Search results for "Biodegradable polymer"

Natural compounds as light stabilizers for biodegradable polymers

2013

USE OF BIODEGRADABLE POLYMERS FOR FOAM EXTRUSION

2013

Toward the Decarbonization of Plastic: Monopolymer Blend of Virgin and Recycled Bio-Based, Biodegradable Polymer.

2022

Decarbonization of plastics is based on two main pillars: bio-based polymers and recycling. Mechanical recycling of biodegradable polymers could improve the social, economic and environmental impact of the use of these materials. In this regard, the aim of this study was to investigate whether concentrations of the same recycled biopolymer could significantly affect the rheological and mechanical properties of biodegradable monopolymer blends. Monopolymer blends are blends made of the same polymers, virgin and recycled. A sample of commercially available biodegradable blend was reprocessed in a single-screw extruder until two extrusion cycles were completed. These samples were exposed to gr…

Photo-Oxidative and Soil Burial Degradation of Irrigation Tubes Based on Biodegradable Polymer Blends

2019

: Irrigation tubes based on biodegradable polymers were prepared via an extrusion-drawing process by Irritec and compared to conventional pipes made of high-density polyethylene (HDPE). A commercial polylactide/poly (butyleneadipate-co-butyleneterephthalate) (PLA/PBAT) blend (Bio-Flex&reg

Mucoadhesive Polymer Hyaluronan as Biodegradable Cationic/Zwitterionic-Drug Delivery Vehicle

2014

Mucoadhesive polymers in pharmaceutical formulations release drugs in mucosal areas. They interact and fix to mucus via molecular interpenetration, etc ., which increase drug bioavailability. Polymers physicochemical properties affect formulation mucoadhesion, rheological behaviour and drug absorption. Hyaluronan (HA) is selected as a mucoadhesive and biodegradable polymer. Geometric, topological and fractal analyses are carried out with program TOPO. Reference calculations are performed with algorithm GEPOL. Procedure TOPO underestimates molecular volume by 0.7%. Error results 5% in surface area and derived topological indices. Solvent-accessible surface is undercalculated by 3%: from hexa…

Biodegradable microtablets made of low molecular weight polyglycolic acid: Bioabbaubare Mikrotabletten aus niedermolekularer Polyglycolsäure

1991

Research work in developing pharmaceutical dosage forms with biodegradable polymers seldom dealt with polyglycolic acid (PGA)1,2. This because of difficult processing procedures and low solubility of PGA in common organic solvents2,3. The only licensed product of the homoplymer in medical use is the sufgical suture Dexon®4

Antibacterial performance of solvent cast polycaprolactone (PCL) films containing essential oils

2013

Abstract The increase of consumer demand for higher quality and longer shelf-life in foods, while reducing the use of non-compostable packaging materials, has encouraged research on biopolymers incorporating natural antimicrobial compounds. Cinnamaldehyde (CNMA) and allyl isothiocyanate (AITC) were incorporated into polycaprolactone (PCL) films by solvent casting. The release study was carried out by means of ATR and transmission FTIR spectroscopy and showed high volatility of the essential oils during the film forming process. While only negligible quantities of AITC were retained in the polymer matrix after film curing, the release of CNMA was prolonged for at least 50 h at room temperatu…

Rheological Behaviour, Mechanical Properties and Processability of Biodegradable Polymer Systems for Film Blowing

2017

Films for agricultural or packaging applications are typically made of low density polyethylene (LDPE). They are produced through the film blowing process, which requires the use of polymers with suitable rheological properties. Furthermore, the short shelf-life which is often related to many packed products leads to huge amounts of plastic-based wastes. This suggests the use of biodegradable and/or compostable polymers in replacement for traditional ones. To this regard, only few data exist on the rheological properties of biodegradable polymers undergoing film blowing processing. In this work, a detailed investigation on the rheological, mechanical and processability behaviour of some bio…

Rheological Behavior Under Shear and Non-Isothermal Elongational Flow of Biodegradable Polymers for Foam Extrusion

2013

The production of many items, in particular for food packaging applications, is based on foam extrusion and thermoforming. These operations require the use of polymers which can grant some specific rheological properties, both under shear and elongational flow. In this work, the behavior of some biodegradable polymers [Mater-Bi® and poly(lactic acid)] under shear and non-isothermal elongational flow was investigated and compared with a traditional, non-biodegradable polymer, in order to assess their suitability for industrial-scale foam extrusion and thermoforming. The rheological characterization evidenced the differences between the different biodegradable polymers and the reference polys…

Synthesis of polycaprolactone by microwave irradiation ? an interesting route to synthesize this polymer via green chemistry

2003

Poly(e-caprolactone) has become an important biocompatible and biodegradable polymer. Indeed, due to its multiple biomedical applications, the synthesis of polycaprolactone has received increased attention in the past few decades. Moreover, microwave irradiation is a very clean modern technique widely used for green chemistry. Here, several polymers were synthesized by microwave irradiation, without any solvent, using nontoxic, biologically acceptable lanthanide halides as initiators. Reaction times varied between 2 and 90 min. The molecular weights of the obtained polymer products were between 3,000 and 16,000 g/mol. After polymerization, the polycaprolactone polymers were functionalized b…