Search results for "Benzotriazole"

showing 10 items of 26 documents

1-Benzyl-1H-benzotriazole 3-oxide-1-hy-droxy-1H-benzotriazole (1/1).

2012

In the title compound, C6H5N3O·C13H11N3O, the benzotriazole ring system in the 1-benzyl-1H-benzotriazole 3-oxide (A) molecule is close to being planar (r.m.s. deviation = 0.011 Å); its mean plane forms a dihedral angle of 67.56 (7)° with that of the attached phenyl ring. The benzotriazole ring system in the 1-hydroxybenzotriazole (B) molecule is also close to being planar (r.m.s. deviation = 0.010 Å). In the crystal, weak C—H...O and C—H...π interactions are present. TheAandBmolecules are linked by an O—H...N hydrogen bond.

BenzotriazoleHydrogen bondOxide1h benzotriazoleGeneral ChemistryDihedral angleCondensed Matter PhysicsRing (chemistry)BioinformaticsOrganic PapersCrystalchemistry.chemical_compoundCrystallographychemistryMoleculeGeneral Materials ScienceActa crystallographica. Section E, Structure reports online
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Synthesis and photovoltaic performance of the porphyrin based sensitizers with 2H-[1,2,3]triazolo[4,5-c]pyridine and benzotriazole as auxiliary accep…

2017

Abstract Two novel zinc porphyrin dyes containing either benzotriazole or 2 H -[1,2,3]triazolo[4,5- c ]pyridine as auxiliary acceptors, respectively, were synthesized for dye-sensitized solar cells. These two auxiliary acceptors were firstly applied into porphyrin based dyes. The photophysical and electrochemical properties of the dyes were investigated. These two dyes show the whole visible light absorption when they are adsorbed on the TiO 2 film, which means that they are promising sensitizers for dye-sensitized solar cells. The absorption intensity of the triazolopyridine containing dye is higher than that of the benzotriazole containing dye, resulting in a better light harvesting. Thus…

BenzotriazoleProcess Chemistry and TechnologyGeneral Chemical EngineeringEnergy conversion efficiency02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologyElectrochemistryPhotochemistry01 natural sciencesPorphyrin0104 chemical scienceslaw.inventionchemistry.chemical_compoundchemistrylawPyridineSolar cellTriazolopyridine0210 nano-technologyVisible spectrumDyes and Pigments
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Inhibitoren der Korrosion 31 (1). Beitrag zur Inhibierung der Korrosion von Zink und Messing

1986

Folgende als Inhibitoren der Korrosion vom Kupfer bewahrte Verbindungen wurden bei Korrosionsstudien mit Zink und Messing eingesetzt: 2-Aminopyrimidin (A), 5-Aminotetrazolmonohydrat (B), Benzotriazol (C), Kupferron (D), 2-Mercaptopyrimidin (E), 2-Mercaptothiazolin (F), 2-Methyl-4-amino-5-cyanopyrimidin (G), Tetrazin-B (H) und Xanthanwasserstoff (I). Bei Zinkblechen wird unter Standardbedingungen in Gegenwart der Verbindungen A, B, C, E und G im Laufe von 15 Tagen Totalkorrosion beobachtet. In Anwesenheit der Verbindungen D, F und H werden prozentuale Schutzwerte von 29%, 14% und 39% beobachtet. Ein differenzierteres Bild vermitteln die pH-statisch ermittelten Saureverbrauchs-Zeit-Kurven mit…

Compound aBenzotriazoleMechanical EngineeringMetals and Alloyschemistry.chemical_elementGeneral MedicineZincCopperSurfaces Coatings and FilmsCorrosionchemistry.chemical_compoundchemistryMechanics of MaterialsMaterials ChemistryEnvironmental ChemistryNuclear chemistryCompound cMaterials and Corrosion/Werkstoffe und Korrosion
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1,1′-[2,3,5,6-Tetramethyl-p-phenylenebis(methyleneoxy)]di-1H-benzotriazole

2009

The complete molecule of the title compound, C(24)H(24)N(6)O(2), is generated by a crystallographic inversion centre. The benzotriazole rings form dihedral angles of 2.10 (7)° with the central aromatic ring. The crystal packing is consolidated by π-π inter-actions, with centroid-centroid distances of 3.6234 (10) Å, together with weak C-H⋯π inter-actions.

