Search results for "Belousov-Zhabotinsky"

showing 7 items of 7 documents

Isotopic Effect on the Kinetics of the Belousov-Zhabotinsky Reaction

2007

In this work we present results about the deuterium isotope effect on the global kinetics of a Belousov-Zhabotinsky reaction in batch conditions. A nonlinear dependence of the Induction Period upon the percentage of deuterated reactants was found. The isotopic effect on the bromination reaction of malonic acid was evaluated.

Belousov-Zhabotinsky reactionInduction periodKineticsInorganic chemistryBelousov-ZhabotinskyBromination reactionMalonic acidIsotopic effectCatalysislcsh:ChemistryInorganic Chemistrychemistry.chemical_compoundBromination reaction.Kinetic isotope effectPhysical and Theoretical Chemistrylcsh:QH301-705.5Molecular BiologySpectroscopyInduction PeriodChemistryCommunicationOrganic ChemistryBelousov-Zhabotinsky; reaction Isotopic effect; Induction Period; Enolization; Bromination reactionHalogenationGeneral MedicineKeto–enol tautomerismEnolizationComputer Science ApplicationsCHIM/02 Chimica fisicareaction Isotopic effectBelousov–Zhabotinsky reactionlcsh:Biology (General)lcsh:QD1-999DeuteriumPhysical chemistryInternational Journal of Molecular Sciences
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Pattern formation in the BZ/C14DMAO zwitterionic micellar system

2009

Belousov-Zhabotinsky zwitterionic surfactantSettore CHIM/02 - Chimica Fisica
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Spatio-temporal perturbation of the dynamics of the ferroin catalyzed Belousov-Zhabotinsky reaction in a batch reactor caused by sodium dodecyl sulfa…

2008

The effects of the anionic surfactant sodium dodecyl sulfate (SDS) on the spatio-temporal and temporal dynamics of the ferroin-catalyzed Belousov-Zhabotinsky (BZ) reaction have been studied over a wide surfactant concentration range. For the first time, investigations were performed also for unstirred systems. The presence of SDS in the reaction mixture influences the oscillatory parameters to an extent that significantly depends on the surfactant concentration. The trend of the wave speed v upon the increasing amount of SDS was found to have a maximum at [SDS] = 0.075 mol dm (-3) ( v = 0.071 mm s (-1)), after which the speed decreased to 0.043 mm s (-1) at [SDS] = 0.5 mol dm (-3), which is…

Inorganic chemistryBatch reactorsodium dodecyl sulfate Belousov-Zhabotinsky non-linear dynamicsMicelleSurfaces Coatings and FilmsCatalysischemistry.chemical_compoundBelousov–Zhabotinsky reactionchemistryPulmonary surfactantFerroinMaterials ChemistryPhysical and Theoretical ChemistrySodium dodecyl sulfateThe journal of physical chemistry. B
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Dynamics of Pattern Formation in Biomimetic Systems

2008

This paper is an attempt to conceptualize pattern formation in self-organizing systems and, in particular, to understand how structures, oscillations or waves arise in a steady and homogenous environment, a phenomenon called symmetry breaking. The route followed to develop these ideas was to couple chemical oscillations produced by Belousov-Zhabotinsky reaction with confined reaction environments, the latter being an essential requirement for any process of Life. Special focus was placed on systems showing organic or lipidic compartments, which represent more reliable biomimetic matrices.

Statistics and Probability{CHEMICAL} {OSCILLATORS}Belousov-Zhabotinsky reactionLipid BilayersPattern formationNanotechnology{CHEMICAL} {OSCILLATORS}; Lipid systems; Reverse microemulsionsModels BiologicalTuring structuresGeneral Biochemistry Genetics and Molecular BiologyDiffusionBiomimeticsChemical oscillatorsAnimalsSymmetry breakingPhysicsGeneral Immunology and MicrobiologyChemistry PhysicalSystems BiologyApplied MathematicsLipid systemsBiomimetic systemsGeneral MedicineBelousov-Zhabotinsky reaction; Chemical oscillators; Turing structures; Biomimetic systems; Lipid systems; Reverse microemulsionsReverse microemulsionsBelousov–Zhabotinsky reactionModeling and SimulationEmulsionsGeneral Agricultural and Biological SciencesBiological system
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Origin and extinction of chaotic oscillations in the Belousov-Zhabotinsky reaction

2010

chaos Belousov-Zhabotinsky reactionSettore CHIM/02 - Chimica Fisica
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Behaviour of the Belousov-Zhabotinsky oscillator in the presence of carboxymethyl-celulose

2008

polymer Belousov-Zhabotinsky oscillatorSettore CHIM/02 - Chimica Fisica
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An experimental model for mimicking biological systems: the Belousov-Zhabotinsky reaction in Lipid membranes

2006

{LIPID} {BILAYERS}Belousov-Zhabotinsky reaction; Biomimetic systems; Cell membranes; Lipid bilayers; Morphogenesis; Self-organizing systemsEcologyLipid bilayersChemistryExperimental modelBelousov-Zhabotinsky reaction{BELOUSOV-ZHABOTINSKY} {REACTION}; Biomimetic systems; Cell membranes; {LIPID} {BILAYERS}; morphogenesis; Self-organizing systemsSelf-organizing systemsBiomimetic systemsCell membranesMembraneBelousov–Zhabotinsky reactionBiophysicsMorphogenesis{BELOUSOV-ZHABOTINSKY} {REACTION}Lipid bilayerEcology Evolution Behavior and Systematics
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