Search results for "Battery"
showing 10 items of 315 documents
Sensor Node Network for Remote Moisture Measurement in Timber Based on Bluetooth Low Energy and Web-Based Monitoring System
2021
This paper proposes an IoT system based on wireless BLE connectivity to monitor the moisture content of wood, using a compact and low-cost moisture device that relies on a resistance measurement method valid for an ultra-wide range of resistance values. This device is digitally controlled with a BLE-incorporated micro-controller characterized by its small size and low power consumption, providing long-life battery. The proposed system consists of two main parts: first, the BLE moisture device including the moisture content measurement and wireless capability (BLE)
The Thermodynamics of Insertion Electrochemical Electrodes—A Team Play of Electrons and Ions across Two Separate Interfaces
2018
Insertion electrochemical electrodes exhibit simultaneous electron and ion transfer, with the two transfers proceeding across different interfaces. Herein the thermodynamics of the overall electrochemical electrode reaction is discussed with respect to the thermodynamics of these two charge-transfer equilibria. This Minireview includes insertion electrochemical systems where the redox centers are in a solid phase and the ions are transferred between that phase and a solution, and also systems where the redox centers are in a liquid phase that is immiscible with another liquid phase and ions are transferred between the two liquid phases. The Minireview is intended to spark similar studies on…
Experimental characterization of a proton exchange membrane fuel-cell for hybrid electric pedal assisted cycles
2017
This paper presents a feasibility study on the prototyping of a hybrid EPAC (Electric Pedal Assisted Cycle) through an FC-B-UC (Fuel Cell — Battery — Ultra-Capacitors) power system. Aim of this work is the characterization of a PEMFC (Proton Exchange Membrane Fuel Cell) in order to confirm its theoretical performances and to verify the possibility of its installation on an e-bike.
Electrostatic Anchoring of Mn4 Single-Molecule Magnets onto Chemically Modified Multiwalled Carbon Nanotubes
2012
Two different routes that enable the electrostatic grafting of cationic single-molecule magnets (SMMs) onto the surface of chemically modified anionic multi-walled carbon nanotubes (MWNTs) are described. The chemical nature and physical properties of the resulting hybrids are discussed on the basis of a complete battery of experimental techniques. The data show that the chemical nature of the SMM unit remains intact, while its magnetic response is significantly affected by the grafting process, which is likely due to surface effects.
<title>Functional models of electrochromic devices: cycling capacity and degradation</title>
1997
Electrical transfer and diffusion of ions and the irreversibility of ion and electron processes in heterojunctions are responsible for degradation of ionic devices. These processes for electrochromic devices (ECD) determine the cycling capacity and lifetime. The basic problem here is how to match the electrochemical parameters (including chemical potential) of heterojunction. The experiments had been carried out on ECD based on system: (phi) - -(phi) , where AAH is solid electrolyte based on antimony acid hydrates. The cycling capacity and degradation processes of ECD are investigated by electro-optical and electro-chemical spectroscopy. The analysis of experimental data are based on assump…
Heat-to-current conversion of low-grade heat from a thermocapacitive cycle by supercapacitors
2015
Thermal energy is abundantly available, and especially low-grade heat is often wasted in industrial processes as a by-product. Tapping into this vast energy reservoir with cost-attractive technologies may become a key element for the transition to an energy-sustainable economy and society. We propose a novel heat-to-current converter which is based on the temperature dependence of the cell voltage of charged supercapacitors. Using a commercially available supercapacitor, we observed a thermal cell-voltage rise of around 0.6 mV K-1 over a temperature window of 0 degrees C to 65 degrees C. Within our theoretical model, this can be used to operate a Stirling-like charge-voltage cycle whose eff…
Electrical power production from low-grade waste heat using a thermally regenerative ethylenediamine battery
2017
Abstract Thermally regenerative ammonia-based batteries (TRABs) have been developed to harvest low-grade waste heat as electricity. To improve the power production and anodic coulombic efficiency, the use of ethylenediamine as an alternative ligand to ammonia was explored here. The power density of the ethylenediamine-based battery (TRENB) was 85 ± 3 W m−2-electrode area with 2 M ethylenediamine, and 119 ± 4 W m−2 with 3 M ethylenediamine. This power density was 68% higher than that of TRAB. The energy density was 478 Wh m−3-anolyte, which was ∼50% higher than that produced by TRAB. The anodic coulombic efficiency of the TRENB was 77 ± 2%, which was more than twice that obtained using ammon…
Copolymerization of Polythiophene and Sulfur To Improve the Electrochemical Performance in Lithium–Sulfur Batteries
2015
We first report on the copolymerization of sulfur and allyl-terminated poly(3-hexylthiophene-2,5-diyl) (P3HT) derived by Grignard metathesis polymerization. This copolymerization is enabled by the conversion of sulfur radicals formed by thermolytic cleavage of S8 rings with allyl end-group. The formation of a C–S bond in the copolymer is characterized by a variety of methods, including NMR spectroscopy, size exclusion chromatography, and near-edge X-ray absorption fine spectroscopy. The S-P3HT copolymer is applied as an additive to sulfur as cathode material in lithium–sulfur batteries and compared to the use of a simple mixture of sulfur and P3HT, in which sulfur and P3HT were not covalent…
High-performing Sn-Co nanowire electrodes as anodes for lithium-ion batteries
2012
Abstract The preparation of Sn 2 Co 3 nanowire arrays (NWs) electrogrown inside the channels of polycarbonate membranes and their characterization as anodes for Li-ion batteries both in half-cell vs. Li and in battery configuration are reported. The Sn 2 Co 3 NW electrodes tested by deep galvanostatic charge/discharge cycles in ethylene carbonate-dimethylcarbonate (1:1) – LiPF 6 1 M displayed 80% capacity retention after 200 cycles at C/2 and 30 °C, and a high charge and discharge rate capability at C-rate from C/3 (0.33 A/g) to 10C (10 A/g) at 30° and 10 °C. Electrodes with the highest alloy loading delivered up to 0.6 mAh cm −2 at C/2. The performance of these electrodes in battery config…
Improved composite materials for rechargeable lithium metal polymer batteries
1999
Abstract The performance of several polymer electrolytes for lithium metal batteries for electric vehicle applications are reported. The best performing electrolyte is the composite PEO 20 LiCF 3 SO 3 –γLiAlO 2 , which was prepared by a solvent-free procedure. It showed coulombic efficiency values of the lithium deposition–stripping process of 94%–96%. Electrochemical tests of lithium polymer battery (LPB) prototypes based on a 3 V LiMn 2 O 4 composite cathode material laminated together with the PEO 20 LiCF 3 SO 3 –γLiAlO 2 electrolyte gave promising results for electric vehicle applications. Even under non-optimized battery design, the prototypes delivered, at the C/3 rate and at 94°C, 40…