Search results for "Bismuthate"
showing 8 items of 8 documents
Phase transitions in i-butylammonium halogenoantimonate(III) and bismuthate(III) crystals
1997
Abstract Differential scanning calorimetry, dielectric, thermal expansion, infrared and preliminary X-ray diffraction studies on i-butylammonium halogenoantimonate(III) and bismuthate(III) crystals are reported. All crystals: (i-C4H9NH3)2BiCl5, (i-C4H9NH3)2SbBr5, (i-C4H9NH3)3BiCl6, (i-C4H9NH3)3Bi2Br9, (i-C4H9NH3)3Sb2Br9, show one or more structural phase transitions of first order type. The values of the transition entropies suggest that the most of the phase transitions are of the order-disorder type. The infrared studies confirmed the contribution of the i-butylammonium cations in the phase transition mechanism.
Synthesis and crystal structure of [(PhenH)(PhenH2)][BiCl6] . 2H2O with different o-phenanthroline protonations.
1998
The reaction between bismuthate oxide and phen (1,10-phenanthroline) in acid medium led to the isolation of the unusual [(PhenH)(PhenH2)][BiCl6] 2H2O derivative, which has been characterized by X-ray analysis and IR spectroscopy. The compound crystallizes in the triclinic space group P1 with a = 8.313(2), b = 9.349(2), c = 9.807(3) A, a = 86.39(3), B = 110.27(3) and y = 106.48(3)°. The crystal structure is made of [BiCl6] 3- anions and [(PhenHXPhenr2)]3+cations. A network of hydrogen bond interactions involving the two clathrated water molecules, the phenanthroline moiety and the chlorines characterizes the entire structure.
CCDC 152558: Experimental Crystal Structure Determination
2001
Related Article: F.Benetollo, G.Bombieri, A.Del Pra, G.Alonzo, N.Bertazzi|2001|Inorg.Chim.Acta|319|49|doi:10.1016/S0020-1693(01)00436-4
CCDC 152557: Experimental Crystal Structure Determination
2001
Related Article: F.Benetollo, G.Bombieri, A.Del Pra, G.Alonzo, N.Bertazzi|2001|Inorg.Chim.Acta|319|49|doi:10.1016/S0020-1693(01)00436-4
CCDC 152559: Experimental Crystal Structure Determination
2001
Related Article: F.Benetollo, G.Bombieri, A.Del Pra, G.Alonzo, N.Bertazzi|2001|Inorg.Chim.Acta|319|49|doi:10.1016/S0020-1693(01)00436-4
Understanding distortions of inorganic substructures in chloridobismuthates(III)
2021
The molar ratio variations of organic and inorganic reactants of chloridobismuthates(III) with N,N-dimethylethane-1,2-diammonium, [(CH3)2NH(CH2)2NH3]2+, and N,N,N′,N′-tetramethylguanidinium, [NH2C{N(CH3)2}2]+, cations lead to the formation of four different products, namely, tris(N,N-dimethylethane-1,2-diammonium) bis[hexachloridobismuthate(III)], [(CH3)2NH(CH2)2NH3]3[BiCl6]2 (1), catena-poly[N,N-dimethylethane-1,2-diammonium [[tetrachloridobismuthate(III)]-μ-chlorido]], {[(CH3)2NH(CH2)2NH3][BiCl5]} n (2), tris(N,N,N′,N′-tetramethylguanidinium) tri-μ-chlorido-bis[trichloridobismuthate(III)], [NH2C{N(CH3)2}2]3[Bi2Cl9] (3), and catena-poly[N,N,N′,N′-tetramethylguanidinium [[dichloridobismutha…
The influence of aromatic cations on the geometries of the Bi(III) halide polyhedra. Synthesis and crystal structures of quinolinium, isoquinolinium …
2001
Abstract The compounds [quinolinium]4[Bi2Cl10] (1), [isoquinolinium]4[Bi2Cl10].2H2O (2) and [8-hydroxyquinolinium]4[BiCl6]·Cl·2H2O (3) have been obtained by reacting bismuthate oxide and the appropriate base in HCl acid medium. The crystal structures of 1 and 2 consist of quinolinium and isoquinolinium cations, respectively, interacting through hydrogen bonding with [Bi2Cl10]4− dimers. The different degree of interactions in the two derivatives causes significant differences in the bond distances of the anions. The crystal structure of 3 is made of [BiCl6]3− and Cl− anions and 8-hydroxyquinolinium cations. Hydrogen bond interactions including the N-bonded and O-bonded H atoms together with …
Phase transitions and distortion of [BiCl6]3– octahedra in (C3H5NH3)3[BiCl6] – DSC and single-crystal X-Ray diffraction studies
2004
The DSC diagram of tris(allylammonium) hexachlorobismuthate(III), (C3H5NH3)3[BiCl6], revealed three anomalies at 152, 191 and 299 K. The structure of the salt was determined at 200 and 315 K, below and above the high-temperature phase transition at 299 K. In both phases the crystals are monoclinic. At 200 K the space group is C2/c whereas at 315 K it is C2/m. The structures, at both temperatures, are composed of [BiCl6]3− octahedra and allylammonium cations. The organic and inorganic moieties are attracted to each other by a network of the N-H. . .Cl hydrogen bonds. The relationship between corresponding parameters of the unit cells has been found. The phase transition at 299 K, of the orde…