Search results for "Biocomposite"
showing 10 items of 74 documents
Coffee grounds as filler for pectin: Green composites with competitive performances dependent on the UV irradiation.
2017
Novel composite bioplastics were successfully prepared by filling pectin matrix with treated coffee grounds. The amount of coffee dispersed into the pectin was changed within a wide filler range. The morphology of the pectin/coffee hybrid films was studied by microscopic techniques in order to investigate their mesoscopic structure as well as the sizes distribution of the particles dispersed into the matrix. The micrographs showed that the coffee grounds are uniformly dispersed within the polymeric matrix. The morphological characteristics of the biocomposite films were correlated to their properties, such as wettability, water uptake, thermal behavior and mechanical performances. Dynamic m…
Impact of hydrothermal ageing on the thermal stability, morphology and viscoelastic performance of PLA/sisal biocomposites
2016
The influence of the combined exposure to water and temperature on the behaviour of polylactide/sisal biocomposites coupled with maleic acid anhydride was assessed through accelerated hydrothermal ageing. The biocomposites were immersed in water at temperatures from 65 to 85 °C, between the glass transition and cold crystallisation of the PLA matrix. The results showed that the most influent factor for water absorption was the percentage of fibres, followed by the presence of coupling agent, whereas the effect of the temperature was not significant. Deep assessment was devoted to biocomposites subjected to hydrothermal ageing at 85 °C, since it represents the extreme degrading condition. Th…
Effect of Elongational Flow and Polarity of Organomodified Clay on Morphology and Mechanical Properties of a PLA Based Nanobiocomposite
2016
Abstract In biodegradable polymer world nanobiocomposites represent a new group of materials filled with inert nanoparticles that shows very interesting properties and the biodegradability of the matrix. In this work we have studied the effect of the polarity of the organomodified montmorillonite and of the elongational flow on the morphology and the rheological and mechanical properties of a new nanobiocomposite with a matrix of biodegradable PLA based blend. The elastic modulus enhances in presence of the nanofiller and this increase is larger and larger with the increment of the orientation. The tensile strength does not show any significant change at the same level of orientation. Moreo…
Thermomechanical degradation of PLA-based nanobiocomposite
2016
Nanobiocomposites are a new class of biodegradable polymer materials with nanometric dispersion of inert particles in a biodegradable polymer matrix that show very interesting properties often very different from those of conventional- filled polymers and also biodegradability. An important issue in the applications of the biodegradable polymers is their easy degradability during processing due to the thermomechanical stress or to the presence of humidity. In this work, the thermomechanical degradation behavior of a nanobiocomposite made by a PLA-based blend and an organomodified montmorillonite has been investigated. The degradation kinetics has been followed by means of rheological, mecha…
Biocomposite PBAT/lignin blown films with enhanced photo-stability.
2022
Lignin can be obtained as a byproduct during cellulose-rich pulp fibers production and it is habitually treated as waste or intended for low-value destinations. However, due to UV absorption and mechanical properties, lignin can contribute to the fabrication of biodegradable blown films with superior performances. In this study, it was established the suitability of lignin for manufacturing biocomposite PBAT blown films with higher stiffness and photo-oxidation resistance. The effect of the filler concentration on the melt rheological behavior in non-isothermal elongational flow was investigated. The results allowed us to choose the correct filler concentration for producing films through a…
DEGRADATION OF MATER-BI /WOOD FLOUR BIOCOMPOSITES IN ACTIVE SEWAGE SLUDGE
2009
The mechanical properties of Mater-Bi® are, in general, not adequate for certain applications and the addition of a filler is therefore necessary. Among the different fillers, natural fibres are particularly interesting because they potentially allow improving the performance of the material without compromising its biodegradability. In order to improve the basic mechanical properties of a Mater-Bi grade and to obtain a new, fully biodegradable material, wood flour based composites were prepared by different processing methods. To simulate actual and not laboratory bacterial attack on the prepared materials, in this work we studied the biodegradation of the composites in a real active sewag…
Optimal manufacturing and mechanical characterization of high performance biocomposites reinforced by sisal fibers
2018
Abstract The increasing interest about eco-sustainable materials in the industrial production (automotive, civil construction, packaging), has led to the increase of the research works dealing with biocomposites. However, until now the most attention has been devoted to the development of short fiber biocomposites for non-structural applications, whereas only a few works have considered high performance biocomposites for structural applications. Consequently, the development of structural biocomposites from robust natural fibers, as sisal fibers, is a result expected from the scientific community, but not yet achieved. In order to give a contribution to the implementation of high performanc…
Thermal and structural properties of a hemp–lime biocomposite
2013
Abstract The need to reduce greenhouse gases emission produced by the building sector leads to the research of renewable and less impacting materials that can replace traditional ones. This subject has encouraged new researches on biocomposite concretes with the aim to exploit renewable resources like vegetal fibres intended as materials whose production processes are generally characterized by low costs and energy demand. This biocomposite is obviously much lighter than concrete and, therefore, can be suitably used in such cases where a structure cannot be overloaded, for instance in the realization of a green covering on top of a preexistent building. In this work, a first analysis of the…
RESISTENZA STATICA E A FATICA DI NUOVI LAMINATI BIOCOMPOSITI RINFORZATI CON FIBRE DI AGAVE
2018
L’obiettivo di ridurre l’inquinamento legato alla produzione ed allo smaltimento dei materiali sintetici ha portato recentemente alla messa punto di normative di protezione ambientale che impongono l’uso crescente di materiali ecocompatibili e/o rinnovabili, e conseguentemente Ad un notevole interesse verso i cosiddetti biocompositi, materiali innovativi ottenuti attraverso il rinforzo di polimeri ecocompatibili o rinnovabili con fibre naturali quali lino, juta, canapa, agave ecc. Nonostante numerosi lavori di ricerca siano stati indirizzati a tali materiali, allo stato attuale pochi lavori hanno riguardato lo sviluppo di biocompositi ad elevate performance per applicazioni strutturali. Al …
Environmental aging effects on high-performance biocomposites reinforced by sisal fibers
2023
Among the innovative materials, an important role is played by the so-called biocomposites, generally made by an eco-friendly matrix reinforced with natural fibers. Unfortunately, due to the degradability of the green matrixes as well as to hydrophilicity of the natural fibers, the resistance of such innovative materials to the environmental agents is, in general, relativity low, and it can significantly limit their use in outdoor conditions. To contribute to the knowledge of the effects of the leading environmental agents on the mechanical properties of highperformance biocomposites made of a green epoxy matrix reinforced by agave fibers, a systematic experimental testing campaign has been…