Search results for "Boundary"

The effects of different radiation parametrizations on cloud evolution

1997

With the use of the microphysical stratus model (MISTRA), investigations into the effects of variations in the radiative-transfer parametrizations on cloud development have been undertaken. Two radiative-transfer schemes were coupled with the microphysical-thermodynamical section of MISTRA, one based on the exponential sumfitting method and the other based on the correlated k-distribution method of determining gaseous absorption properties. Model runs were initiated with parameter values in accordance with measurements made over the North Sea and comparisons made between model runs where only the radiation schemes were altered. Results indicated that differences between the two schemes had …

A numerical model of the cloud-topped planetary boundary-layer: Radiation, turbulence and spectral microphysics in marine stratus

1996

A numerical model of the cloud-topped planetary boundary-layer is presented. The model is one-dimensional with special emphasis on a detailed description of cloud microphysical processes. Aerosols and cloud droplets are treated in a two-dimensional particle-distribution whereby the activation of aerosols is calculated explicitly by solving the droplet-growth equation at all relative humidities. Atmospheric radiation is determined with a δ-two-stream radiation scheme. Turbulent fluxes are parametrized as a function of the turbulent kinetic energy. Numerical results are presented which are obtained by utilizing measurements made over the North Sea. The interaction between radiation, turbulenc…

Toward Parametrization of Precipitating Shallow Cumulus Cloud Organization via Moisture Variance

2021

The influence of the initial vertical moisture profile on precipitating shallow cumulus cloud organization in terms of the column‐averaged moisture variance is investigated using large‐eddy simulations. Five idealized simulations based on the Rain in Cumulus over the Ocean field experiment with different initial moisture profiles are investigated. All cases simulate precipitating shallow cumulus convection in a marine sub‐tropical region under large‐scale subsidence. The results show that the moisture variance is mainly generated through the interaction of the moisture flux and the moisture gradient in the gradient production term at the top of the boundary layer. The development is charact…

Temperature effect on phase state and reactivity controls atmospheric multiphase chemistry and transport of PAHs

2017

Atmospheric refrigerator increases the global transport and health risks of carcinogenic PAHs.

2017

Abstract. Ozone (O3) is an important atmospheric oxidant, a greenhouse gas, and a hazard to human health and agriculture. Here we describe airborne in situ measurements and model simulations of O3 and its precursors during tropical and extratropical field campaigns over South America and Europe, respectively. Using the measurements, net ozone formation/destruction tendencies are calculated and compared to 3-D chemistry–transport model simulations. In general, observation-based net ozone tendencies are positive in the continental boundary layer and the upper troposphere at altitudes above  ∼  6 km in both environments. On the other hand, in the marine boundary layer and the middle tropospher…

Airborne observation of mixing across the entrainment zone during PARADE 2011

2016

This study presents the analysis of the structure and air mass characteristics of the lower atmosphere during the field campaign PARADE (PArticles and RAdicals: Diel observations of the impact of urban and biogenic Emissions) on Mount Kleiner Feldberg in southwestern Germany during late summer 2011. We analysed measurements of meteorological variables (temperature, moisture, pressure, wind speed and direction) from radio soundings and of chemical tracers (carbon dioxide, ozone) from aircraft measurements. We focus on the thermodynamic and dynamic properties that control the chemical distribution of atmospheric constituents in the boundary layer. We show that the evolution of tracer profiles…

The importance of stratospheric–tropospheric transport in affecting surface ozone concentrations in the western and northern tier of the United States

2011

Stratospheric–tropospheric exchange (STE) processes contribute at both high and low-elevation monitoring sites to background ozone (O3) concentrations. This study addresses the importance of stratospheric intrusions contributing to enhanced hourly average surface O3 concentrations (i.e., ≥50 ppb) at 12 O3 monitoring stations in the western and northern tier of the US for 2006, 2007, and 2008. The Lagrangian Analysis Tool (LAGRANTO) trajectory model identified specific days when stratosphere-to-troposphere transport was optimal to elevate surface O3 levels. The coincidences between the number of days with a daily maximum hourly average O3 concentration ≥ 50 ppb and stratosphere-to-tropospher…

Emission of iodine-containing volatiles by selected microalgae species

2014

In this study we present the results of an emission study of different phytoplankton samples in aqueous media treated with elevated ozone levels. Halocarbon measurements show that the samples tested released bromoform and different iodocarbons, including iodomethane, iodochloromethane and diiodomethane. Iodide and iodate levels in the liquid phase were representative of concentrations of surface water in a natural environment. Measurement of volatile iodine (I2) emissions from two diatom samples (Mediopyxis helysia and Porosira glacialis) and the background sample (F/2 medium from filtered natural seawater) showed that the quantity of evolved I2 depends on the ozone concentration in the air…

Overview of aerosol properties associated with air masses sampled by the ATR-42 during the EUCAARI campaign (2008)

2013

Abstract. Within the frame of the European Aerosol Cloud Climate and Air Quality Interactions (EUCAARI) project the Météo-France aircraft ATR-42 performed 22 research flights, over central Europe and the North Sea during the intensive observation period in May 2008. For the campaign, the ATR-42 was equipped in order to study aerosol physical, chemical and optical properties, as well as cloud microphysics. During the campaign, continental air masses from Eastern and Western Europe were encountered, along with polar and Scandinavian air masses. For the 22 research flights, retroplume analyses along the flight tracks were performed with FLEXPART in order to classify air masses into five sector…

Seasonal variations in aerosol particle composition at the puy-de-Dôme research station in France

2011

Detailed investigations of the chemical and microphysical properties of atmospheric aerosol particles were performed at the puy-de-Dôme (pdD) research station (1465 m) in autumn (September and October 2008), winter (February and March 2009), and summer (June 2010) using a compact Time-of-Flight Aerosol Mass Spectrometer (cToF-AMS). Over the three campaigns, the average mass concentrations of the non-refractory submicron particles ranged from 10 μg m<sup>−3</sup> up to 27 μg m<sup>−3</sup>. Highest nitrate and ammonium mass concentrations were measured during the winter and during periods when marine modified airmasses were arriving at the site, wh…