Search results for "Balance"
showing 10 items of 1379 documents
Electrochemistry and electrocatalysis of a Pt@poly(neutral red) hybrid nanocomposite
2015
Abstract Platinum nanoparticles have been deposited on a scaffold of electrosynthetized phenazine-type polymer, the poly(neutral red). This work discusses the role of poly(neutral red) in the electrochemistry and electrocatalysis properties of the hybrid nanocomposite. In situ combination of electrochemical quartz crystal microbalance and visible-near infrared spectroscopy (cyclic Vis-NIR spectroelectrogravimetry) and a combination of electrochemical impedance spectroscopy and mass impedance spectroscopy ( ac -electrogravimetry) were employed. Two electrochemical processes have been identified in our experimental conditions. On the one hand, the radical cations (polarons) localized in the i…
Detailed balance analysis of area de-coupled double tandem photovoltaic modules
2015
Published version of an article in the journal: Applied Physics Letters. Also available from the publisher at: http://dx.doi.org/10.1063/1.4906602 This paper describes how layers of area de-coupled top and bottom cells in photovoltaic tandem modules can increase the efficiency of two-terminal tandem devices. The point of the area de-coupling is to allow the number of top cells to differ from the number of bottom cells. Within each of the layers, the cells can be horizontally series-connected and the layers can then be currentor voltage-matched with each other in a tandem module. Using detailed balance modeling, it is shown that two-terminal tandem modules of this type can achieve the same t…
Steady State Counterbalance Valve Modeling with the Influence of Synthetic Ester Oils Using CFD
2020
This study looks in details at the effects of synthetic esters being applied to a counterbalance valve from the perspective of a system engineer. There is limited literature on the subject of applied synthetic esters and as such limited unbiased sources for information. This creates reluctance against the use of these fluids in sectors and regions with no prior experience and knowledge of what to expect. This study expands the applied literature by investigating a commercially available valve using commercial oils, a basic synthetic ester, a fully saturated synthetic ester and a typical mineral oil type for benchmarking. The investigation is based on both computational fluid dynamics and ex…
Toxicity of gold-nanoparticles: Synergistic effects of shape and surface functionalization on micromotility of epithelial cells
2010
Nanoparticle exposure is monitored by a combination of two label-free and non-invasive biosensor devices which detect cellular shape and viscoelasticity (quartz crystal microbalance), cell motility and the dynamics of epithelial cell-cell contacts (electric cell-substrate impedance sensing). With these tools we have studied the impact of nanoparticle shape on cellular physiology. Gold (Au) nanoparticles coated with CTAB were synthesized and studied in two distinct shapes: Spheres with a diameter of (43 ± 4) nm and rods with a size of (38 ± 7) nm × (17 ± 3) nm. Dose-response experiments were accompanied by conventional cytotoxicity tests as well as fluorescence and dark-field microscopy to v…
Enzymatic Synthesis and Surface Deposition of Tin Dioxide using Silicatein-α
2011
Nanostructured tin dioxide was synthesized by making use of the catalytic activity of silicatein-α. TEM, HRTEM, and XRD revealed the formation of cassiterite SnO2. Surface bound silicatein retains its biocatalytic activity. This was demonstrated by immobilizing silicatein on glass surfaces using a histidine-tag chelating anchor. The subsequent deposition of SnO2 on glass was monitored by quartz crystal microbalance (QCM) measurements and scanning electron microscopy (SEM). This new aspect of silicatein activity toward the formation of metal oxides other than SiO2, TiO2, and BaTiO3 opens up new vistas in composite material synthesis.
Deposition Kinetics and Compositional Control of Vacuum-Processed CH3NH3PbI3 Perovskite
2020
Halide perovskites have generated considerable research interest due to their excellent optoelectronic properties in the past decade. To ensure the formation of high-quality semiconductors, the deposition process for the perovskite film is a critical issue. Vacuum-based processing is considered to be a promising method, allowing, in principle, for uniform deposition on a large area. One of the benefits of vacuum processing is the control over the film composition through the use of quartz crystal microbalances (QCMs) that monitor the rates of the components in situ. In metal halide perovskites, however, one frequently employed component or precursor, CH3NH3I, exhibits nonstandard sublimatio…
The Influence of MSW Landfill Height in the Perched Leachate Formation
2012
During the last decades, the largest part of municipal solid waste (MSW) generated world wide has been disposed of in landfills without any pre-treatment. The main environmental impacts of such landfills, containing high amounts of biodegradable organic matter, are caused by emissions of liq-uid effluents and landfill gas. With no collection and treatment, leachates from landfills pollute groundwater and soils locally. Furthermore, besides the biological processes, many physical phe-nomena occur inside the landfill body which negatively affect landfill management. Indeed, the waste settlement inside the landfill body, with a consequent increase of its density, corresponds to a proportional …
A Hybrid Strategic Oscillation with Path Relinking Algorithm for the Multiobjective k-Balanced Center Location Problem
2021
This paper presents a hybridization of Strategic Oscillation with Path Relinking to provide a set of high-quality nondominated solutions for the Multiobjective k-Balanced Center Location problem. The considered location problem seeks to locate k out of m facilities in order to serve n demand points, minimizing the maximum distance between any demand point and its closest facility while balancing the workload among the facilities. An extensive computational experimentation is carried out to compare the performance of our proposal, including the best method found in the state-of-the-art as well as traditional multiobjective evolutionary algorithms.
Load match optimisation of a residential building case study: A cross-entropy based electricity storage sizing algorithm
2015
Abstract The EU EPBD recast regulation marked the application of the net zero energy building (Net ZEB) concept in all fields of building construction in Europe as a building able to generate as much energy as it consumes over a selected time frame. A more detailed insight is however needed, as even if a building achieves a long-term energy balance between energy generated and consumed, smaller time scales must also be considered. For example, from the utility’s point of view, if a Net ZEB is a heavy consumer in the winter, it will appear to be quite similar to a conventional building, requiring the use of additional generation. The increase in the generation-load match means reducing the s…
Driven Primary Regulation for Minimum Power Losses Operation in Islanded Microgrids
2018
The paper proposes an improved primary regulation method for inverter-interfaced generating units in islanded microgrids. The considered approach employs an off-line minimum losses optimal power flow (OPF) to devise the primary frequency regulation curve’s set-points while satisfying the power balance, frequency and current constraints. In this way, generators will reach an optimized operating point corresponding to a given and unique power flow distribution presenting the minimum power losses. The proposed approach can be particularly interesting for diesel-based islanded microgrids that face, constantly, the issue of reducing their dependency from fossil fuels and of enhancing their gener…