Crystalchemistry.chemical_compoundBenzotriazoleChemistryMoleculeGeneral Materials ScienceGeneral ChemistryDihedral angleCondensed Matter PhysicsBioinformaticsRing (chemistry)Organic PapersMedicinal chemistryActa Crystallographica Section E Structure Reports Online
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1-(2,3,5,6-Tetramethylbenzyloxy)-1H-benzotriazole

2009

In the title compound, C17H19N3O, the benzotriazole ring is essentially planar, with a maximum deviation of 0.0069 (15) Å. The mean plane of the benzotriazole ring forms a dihedral angle of 13.16 (4)° with the mean plane of the benzene ring. The crystal packing is stabilized by π–π stacking interactions, with a centroid–centroid distance of 3.8077 (12) Å, together with weak C—H...π interactions. Molecules are stacked along the a axis.

CrystallographyBenzotriazolebiologyPlane (geometry)StackingGeneral ChemistryDihedral angleCondensed Matter PhysicsBioinformaticsRing (chemistry)biology.organism_classificationOrganic PapersCrystalchemistry.chemical_compoundCrystallographychemistryQD901-999TetraGeneral Materials ScienceBenzeneActa Crystallographica Section E Structure Reports Online
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Titanium complexes for the formation of nitrogen compounds : synthesis of homoallylamines and amidines

2011

Homoallylic amines are key reagents for the formation of a large number of biologically interesting products. Due to the double bond of their allylic moiety, easily functionalisable, they are commonly used in organic synthesis. This research work deals with the synthesis of homoallylic amines thanks to titanium complexes. In fact, the reductive coupling between of imines and dienes promoted by titanium allows the formation of diastereoisomeric homoallylamines syn and anti. The diastereoselectivity of the reaction is directly affected by the nitrogen substituent. Whether it is benzyl or phenyl, the selectivity will be in favour of syn or anti respectively. Moreover, the addition of a the Lew…

Homoallylic aminesTitaniumDérivés benzotriazoleAllyltitanationHomoallyl-(E)-homocrotylaminesHomoallylaminesMacrocyclic diamidinesRéarrangement cationique 2-Aza-CopeTitaneCationic 2-Aza- Cope rearrangementDioxocyclamesDérivés bis(benzotriazole)HomocrotylaminesBenzotriazole derivatives[CHIM.OTHE] Chemical Sciences/Other[ CHIM.OTHE ] Chemical Sciences/OtherBis(benzotriazole) derivativesDioxocyclamsAmines homoallyliques[CHIM.OTHE]Chemical Sciences/OtherDiamidines macrocyliques
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CCDC 726494: Experimental Crystal Structure Determination

2009

Related Article: B.R.D.Nayagam, S.R.Jebas, C.Daisy, D.Schollmeyer|2009|Acta Crystallogr.,Sect.E:Struct.Rep.Online|65|o918|doi:10.1107/S1600536809010782

Space GroupCrystallography11'-[2356-Tetramethyl-p-phenylenebis(methyleneoxy)]di-1H-benzotriazoleCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 914295: Experimental Crystal Structure Determination

2013

Related Article: P.Selvarathy Grace, S.R.Jebas, B.Ravindran Durai Nayagam, D.Schollmeyer|2012|Acta Crystallogr.,Sect.E:Struct.Rep.Online|68|o3297|doi:10.1107/S1600536812044868

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates1-Benzyl-1H-benzotriazole 3-oxide monohydrate
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CCDC 253085: Experimental Crystal Structure Determination

2005

Related Article: E.A.Goreshnik, D.Schollmeyer, M.G.Mys'kiv|2005|Z.Anorg.Allg.Chem.|631|835|doi:10.1002/zaac.200400469

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(mu~2~-1-Allylbenzotriazole-NN')-tetrakis(mu~2~-chloro)-bis(1-allylbenzotriazole-N)-dichloro-tri-copper(ii)
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CCDC 253086: Experimental Crystal Structure Determination

2005

Related Article: E.A.Goreshnik, D.Schollmeyer, M.G.Mys'kiv|2005|Z.Anorg.Allg.Chem.|631|835|doi:10.1002/zaac.200400469

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu~3~-Chloro)-bis(mu~2~-1-allylbenzotriazole-NN')-bis(mu~2~-chloro)-chloro-di-copper(ii))Experimental 3D Coordinates
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