Search results for "Bases"
showing 10 items of 1240 documents
Fine-Mesh Numerical Simulations for 2D Riemann Problems with a Multilevel Scheme
2001
The numerical simulation of physical problems modeled by systems of conservation laws can be difficult due to the occurrence of discontinuities and other non-smooth features in the solution.
Ambit processes and stochastic partial differential equations
2011
Ambit processes are general stochastic processes based on stochastic integrals with respect to Levy bases. Due to their flexible structure, they have great potential for providing realistic models for various applications such as in turbulence and finance. This papers studies the connection between ambit processes and solutions to stochastic partial differential equations. We investigate this relationship from two angles: from the Walsh theory of martingale measures and from the viewpoint of the Levy noise analysis.
Heuristic algorithms for a storage location assignment problem in a chaotic warehouse
2014
The extensive application of emerging technologies is revolutionizing warehouse management. These technologies facilitate working with complex and powerful warehouse management models in which products do not have assigned fixed locations (random storage). Random storage allows the utilization of the available space to be optimized. In this context, and motivated by a real problem, this article presents a model that looks for the optimal allocation of goods in order to maximize the storage space availability within the restrictions of the warehouse. For the proposed model a construction method, a local search algorithm and different metaheuristics have been developed. The introduced algorit…
Reliable Planar Object Pose Estimation in Light Fields From Best Subaperture Camera Pairs
2018
International audience; A light-field camera can obtain richer information about a scene than a usual camera. This property offers a lot of potential for robot vision. In this paper, we present a method for pose estimation of a planar object with a light-field camera. The light-field camera can be regarded as a set of sub-aperture cameras. Although any combination of them can theoretically be used for the pose estimation, the accuracy depends on the combination. We show that the estimated pose error can be reduced by selecting the best pair of sub-aperture cameras. We have evaluated the accuracy of our approach with real experiments using a light-field camera in front of planar targets held…
Synthesis and characterization of vanadyl(IV) complexes of Schiff bases derived from anthranilic acid and salicylaldehyde (or its derivatives) or ace…
1997
Anhydrous, dimeric vanadyl(IV) complexes of Schiff bases derived from [1+1] condensation of salicylaldehyde (or its derivatives) and anthranilic acid, have been synthesized from CH3CN and were characterized by elemental analysis, FTIR, EPR, absorption, TGA, cyclic voltammetry and room temperature magnetic susceptibility measurements. These complexes were found to be oxidized by air in polar solvents like MeOH and DMF to V-V products. The E(1/2) values were found to be around 660 mV indicating that the carboxylate group favours vanadyl(IV) binding when compared to the alkoxo-bound vanadium complexes. Oxidative instability of these complexes are dependent on the substituent on the salicylalde…
Multidentate Tetrahydrofurfuryloxide Ligand in a Ziegler−Natta Catalyst Studied by Molecular Modeling
2008
The transition from a generation III Ziegler-Natta catalyst with a monodentate Lewis base to a more modem generation 1V/V system, containing a tetrahydrofuran derivative, the tetrahydrofurturyloxide C 4 H 7 O-CH 2 O - bidentate ligand (THFFO), was studied by means of molecular modeling and DFT calculations. This particular ligand was carefully chosen so that it remained in the titanium coordination sphere in the model active site. With such a constraint, the dual role of tetrahydrofurfuryloxide was identified: it was demonstrated how the presence of this ligand limits the number of isomeric active sites as well as enhances the selectivity of the species that can still exist. The results ind…
Lambda+, the renewal of the Lambda Architecture: Category Theory to the rescue
2021
Designing software architectures for Big Data is a complex task that has to take into consideration multiple parameters, such as the expected functionalities, the properties that are untradeable, or the suitable technologies. Patterns are abstractions that guide the design of architectures to reach the requirements. One of the famous patterns is the Lambda Architecture, which proposes real-time computations with correctness and fault-tolerance guarantees. But the Lambda has also been highly criticized, mostly because of its complexity and because the real-time and correctness properties are each effective in a different layer but not in the overall architecture. Furthermore, its use cases a…
The miniJPAS survey: a preview of the Universe in 56 colours
2021
Full list of authors: Bonoli, S.; Marín-Franch, A.; Varela, J.; Vázquez Ramió, H.; Abramo, L. R.; Cenarro, A. J.; Dupke, R. A.; Vílchez, J. M.; Cristóbal-Hornillos, D.; González Delgado, R. M.; Hernández-Monteagudo, C.; López-Sanjuan, C.; Muniesa, D. J.; Civera, T.; Ederoclite, A.; Hernán-Caballero, A.; Marra, V.; Baqui, P. O.; Cortesi, A.; Cypriano, E. S.; Daflon, S.; de Amorim, A. L.; Díaz-García, L. A.; Diego, J. M.; Martínez-Solaeche, G.; Pérez, E.; Placco, V. M.; Prada, F.; Queiroz, C.; Alcaniz, J.; Alvarez-Candal, A.; Cepa, J.; Maroto, A. L.; Roig, F.; Siffert, B. B.; Taylor, K.; Benitez, N.; Moles, M.; Sodré, L.; Carneiro, S.; Mendes de Oliveira, C.; Abdalla, E.; Angulo, R. E.; Apari…
‘An apple a day’?: Psychiatrists, psychologists and psychotherapists report poor literacy for nutritional medicine: international survey spanning 52 …
2021
Nutritional interventions have beneficial effects on certain psychiatric disorder symptomatology and common physical health comorbidities. However, studies evaluating nutritional literacy in mental health professionals (MHP) are scarce. This study aimed to assess the across 52 countries. Surveys were distributed via colleagues and professional societies. Data were collected regarding self-reported general nutrition knowledge, nutrition education, learning opportunities, and the tendency to recommend food supplements or prescribe specific diets in clinical practice. In total, 1056 subjects participated in the study: 354 psychiatrists, 511 psychologists, 44 psychotherapists, and 147 MHPs in-t…
One-bond 1 J (15 N,H) coupling constants at sp2 -hybridized nitrogen of Schiff bases, enaminones and similar compounds: A theoretical study
2020
1 J(15 N,H) coupling constants for enaminones and NH-forms of intramolecularly hydrogen-bonded Schiff bases as model compounds for sp2 -hybridized nitrogen atoms are evaluated using density functional theory (DFT) to find the optimal functionals and basis sets. Ammonia is used as a test molecule and its one-bond coupling constant is compared with experiment. A methylamine Schiff base of a truncated molecule of gossypol is used for checking the performance of selected B3LYP, O3LYP, PBE, BHandH, and APFD density functionals and standard, modified, and dedicated basis sets for coupling constants. Both in vacuum and in chloroform, modeled by the simple continuum model of solvent, the modified b…