Search results for "Beni culturali"
showing 10 items of 1017 documents
La comunicazione del paesaggio come strategia di marketing territoriale
2018
Pensare al marketing territoriale in un contesto complesso come il sistema Italia impone di risemantizzare il termine soprattutto in funzione del patri- monio culturale. A fronte della ricchezza del patrimonio culturale italiano, che si distingue sia per la qualità e l’elevata concentrazione su tutto il territorio nazionale (l’Italia è la nazione dove è localizzato il maggior numero di siti inclusi nella lista mondiale del patrimonio dell’umanità riconosciuta dall’UNESCO), sia per la diversificazione dei beni che si estende dalle aree archeologiche ai monumenti architettonici, dai beni di interesse storico-artistico e paesaggi- stico al patrimonio immateriale, risalta con particolare eviden…
Un protocollo scientifico per la desalinizzazione di materiali lapidei: caso studio dei mosaici della Villa del Casale (Sicilia)
2009
Dynamical properties of myoglobin in an ultraviscous water-glycerol solvent investigated with elastic neutron scattering and FTIR spectroscopy
2018
Abstract Proteins have distinctive dynamical properties, characterized by the fluctuations of protein molecules among the different minima of their energy landscape. These fluctuations, progressively activated for temperature values larger than ~180 K, lead to a steep increase in the temperature dependence of all measurable dynamical properties. This phenomenon is known as Protein Dynamical Transition and, in spite of the intense studies due to its importance in protein function and to the relation with the fascinating fundamental thermodynamics of complex systems, many aspects of it are not yet clearly understood. Among these, the relationship with the properties of the external solvent an…
Hysteresis in the temperature dependence of the IR bending vibration of deeply cooled confined water.
2019
Using Fourier Transform Infrared (FTIR) spectroscopy, we investigate the temperature dependence of the bending vibrations of water confined in the pores of a silica hydrogel in the temperature interval of 270-180 K. We also investigate the presence of thermal hysteresis by cooling and reheating temperature scans. The results clearly show the presence, at about 230 K, of a crossover in the temperature dependence of the IR spectra; moreover, the presence of hysteresis is clearly demonstrated. By comparing FTIR data with neutron diffraction data and previous calorimetric data on the same samples, we conclude that the crossover and the hysteretical behavior do not involve a water glass transiti…
Energy resolution and throughput of a new real time digital pulse processing system for x-ray and gamma ray semiconductor detectors
2013
New generation spectroscopy systems have advanced towards digital pulse processing (DPP) approaches. DPP systems, based on direct digitizing and processing of detector signals, have recently been favoured over analog pulse processing electronics, ensuring higher flexibility, stability, lower dead time, higher throughput and better spectroscopic performance. In this work, we present the performance of a new real time DPP system for X-ray and gamma ray semiconductor detectors. The system is based on a commercial digitizer equipped with a custom DPP firmware, developed by our group, for on-line pulse shape and height analysis. X-ray and gamma ray spectra measurements with cadmium telluride (Cd…
Fluorescent nitrogen-rich carbon nanodots with an unexpected β-C3N4nanocrystalline structure
2016
Carbon nanodots are a class of nanoparticles with variable structures and compositions which exhibit a range of useful optical and photochemical properties. Since nitrogen doping is commonly used to enhance the fluorescence properties of carbon nanodots, understanding how nitrogen affects their structure, electronic properties and fluorescence mechanism is important to fully unravel their potential. Here we use a multi-technique approach to study heavily nitrogen-doped carbon dots synthesized by a simple bottom-up approach and capable of bright and color-tunable fluorescence in the visible region. These experiments reveal a new variant of optically active carbonaceous dots, that is a nanocr…
Halloysite Nanotubes: Interfacial Properties and Applications in Cultural Heritage
2020
The peculiar surfaces of halloysite nanotubes and their biocompatibility are attracting the interest of researchers based on the wide range of attainable applications. The large aspect ratio of this nanotubular material ensures promising properties as a reinforcing agent in polymeric matrixes, such as cellulose and its derivatives, that entail strengthening due to, for instance, aging-induced degradation. The halloysite cavity has a suitable size for hosting a large variety of active species such as deacidifying (calcium hydroxide) and flame retardant agents (fluorinated surfactants) for a controlled and sustained release relevant to the conservation of cultural heritage. Additionally, anio…
Proteins in amorphous saccharide matrices: Structural and dynamical insights on bioprotection
2013
Bioprotection by sugars, and in particular trehalose peculiarity, is a relevant topic due to the implications in several fields. The underlying mechanisms are not yet clearly elucidated, and remain the focus of current investigations. Here we revisit data obtained at our lab on binary sugar/water and ternary protein/sugar/water systems, in wide ranges of water content and temperature, in the light of the current literature. The data here discussed come from complementary techniques (Infrared Spectroscopy, Molecular Dynamics simulations, Small Angle X-ray Scattering and Calorimetry), which provided a consistent description of the bioprotection by sugars from the atomistic to the macroscopic …
Detection of Irradiated Food and Evaluation of the Given Dose by Electron Spin Resonance, Thermoluminescence, and Gas Chromatographic/Mass Spectromet…
2018
Abstract The treatment of food with ionizing radiation, at doses lower than 10 kGy, is a preservation technology, which can be used to reduce food spoilage due to microorganisms and to decrease insect infestation, enhancing, in the same time, the hygienic quality, extending the shelf life of food itself. In order to increase the general consumer acceptance and accordingly to facilitate the commercialization and trade of irradiated food, the European Committee for Standardization (CEN) validated reliable analytical techniques to identify irradiated foodstuffs for legal control purposes, distinguished in Chemical, Physical, and Microbiological ones, depending on the characteristics of marker …
Dynamics of nanoparticles in a supercooled liquid
2008
The dynamic properties of nanoparticles suspended in a supercooled glass forming liquid are studied by x-ray photon correlation spectroscopy. While at high temperatures the particles undergo Brownian motion the measurements closer to the glass transition indicate hyperdiffusive behavior. In this state the dynamics is independent of the local structural arrangement of nanoparticles, suggesting a cooperative behavior governed by the near-vitreous solvent.