation Induced by Partial Restoration of Chiral Symmetry

2000

We show that both the linear and the non-linear chiral models give an enhancement of the pi-pi cross section near the 2pi threshold in the scalar-iso-scalar (I=J=0) channel in nuclear matter. The reduction of the chiral condensate, i.e., the partial chiral restoration in nuclear matter, is responsible for the enhancement in both cases. We extract an effective 4pi-nucleon vertex which is responsible for the enhancement but has not been considered in the non-liear models for in-medium pi-pi interaction. Relation of this vertex and a next-to-leading order terms in the heavy-baryon chiral lagrangian, L_piN^(2), is also discussed.

ChPT parameters from tau-decay data

2015

Using the updated ALEPH V-A spectral function from tau decays, we determine the lowest spectral moments of the left-right correlator and extract dynamical information on order parameters of the QCD chiral symmetry breaking. Uncertainties associated with violations of quark-hadron duality are estimated from the data, imposing all known short-distance constraints on a resonance-based parametrization. Employing proper pinched weight functions, we obtain an accurate determination of the effective chiral couplings L10 and C87 and the dimension-six and -eight contributions in the Operator Product Expansion.

Excited charmed mesons in chiral perturbation theory

1992

Abstract Heavy meson, p- to s-wave, one-pion transitions are studied in the context of the union of heavy quark and chiral symmetries. The interactions are described by an effective lagrangian density invariant under the combined heavy quark and chiral symmetries. We study the pattern of the heavy quark symmetry breaking by considering 1 m Q corrections to the infinite mass limit.