Search results for "Bases"
showing 10 items of 1240 documents
Crystal structure of (E)-N-(3,4-dimethoxybenzylidene)morpholin-4-amine
2014
In the title compound, C13H18N2O3, the benzene ring makes a dihedral angle of 17.19 (11)° with the least-squares plane formed by the four C atoms of the morpholine ring, which adopts a chair conformation. In the crystal, C—H...N hydrogen bonds link the molecules into supramolecular chains running along a 21screw axis parallel to theb-axis direction. Weak C—H...π interactions are also observed.
A tetranuclear cubane-like nickel(II) complex with a tridentate salicylideneimine Schiff base ligand: tetrakis[μ3-4-methyl-N-(2-oxidophenyl)salicylid…
2016
The tetranuclear title complex, [Ni4(C14H11NO2)4(CH3OH)4]·0.8CH3OH, has a distorted cubane topology shaped by four Schiff base ligands. The cubane [Ni4(μ3-O4)] core is formedviathe O atoms from the Schiff base ligands. The octahedrally coordinated NiIIions occupy alternating vertices of the cube. Each NiIIion is coordinated by oneO,N,O′-tridentate dianionic ligand, two O atoms of oxidophenyl groups from adjacent ligands and the O atom of a coordinating methanol molecule. The cubane core is stabilizedviaan intramolecular O—H...O hydrogen bond between the hydroxy group of the coordinating methanol molecules and the phenolate O atom of the aldehyde Schiff base fragment. Additional stabilizatio…
The Key Concepts of Ethics of Artificial Intelligence
2018
The growing influence and decision-making capacities of Autonomous systems and Artificial Intelligence in our lives force us to consider the values embedded in these systems. But how ethics should be implemented into these systems? In this study, the solution is seen on philosophical conceptualization as a framework to form practical implementation model for ethics of AI. To take the first steps on conceptualization main concepts used on the field needs to be identified. A keyword based Systematic Mapping Study (SMS) on the keywords used in AI and ethics was conducted to help in identifying, defying and comparing main concepts used in current AI ethics discourse. Out of 1062 papers retrieve…
The reliability of spanish and german electricity forward prices. Databases and price discovery process
2021
Given the existence of different databases from different sources that offer information on forward electricity prices, the need to compare them arises to guarantee that research results and trading decisions based on them are not sensitive to the database used. We worked with forward electricity prices traded over the counter, closest month to maturity, covering the period from 2010 to 2016 for the Spanish over the counter (OTC) market, and from 2008 to 2016 for the German OTC market. The goal of this paper was to test whether there were significant discrepancies between the price series provided by two of the main agencies of financial information (Thomson Reuters and Bloomberg), as well …
Testing the Sobolev property with a single test plan
2020
We prove that in a vast class of metric measure spaces (namely, those whose associated Sobolev space is separable) the following property holds: a single test plan can be used to recover the minimal weak upper gradient of any Sobolev function. This means that, in order to identify which are the exceptional curves in the weak upper gradient inequality, it suffices to consider the negligible sets of a suitable Borel measure on curves, rather than the ones of the $p$-modulus. Moreover, on $\sf RCD$ spaces we can improve our result, showing that the test plan can be also chosen to be concentrated on an equi-Lipschitz family of curves.
Mining Maximal Frequent Patterns in Transactional Databases and Dynamic Data Streams: A Spark-based Approach
2018
Mining maximal frequent patterns (MFPs) in transactional databases (TDBs) and dynamic data streams (DDSs) is substantially important for business intelligence. MFPs, as the smallest set of patterns, help to reveal customers’ purchase rules and market basket analysis (MBA). Although, numerous studies have been carried out in this area, most of them extend the main-memory based Apriori or FP-growth algorithms. Therefore, these approaches are not only unscalable but also lack parallelism. Consequently, ever increasing big data sources requirements cannot be met. In addition, mining performance in some existing approaches degrade drastically due to the presence of null transactions. We, therefo…
Consistency of Targeted Metatranscriptomics and Morphological Characterization of Phytoplankton Communities
2020
The composition of phytoplankton community is the basis for environmental monitoring and assessment of the ecological status of aquatic ecosystems. Community composition studies of phytoplankton have been based on time-consuming and expertise-demanding light microscopy analyses. Molecular methods have the potential to replace microscopy, but the high copy number variation of ribosomal genes and the lack of universal primers for simultaneous amplification of prokaryotic and eukaryotic genes complicate data interpretation. In this study, we used our previously developed directional primer-independent high-throughput sequencing (HTS) approach to analyze 16S and 18S rRNA community structures. C…
Mexican journals of educational research towards mainstream dissemination of science
2014
The purpose of this study is to analyze the Electronic Journal of Educational Research (REDIE) on its path towards the common manner of scientific dissemination. This research presents the evolution of Mexican policy with regards to the journals, the situation of the Educational Research Mexican journals, and its profundity relating to REDIE. In its evolution, there were three moments that stood out the most: the standardization of quality criteria, the digitalization and open access of the scientific journals, those that came together with REDIE like REDALYC and LATINDEX , and the individual initiatives of those journals that motivated the development of the scientific dissemination in Mex…
Genetic database development for the characterisation of Sicilian sheep population
2019
The most representative sheep in Sicily are Belicina, Comisana, Pinzirita, Barbarescaand the crossbred derived sheep from all this species. In this study, the allelic frequencies of the Sicilian sheep population were investigated. It currently represents the best way to determine the genetic identity and/or family even with limited amounts of sample or when the DNA is degraded. The aim of the study was to provide a reference data bank and to evaluate a microsatellite panel for pedigree analysis as suggested by the International Society for Animal Genetics (ISAG). There are various studies on European sheep, but few datasets were developed on the population of Sicilian sheep. The reference d…
Training machine learning models with synthetic data improves the prediction of ventricular origin in outflow tract ventricular arrhythmias
2022
In order to determine the site of origin (SOO) in outflow tract ventricular arrhythmias (OTVAs) before an ablation procedure, several algorithms based on manual identification of electrocardiogram (ECG) features, have been developed. However, the reported accuracy decreases when tested with different datasets. Machine learning algorithms can automatize the process and improve generalization, but their performance is hampered by the lack of large enough OTVA databases. We propose the use of detailed electrophysiological simulations of OTVAs to train a machine learning classification model to predict the ventricular origin of the SOO of ectopic beats. We generated a synthetic database of 12-l…