Search results for "Branch"

Polyester and Ester Functionalized Dendrimers

2000

Demand for smart and functional materials has raised the importance of the research of dendritic (Greek = tree-like) molecules in organic and polymer chemistry due to their novel physical and mechanical properties. The properties of linear polymers as well as small discrete molecules are combined in this new architectural class of macromolecules, that can be divided into two families: dendrimers and hyperbranched macromolecules, that differ in their branching sequences. Dendrimers contain symmetrically arranged branches emanating from a core molecule together with a well-defined number of end groups corresponding to each generation. This results in an almost monodisperse three-dimensional g…

Dual-broadband rotational CARS modelling of nitrogen at pressures up to 9 MPa. II. Rotational Raman line widths

2002

International audience; Rotational coherent anti-Stokes Raman spectroscopy (CARS) is a well-established spectroscopic technique for thermometry at pre-combustion temperatures an atmospheric pressure. However, at pressures of several MPa, a previous investigation revealed large discrepancies between experimental data and the theoretical model. A re-evaluation has been made of these data (at room temperature and in the range 1.5-9 MPa) with two improvements to the spectral code. The first is the inclusion of an inter-branch interference effect, which is described in detail in Paper I. The second is the use of experimental S-1-branch Raman line widths measured at 295 K, with a temperature depe…

Promising Dendritic Materials: An Introduction to Hyperbranched Polymers

2011

In nature and universe from living to nonliving things, branching occurs anywhere and anytime, such as the Crab Nebula, forked lightning, river basins, trees, nerves, veins, snow crystals, nervures, and proteoglycan ranging from light-years to kilometers, and to microscale and nanoscales (see Figure 1.1 for selected branching patterns). Hence, branching is a general and important phenomenon that could result in faster and more efficient transfer, dissipation, and distribution of energy and/or matter.

Control over Branching Topology by Introducing a Dual Catalytic System in Coordinative Chain Transfer Polymerization of Olefins

2020

Coordinative polymerization brings opportunities for producing well-defined long-chain branched polyolefins specifically by using homogeneous single-site catalysts. Herein, we report a new dual cat...

Amphiphilic Graft Copolymers and Hyperbranched Polymers Based on (3-Vinylphenyl)azomethyl-malonodinitrile

2001

A convenient approach to amphiphilic hyperbranched polymers with thioether shell for the preparation and stabilization of coinage metal (Cu, Ag, Au) …

2014

Direct synthesis of fibrous high molecular weight polyethylene using vanadium catalysts supported on an SiO2ionic liquid system

2015

Polyethylene of fibrous morphology was obtained using Cp2VCl2 and VCl2(salenCl2) catalysts activated by AlEt2Cl and AlEtCl2 and heterogenized on a supported ionic liquid system prepared with SiO2 and 1-(3-triethoxysilyl)propyl-3-methylimidazolium chloroaluminate. The fibre length ranges from 15 to 60 µm, depending on the reaction conditions. The polyethylene is characterized by a high molecular weight ((1.1–2.4) × 106 g mol−1) and a narrow molecular weight distribution (1.4–2.5). It is a linear polymer, properly without branching. The DSC method reveals characteristic changes in melting temperature and crystallinity degree between the first and second scan heating cycles (141 °C and 136 °C,…

Thioether-Bearing Hyperbranched Polyether Polyols with Methionine-Like Side-Chains: A Versatile Platform for Orthogonal Functionalization

2016

The synthesis of thioether-bearing hyperbranched polyether polyols based on an AB/AB2 type copolymerization (cyclic latent monomers) is introduced. The polymers are prepared by anionic ring-opening multibranching copolymerization of glycidol and 2-(methylthio)ethyl glycidyl ether (MTEGE), which is conveniently accessible in a single etherification step. Slow monomer addition provides control over molecular weights. Moderate dispersities (Đ = 1.48–1.85) are obtained, given the hyperbranched structure. In situ 1H NMR copolymerization kinetics reveal reactivity ratios of rG = 3.7 and rMTEGE = 0.27. Using slow monomer addition, copolymer composition can be systematically varied, allowing for th…

Coating fragmentation by branching cracks at large biaxial strain

2007

The fragmentation behaviour of a thin brittle coating attached to a ductile substrate subjected to equibiaxial quasi-static in-plane tension is studied. The experimentally observed cracking patterns are related to repetitively branching coating cracks. The fragmentation process is modelled by the rate equation approach. It is established that fragmentation by branching cracks leads to a qualitatively different fragment distribution compared to binary fragmentation. The fragmentation model is applied to identify crack branching and coating/substrate stress transfer parameters.

Lithium in metal-poor red giants

2009

AbstractThe lithium abundance was calculated for five metal-poor red giant stars from Li i doublet at 6707 Å by fitting the observed high-resolution spectra with synthetic spectra. The lithium abundance was found to be low in all stars, logϵ(Li) ≤ 1.8, confirming lithium depletion on the red giant and asymptotic giant branch.