Search results for "Breaking"
showing 10 items of 383 documents
The replacement of striking workers by technological means
2021
Las tecnologías de la información y la comunicación están teniendo una incidencia decisiva en las relaciones de trabajo tanto en el plano individual como en el plano colectivo. Atendiendo a esta última perspectiva, uno de los ámbitos en los que el impacto de los avances tecnológicos se está manifestando con especial intensidad es en el derecho de huelga. En concreto, uno de los principales retos que se plantean es el relativo a la sustitución de los trabajadores huelguistas mediante medios técnicos, lo cual se ha denominado esquirolaje tecnológico. Con estas premisas, el presente trabajo aborda la problemática subyacente a este tipo de prácticas, partiendo de la obsolescencia de la regulaci…
The su(2|1) Model of Electroweak Interactions and Its Connection to NC Geometry
2002
I review the su(2|1) model of electroweak interactions which is essentially based on the super Lie algebra su(2|1), thus incorporating both usual gauge fields and Higgs fields in one generalized Yang-Mills field. Special emphasis is put on the natural appearance of spontaneous symmetry breaking and other appealing features of the model like generation mixing. Also the connection of the model to noncommutative geometry is briefly discussed.
S-4 as a natural flavor symmetry for lepton mixing
2008
Group theoretical arguments seem to indicate the discrete symmetry S4 as the minimal flavour symmetry compatible with tribimaximal neutrino mixing. We prove in a model independent way that indeed S4 can realize exact tribimaximal mixing through different symmetry breaking patterns. We present two models in which lepton tribimaximal mixing is realized in different ways and for each one we discuss the superpotential that leads to the correct breaking of the flavor symmetry.
Photo Induced Radical Reactions
2012
This article discusses a number of reactions of potential synthetic interest occurring through photochemically generated organic radicals. Emphasis is placed on the nature of the resulting photoproducts, whose formation is discussed on a mechanistic basis. If available, experimental evidence (obtained by laser flash photolysis or related time-resolved techniques) is provided. The material is organized according to the reaction types, for instance, homolytic cleavage, mesolytic cleavage, radical addition, and oxidative or reductive electron transfer. In addition to the classical carboncarbon or carbonhydrogen bond breaking processes, such as the Norrish type I reaction, the hydrogen abstract…
Inverse nonlinear design in silicon waveguides
2014
La tecnologia fotònica basada en silici és objecte d'intensa investigació tant al món acadèmic com a la indústria. Un dels seus principals atractius rau en la seua elevada compatibilitat amb tècniques ja desenvolupades per a la integració de circuits electrònics, cosa que podria reduir el seu cost. A més, el silici ofereix una gran diversitat d'efectes no lineals que poden ser aprofitats per processar senyals òptics en xips compactes a velocitats superiors als dispositius electrònics actuals. En particular, l'objectiu d'aquesta tesi ha estat dissenyar una guia integrada en una plataforma híbrida de silici i sílice per generar espectres supercontinus. Aquest projecte presentava diferents rep…
Global dynamical behaviors in a physical shallow water system
2016
International audience; The theory of bifurcations of dynamical systems is used to investigate the behavior of travelling wave solutions in an entire family of shallow water wave equations. This family is obtained by a perturbative asymptotic expansion for unidirectional shallow water waves. According to the parameters of the system, this family can lead to different sets of known equations such as Camassa-Holm, Korteweg-de Vries, Degasperis and Procesi and several other dispersive equations of the third order. Looking for possible travelling wave solutions, we show that different phase orbits in some regions of parametric planes are similar to those obtained with the model of the pressure …
Quasi-soliton spatial autoguidé en milieu non lineaire quadratique
2021
International audience; Nous démontrons ici des phénomènes d'autoguidage optique existant dans les milieux à non-linéarités quadratiques. En plus de la formation puis disparition d'un phénomène auto confiné, nous observons des effets de commutation ultrarapide et de démultiplication spatiale, ainsi qu'une restructuration temporelle suivie d'élargissements spectraux.
Symmetry breakings in a metal organic framework with a confined guest
2020
The MOF $[{\text{Fe(tvp)}}_{2}{(\text{NCS})}_{2}]\ifmmode\cdot\else\textperiodcentered\fi{}2\text{BzCHO}$ is demonstrated to undergo a complex sequence of phase transitions and spin-crossover behavior of its constitutive ${\text{Fe}}^{\text{II}}$ ions upon adsorption of benzaldehyde guest molecules. Our study, combining Raman and synchrotron x-ray diffraction measurements on a single crystal, reveals that the conversion from the pure high-spin to the pure low-spin phases implies a rich sequence of intermediate phases, with symmetry breaking forming at least three different space groups. These different symmetries involve spin-state ordering, ligand ordering, and guest ordering, interpreted …
Influence of Different Rehydration Protocols on Biomechanical Properties of Allogeneic Cortical Bone Plates: A Combined in-vitro/in-vivo Study
2020
Introduction: Allogeneic cortical bone plates (CP) are used for alveolar ridge augmentation. Since CP are freeze-dried and dehydrated during processing, the breaking strength (BS) and the flexibility (FX) are reduced, resulting in a relevant risk for plate fractures during insertion. The aim of this study was to evaluate the influence of rehydration time on the biomechanical properties (BS & FX) of CP in-vitro and in vivo.Material and Methods: 40 CP were randomly divided into four experimental groups. (A) untreated control (n = 10), rehydration for 10 (B), 30 (C) and 60 (D) minutes in 0.9% saline solution (n = 10 each). BS [Newton, N] and FX [mm] (force till fracture and distance of deflect…
Spin-crossover iron(ii) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T(LIESST) of 120 K.
2019
We report a Fe(II) complex based on 4′,4′′ carboxylic acid disubstituted dipyrazolylpyridine that shows a spin-crossover close to room temperature associated to a crystallographic phase transition and the LIESST effect with a high T(LIESST) of 120 K.